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Q.Which of the following compounds has the most electronegative carbon atom?

(a) CH4
(b) CH3-CH3
(c) CH2=CH2
(d) CH3-C≡CH
Manipur CohsemCouncil of Higher Secondary Education, Manipur (Higher Secondary 1st Year) 2024MCQ· 1mImportance★★★★★
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Electronegativity of a carbon atom rises with the percentage of s-character in its hybridisation: sp3 < sp2 < sp. CH3-C≡CH contains an sp carbon.

The electronegativity of a carbon atom depends on its hybridisation, because s-orbitals hold electrons closer to the nucleus than p-orbitals — the greater the s-character, the more electronegative the carbon:

  • CH4: all carbon is sp3 (25% s-character) — least electronegative.
  • CH3-CH3 (ethane): both carbons sp3 — same as above.
  • CH2=CH2 (ethene): carbons are sp2 (33% s-character) — more electronegative than sp3. …

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