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Q.In the formula (P + A/V²)(V − B) = RT, P is pressure and V is the volume. Calculate the dimensions of A and B.

Haryana BsehBoard of School Education Haryana (Senior Secondary Part-I / Class 11) 2025Subjective· 2mImportance★★★★★
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Every term added to or subtracted from a quantity must share its dimensions — so A/V2A/V^2 must dimensionally match pressure, and BB must dimensionally match volume.

The given equation is the van der Waals-type equation (P+A/V2)(V−B)=RT(P + A/V^2)(V - B) = RT.

Dimension of B: Since BB is subtracted from VV inside the bracket, BB must have the same dimensions as volume:

[B]=[V]=[L3]=[M0L3T0][B] = [V] = [L^3] = [M^0L^3T^0]

Dimension of A: Since A/V2A/V^2 is added to pressure PP, it must have the same dimensions as pressure:

[A/V2]=[P][A/V^2] = [P]

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