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Q.Give construction and working of Dry cell.
Himachal HpboseHPBOSE Plus Two Board 2023Subjective· 2mImportance★★★★★
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Start your 14-day free trial to unlock the full solution →The dry cell is a compact Leclanché-type primary cell: Zn container (anode), graphite rod (cathode) surrounded by MnO₂/carbon/NH₄Cl paste (electrolyte).
Construction:
- The outer casing is a cylindrical zinc container, which itself acts as the anode.
- In the centre is a graphite (carbon) rod, surrounded by a compact paste/powder of manganese dioxide () and carbon powder — this rod acts as the cathode.
- The space between the zinc container and the central rod is filled with a moist paste of ammonium chloride () and zinc chloride (), which serves as the electrolyte.
- The whole assembly is sealed at the top, with the carbon rod projecting out as the positive terminal and the zinc case as the negative terminal.
Working (electrode reactions):
At the anode (zinc container), oxidation occurs:
At the cathode, manganese dioxide is reduced (ammonium ions are also involved in the overall process):
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