Q.Identify and in the following reaction (1+1=2): bromocyclohexane
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Start your 14-day free trial to unlock the full solution →Mg insertion into the C–Br bond of bromocyclohexane (in dry ether) gives the Grignard reagent [A]; its hydrolysis by aqueous acid replaces the group with to give plain cyclohexane [B].
Formation of [A] — the Grignard reagent: Bromocyclohexane reacts with magnesium metal in anhydrous (dry) ether. Dry conditions are essential because Grignard reagents are extremely moisture-sensitive. Magnesium inserts into the carbon–halogen bond:
[A] is cyclohexylmagnesium bromide, a Grignard reagent in which the cyclohexyl carbon bears a highly polarized, carbanion-like bond.
Hydrolysis of [A] — formation of [B]: Grignard reagents react instantly with any active-hydrogen compound, including water; the strongly nucleophilic/basic carbanion-like carbon is simply protonated, replacing with : …
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