Q.State and explain law of constant proportion.
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Start your 14-day free trial to unlock the full solution →Every pure sample of a given compound has a fixed mass ratio of its constituent elements, no matter how or where it was made — this is the law of constant/definite proportions.
Statement (Proust, 1799). A given chemical compound always contains exactly the same proportion of elements by mass, irrespective of the method of preparation or the source of the compound.
Explanation. If a compound is broken down into its elements, or synthesised from its elements, the ratio of the masses of the elements present is always the same fixed value for that compound.
Example. Pure water (H2O), whichever way it is obtained — from a river, from rainfall, by burning hydrogen in oxygen, or by neutralising an acid and a base — always contains hydrogen and oxygen combined in the same mass ratio of 1:8 (i.e., 2 g of hydrogen combines with 16 g of oxygen to give 18 g of water). Similarly, carbon dioxide always has carbon and oxygen in a mass ratio of 3:8, regardless of source.
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