Q.The colligative properties of a dilute solution depend upon the
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Start your 14-day free trial to unlock the full solution →Colligative properties are defined precisely as properties that depend on the number of solute particles in solution, not on what those particles are — so option (b) is correct by definition.
The defining feature of colligative properties
Colligative properties — relative lowering of vapour pressure, elevation in boiling point (), depression in freezing point (), and osmotic pressure () — arise purely from the dilution effect a solute has on the solvent: adding solute particles lowers the effective mole fraction/chemical potential of solvent molecules at the surface, which shifts vapour–liquid and solid–liquid equilibria. This shift depends only on how many solute particles are present per unit amount of solvent, e.g. or , where (or molality ) counts particles, with no term for the solute's identity, mass, or specific charge (beyond the van't Hoff factor , which itself just corrects the particle count for dissociation/association).
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