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Q.Calculate the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride.
[Given Molar mass of Benzene = 78 g/mol, Molar mass of carbon tetrachloride = 154 g/mol]

Karnataka PUCKarnataka II PUC Board 2024Subjective· 3mImportance★★★★★
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Taking 100 g of solution (30 g benzene, 70 g CCl4\text{CCl}_4), the mole fraction of benzene works out to about 0.458.

Given: 30% benzene by mass in CCl4\text{CCl}_4; Mbenzene=78 g mol−1M_{\text{benzene}} = 78\,\text{g mol}^{-1}, MCCl4=154 g mol−1M_{\text{CCl}_4} = 154\,\text{g mol}^{-1}.

Take 100 g of solution ⇒\Rightarrow 30 g benzene and 70 g CCl4\text{CCl}_4.

Moles:

nbenzene=3078=0.3846 moln_{\text{benzene}} = \frac{30}{78} = 0.3846\,\text{mol}

nCCl4=70154=0.4545 moln_{\text{CCl}_4} = \frac{70}{154} = 0.4545\,\text{mol}

Mole fraction of benzene: …

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