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Q.Describe any two methods of preparation of Ethane.

Andhra Pradesh BieapBIEAP Intermediate Board (1st Year) 2019Subjective· 4mImportance★★★★★
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Two standard laboratory routes to ethane: the Wurtz reaction on methyl bromide, and catalytic hydrogenation of ethylene.

Method 1: Wurtz reaction

An alkyl halide is treated with sodium metal in dry ether; two alkyl groups couple to form a higher alkane with twice the number of carbons.

2CH3-Br + 2Na --dry ether--> CH3-CH3 + 2NaBr

This works well for making a symmetrical alkane like ethane from methyl bromide.

Method 2: Catalytic hydrogenation of an alkene (or alkyne)

Ethylene (ethene) is hydrogenated using hydrogen gas in the presence of a finely divided metal catalyst (Ni, Pt or Pd):

CH2=CH2 + H2 --Ni/Pt/Pd, catalyst--> CH3-CH3

The pi bond of the alkene is saturated by addition of H2 across the double bond.

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