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Q.Identify AA and BB in the following reaction (1+1=2): bromocyclohexane +Mg→dry ether[A]→H2O/H+[B]+ Mg \xrightarrow{\text{dry ether}} [A] \xrightarrow{H_2O/H^+} [B]

Meghalaya MboseMBOSE Meghalaya Intermediate Board 2023Subjective· 2mImportance★★★★★
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Mg insertion into the C–Br bond of bromocyclohexane (in dry ether) gives the Grignard reagent [A]; its hydrolysis by aqueous acid replaces the −MgBr-MgBr group with −H-H to give plain cyclohexane [B].

Formation of [A] — the Grignard reagent: Bromocyclohexane reacts with magnesium metal in anhydrous (dry) ether. Dry conditions are essential because Grignard reagents are extremely moisture-sensitive. Magnesium inserts into the carbon–halogen bond:

C6H11Br+Mg→dry etherC6H11MgBr    [A]C_6H_{11}Br + Mg \xrightarrow{\text{dry ether}} C_6H_{11}MgBr \;\; [A]

[A] is cyclohexylmagnesium bromide, a Grignard reagent in which the cyclohexyl carbon bears a highly polarized, carbanion-like Cδ−−Mgδ+C^{\delta-}-Mg^{\delta+} bond.

Hydrolysis of [A] — formation of [B]: Grignard reagents react instantly with any active-hydrogen compound, including water; the strongly nucleophilic/basic carbanion-like carbon is simply protonated, replacing −MgBr-MgBr with −H-H: …

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