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Q.(a) What could be the IUPAC name and symbol for the element with atomic number 120? [1]

(b) Explain why cations are smaller and anions larger in radii than their parent atoms. [2]
Rajasthan RbseRajasthan Board Senior Secondary Part-I Examination 2017Subjective· 3mImportance★★★★★
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(a) IUPAC names element 120 systematically as Unbinilium (Ubn) using digit roots 1=un, 2=bi, 0=nil. (b) Cations shrink and anions expand relative to the parent atom because of the change in the ratio of nuclear charge to number of electrons (effective nuclear charge per electron).

(a) IUPAC name/symbol for element 120:

For elements without a permanent, officially assigned name (or in general, using the systematic method), IUPAC assigns a temporary name built from digit roots for each digit of the atomic number, followed by the suffix "-ium":

0 = nil, 1 = un, 2 = bi, 3 = tri, 4 = quad, 5 = pent, 6 = hex, 7 = sept, 8 = oct, 9 = enn.

For Z = 120, the digits are 1-2-0, giving: un + bi + nil + ium = Unbinilium.

The three-letter symbol is formed from the first letter of each root: U-b-n = Ubn.

(b) Why cations are smaller and anions are larger than the parent atom:

Cations: When an atom loses one or more electrons to form a cation, the same (unchanged) nuclear charge now acts on fewer electrons. This increases the effective nuclear charge experienced by each remaining electron, pulling the electron cloud in more tightly. Additionally, for many cations, the electron removed comes from the outermost shell, which can leave the ion with one fewer occupied shell altogether (e.g., Na loses its single 3s electron to become Na+, which then has only the compact 2,8 core left) -- both effects sharply reduce the ionic size compared to the neutral atom. …

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