Skip to content
Question of 87

Q.CH3-CN reacts with 2H2O/H+ (-NH3) to give [A]; [A] reacts with NH3 to give [B]; [B] on heating (Delta, -H2O) gives [C]. Write chemical formula of [A], [B] and [C] in the above reaction sequence.

Rajasthan RbseRajasthan Board Senior Secondary Examination 2022Subjective· 2mImportance★★★★★
0% · 0/87 Questions
🔒 Locked · start free trial →

You're viewing a preview — the full solution, concept, methods & PYQ mapping are locked.

Start your 14-day free trial to unlock the full solution →

Acid hydrolysis of the nitrile CH3CN gives acetic acid [A], which forms ammonium acetate [B] with NH3, and heating [B] drives off water to form the amide acetamide [C].

Step 1: CH3-C(triple bond)N (acetonitrile) is hydrolysed with 2 mol of water under acidic (H+) conditions. This converts the nitrile to a carboxylic acid, releasing NH3 (shown in the question as '-NH3'):

CH3CN + 2H2O --H+--> CH3COOH + NH3

So [A] = CH3COOH (acetic acid / ethanoic acid).

Step 2: Acetic acid [A] reacts with ammonia (an acid-base neutralisation) to form ammonium acetate:

CH3COOH + NH3 -> CH3COONH4

So [B] = CH3COONH4 (ammonium acetate).

…

Unlock everything free for 14 days

  • Full step-by-step solutions
  • Concept-first explanations
  • Methods, shortcuts & mistakes
  • PYQ mapping + timed mock tests

Full access for 14 days. No credit card required.