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Question of 147

Q.Identify the products X and Y formed in the following reactions :

(i) CH3CH2OH + PCl5 -> X + POCl3 + HCl
(1)
(ii) CH3Br + AgF -> Y + AgBr (1)
Kerala DhseKerala DHSE Plus Two Board 2026Subjective· 2mImportance★★★★★
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PCl5 converts an alcohol -OH into -Cl (X = C2H5Cl); AgF converts an alkyl bromide into an alkyl fluoride by the Swarts reaction (Y = CH3F).

  1. CH3CH2OH + PCl5 -> CH3CH2Cl + POCl3 + HCl. The hydroxyl group of ethanol is replaced by chlorine, giving chloroethane (X).
  2. CH3Br + AgF -> CH3F + AgBr. …

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