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Q.Write the bond line formula for: 4-Chloro - 2, 3, 5 - trimethyl hexanal

Manipur CohsemCouncil of Higher Secondary Education, Manipur (Higher Secondary 1st Year) 2023Subjective· 1mImportance★★★★★
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4-Chloro-2,3,5-trimethylhexanal is a 6-carbon aldehyde chain: CHO-CH(CH3)-CH(CH3)-CHCl-CH(CH3)-CH3.

To build the structure from the IUPAC name:

  1. 'Hexanal' fixes the parent chain as 6 carbons with an aldehyde (-CHO) group, which is always numbered as C1 (the principal characteristic group gets the lowest possible locant, and for an aldehyde the carbonyl carbon IS C1).

    C1(CHO) - C2 - C3 - C4 - C5 - C6

  2. Place the substituents at the numbered positions given by the name '4-Chloro-2,3,5-trimethyl':

  • Chloro (Cl) at C4

  • Methyl (CH3) at C2, C3 and C5

  1. Filling in the full structure: C1: -CHO C2: -CH(CH3)- C3: -CH(CH3)- C4: -CHCl- C5: -CH(CH3)- C6: -CH3 (terminal carbon, now bearing 3 H since C5 already has a methyl branch)

Full condensed structural formula:

OHC-CH(CH3)-CH(CH3)-CHCl-CH(CH3)-CH3

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