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Q.The colligative properties of a dilute solution depend upon the

(a) nature of solute
(b) number of particles of solute
(c) number of particles of solvent
(d) nature of solvent
Meghalaya MboseMBOSE Meghalaya Intermediate Board 2022MCQ· 1mImportance★★★★★
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Colligative properties are defined precisely as properties that depend on the number of solute particles in solution, not on what those particles are — so option (b) is correct by definition.

The defining feature of colligative properties

Colligative properties — relative lowering of vapour pressure, elevation in boiling point (ΔTb\Delta T_b), depression in freezing point (ΔTf\Delta T_f), and osmotic pressure (π\pi) — arise purely from the dilution effect a solute has on the solvent: adding solute particles lowers the effective mole fraction/chemical potential of solvent molecules at the surface, which shifts vapour–liquid and solid–liquid equilibria. This shift depends only on how many solute particles are present per unit amount of solvent, e.g. π=CRT\pi = CRT or ΔTb=Kb m\Delta T_b = K_b\,m, where CC (or molality mm) counts particles, with no term for the solute's identity, mass, or specific charge (beyond the van't Hoff factor ii, which itself just corrects the particle count for dissociation/association).

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