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Q.What is the mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride?

(a) 0.540
(b) 0.459
(c) 0.500
(d) 0.300
Punjab PsebPSEB Punjab Class 12 Board 2025MCQ· 1mImportance★★★★★
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Taking 100 g of solution (30 g benzene + 70 g CCl₄) and converting to moles gives a benzene mole fraction of 0.459.

Assume 100 g of solution: mass of benzene (C6H6C_6H_6, M = 78 g mol⁻¹) = 30 g; mass of CCl4CCl_4 (M = 12 + 4×35.5 = 154 g mol⁻¹) = 70 g.

nbenzene=3078=0.3846 moln_{benzene} = \frac{30}{78} = 0.3846\ mol

nCCl4=70154=0.4545 moln_{CCl_4} = \frac{70}{154} = 0.4545\ mol

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