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Q.Give the structure of diamond, graphite and fullerenes.

Bihar BsebBihar Board Intermediate 1st Year 2022Subjective· 5mImportance★★★★★
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Structures of diamond and graphite (carbon allotropes)
Structures of diamond and graphite (carbon allotropes)

Diamond = sp³ 3D tetrahedral network; graphite = sp² hexagonal layers with delocalised electrons; fullerene (C₆₀) = sp² closed cage of hexagons and pentagons.

From NCERT Class 11 Chemistry (p-Block Elements — allotropes of carbon):

  1. Diamond:
  • Each carbon atom is sp³ hybridised and covalently bonded to four other carbons at the corners of a regular tetrahedron (bond angle 109.5°).

  • This gives a rigid, three-dimensional covalent network throughout the crystal.

  • Because all four valence electrons are used in strong σ-bonds, diamond is the hardest natural substance, has a very high melting point, and is a non-conductor of electricity.

  1. Graphite:
  • Each carbon atom is sp² hybridised and bonded to three other carbons in the same plane, forming flat sheets of fused hexagonal rings.

  • These layers are held together by weak van der Waals forces, so they can slide over one another — graphite is soft and used as a lubricant and in pencils.

  • The fourth (unhybridised p) electron of each carbon is delocalised over the layer, so graphite conducts electricity along the sheets.

  1. Fullerenes: …

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