Q.Compound (X) reacts with magnesium in the presence of dry ether to form a Grignard reagent, which is then treated with compound (Y) containing 3 carbon atoms to form an adduct which on hydrolysis gives 2-methylbutan-2-ol. Write the chemical reactions involved and name the compounds (X) and (Y).
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Start your 14-day free trial to unlock the full solution →Ethylmagnesium bromide (from bromoethane + Mg) adds across acetone's carbonyl; hydrolysis of the adduct gives 2-methylbutan-2-ol.
The target alcohol, 2-methylbutan-2-ol, is — a tertiary alcohol with an ethyl group and two methyl groups attached to the carbinol (C–OH) carbon. A tertiary alcohol of this type is made by adding a Grignard reagent, , across a ketone : the carbanion-like R group of the Grignard attacks the electrophilic carbonyl carbon, and after hydrolysis the three groups R, R', R'' (plus OH) end up on that carbon.
Working backwards: the carbinol carbon of the product carries , , and . The ketone (Y) supplies two of these groups still joined together as its own , and the Grignard reagent supplies the third group.
- Compound X (2 carbons): bromoethane, . Reacting with magnesium turnings in dry ether forms the Grignard reagent, ethylmagnesium bromide: .
- Compound Y (3 carbons): propan-2-one (acetone), — it already carries the two methyl groups needed on the final carbinol carbon. …
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