Chemistry · Class 11 Science
Ch 12Basic Concepts of Organic Reactions — Class 11 Chemistry, concept-first.
Knowing WHAT an organic reaction produces is only half the story -- this unit is about HOW it gets there: which bonds break, which electrons move, and what fleeting species form along the way.
Key concepts
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Types of Organic Reactions
Organic reactions are classified by the overall structural change:
Most relevant Q&A
Chapter contents
The NCERT structure, section by section. Open a section to see its questions, then read the concept-first solution.
Introduction
Knowing WHAT an organic reaction produces is only half the story -- this unit is about HOW it gets there: which bonds break, which electrons move, and what fleeting species form along the way.
Introduction
A chemical reaction is, at its core, a process in which some of the bonds already present in the reacting molecules break while new bonds form -- the reactant is converted into the product, and this c…
Fundamental Concepts in Organic Reaction Mechanism
To actually use the idea of a mechanism, this unit builds up a small toolkit of fundamental concepts that recur in every organic reaction from here on.
Fission of a Covalent Bond
All organic molecules are built from covalent bonds, formed by two atoms mutually sharing a pair of electrons.
Homolytic Cleavage
Homolytic cleavage is the process in which a covalent bond breaks symmetrically, so that each of the two previously bonded atoms keeps exactly one of the shared electrons.
Heterolytic Cleavage
Heterolytic cleavage is the process in which a covalent bond breaks unsymmetrically -- one of the two bonded atoms keeps both electrons of the bonding pair, while the other keeps none.
Nucleophiles and Electrophiles
Once a bond has broken -- homolytically into free radicals, or heterolytically into a carbocation-type or carbanion-type fragment -- the reacting species that come together to form new bonds fall into…
Electron Movement in Organic Reactions
Beyond simply classifying a species as a nucleophile or electrophile, every organic reaction can be understood in a deeper, unified way by following the movement of electrons -- that is, tracking how…
Electron Displacement Effects in Co-valent Bonds
So far, the unit has looked at electron movement during a reaction. But even before any reagent arrives, an organic molecule's own covalent bonds are not electronically neutral or static -- properties…
Inductive Effect (I)
The inductive effect (I) is defined as the change in the polarisation of a covalent bond caused by the presence of an adjacent bond, atom or group elsewhere in the molecule.
Electromeric Effect (E)
The electromeric effect (E) is a temporary effect -- unlike the inductive, resonance and hyperconjugation effects covered elsewhere in this unit, it exists only while a reagent is actually attacking,…
Resonance or Mesomeric Effect
Resonance (also called mesomerism or the mesomeric effect) is a phenomenon seen in certain organic compounds that carry a double bond at a suitable position, and in which the true structure cannot be…
Hyperconjugation
Hyperconjugation is the delocalisation of electrons from a sigma bond (typically a C-H or C-C bond) into an adjacent, empty non-bonding p-orbital, or into an adjacent anti-bonding or -orbital -- in ef…
Different Types of Organic Reactions
Individual organic compounds can undergo an enormous number of specific named reactions, but almost the entire universe of organic reactions can be sorted into just six broad mechanistic categories:
Substitution Reaction (Displacement Reaction)
A substitution reaction (also called a displacement reaction) is one in which an atom or a group of atoms already attached to a carbon is replaced by a new atom or group.
Addition Reactions
An addition reaction is the characteristic reaction of an unsaturated compound -- one containing a localised C=C double bond or CC triple bond.
Elimination Reactions
In an elimination reaction, two substituents are removed from the substrate -- one from each of two adjacent carbon atoms (conventionally labelled the -carbon, bearing the leaving group, and the -carb…
Oxidation and Reduction Reactions
Many oxidation and reduction reactions of organic compounds can, on close inspection, be understood as a special case of one of the four reaction types already introduced (substitution, addition, elim…
Functional Group Interconversion
Beyond classifying reactions by mechanism, organic synthesis in practice is very often about functional group interconversion -- taking a molecule that already carries one functional group and convert…
Sample & Board Papers
Sample papers and previous-year board questions for this subject.
+−Show 13 questionsHide questions13 questions
- Q1Which of the following species does not exert a resonance effect? (a) C6H5NH2 (b) C6H5NH3+ (c) C6H5OH (d) C6H5ClPreview
- Q2(a) (i) What is Van't Hoff factor 'i'? (ii) Complete: (A) H2C=CH2 + H-Br, in the presence of Benzoyl peroxide, gives ___. (B) CH3CHO, treate…Preview
- Q3The correct relative order of +I effect of alkyl groups is: (a) -C(CH3)3 > -CH(CH3)2 > -CH2CH3 > -CH3 (b) -CH3 > -CH2CH3 > -CH(CH3)2 > -C(CH…Preview
- Q4(-)CH2-C(=O)-CH3 and CH2=C(-O^-)-CH3 (structures shown in the original paper) are: (a) optical isomers (b) resonating structures (c) conform…Preview
- Q5Give any three differences between nucleophiles and electrophiles.Preview
- Q6-I effect is shown by : (a) -Cl (b) -Br (c) both (a) and (b) (d) -CH3Preview
- Q7Explain inductive effect with suitable example.Preview
- Q8Homolytic fission of covalent bond leads to the formation of: (a) carbo cation (b) electrophile (c) free radical (d) nucleophilePreview
- Q9Differentiate Nucleophile and Electrophile.Preview
- Q10Explain SN2 reaction mechanism.Preview
- Q11Which of the following species does not exert a resonance effect ? (a) C6H5NH2 (b) C6H5OH (c) C6H5NH3+ (d) C6H5ClPreview
- Q12What is Inductive effect ?Preview
- Q13Why chlorination of methane is not possible in dark ?Preview
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21 Q+−Show 15 questionsHide questions15 questions
- Q1For the following reactions (A) CH₃CH₂CH₂Br + KOH → CH₂=CH₂ + KBr + H₂O (B) (CH₃)₃CBr + KOH → (CH₃)₃COH + KBr (C) Cyclohexene + Br₂ → 1,2-di…Free
- Q2What is the hybridisation state of benzyl carbonium ion? (a) sp² (b) spd² (c) sp³ (d) sp²dFree
- Q3Decreasing order of nucleophilicity is (a) OH⁻ > NH₂⁻ > ⁻OCH₃ > RNH₂ (b) NH₂⁻ > OH⁻ > ⁻OCH₃ > RNH₂ (c) NH₂⁻ > CH₃O⁻ > OH⁻ > RNH₂ (d) CH₃O⁻ >…Free
- Q4Which of the following species is not electrophilic in nature? (a) Cl⁺ (b) BH₃ (c) H₃O⁺ (d) ⁺NO₂Preview
- Q5Homolytic fission of covalent bond leads to the formation of (a) electrophile (b) nucleophile (c) Carbocation (d) free radicalPreview
- Q6Hyper Conjugation is also known as (a) no bond resonance (b) Baker - nathan effect (c) both (a) and (b) (d) none of thesePreview
- Q7Which of the group has highest +I effect? (a) CH₃- (b) CH₃-CH₂- (c) (CH₃)₂-CH- (d) (CH₃)₃-C-Preview
- Q8Which of the following species does not exert a resonance effect? (a) C₆H₅OH (b) C₆H₅Cl (c) C₆H₅NH₂ (d) C₆H₅NH₃⁺Preview
- Q9-I effect is shown by (a) -Cl (b) -Br (c) both (a) and (b) (d) -CH₃Preview
- Q10Which of the following carbocation will be most stable? (a) Ph₃C-⁺ (b) CH₃-CH₂⁺ (c) (CH₃)₂-CH⁺ (d) CH₂=CH-CH₂⁺Preview
- Q11Assertion: Tertiary Carbocations are generally formed more easily than primary Carbocations ions. Reason: Hyper conjugation as well as induc…Preview
- Q12Heterolytic fission of C-Br bond results in the formation of (a) free radical (b) Carbanion (c) Carbocation (d) Carbanion and CarbocationPreview
- Q13Which of the following represent a set of nuclephiles? (a) BF₃, H₂O, NH₂⁻ (b) AlCl₃, BF₃, NH₃ (c) CN⁻, RCH₂⁻, ROH (d) H⁺, RNH₃⁺, :CCl₂Preview
- Q14Which of the following species does not acts as a nucleophile? (a) ROH (b) ROR (c) PCl₃ (d) BF₃Preview
- Q15The geometrical shape of carbocation is (a) Linear (b) tetrahedral (c) Planar (d) PyramidalPreview
+−Show 6 questionsHide questions6 questions
- Q1Write short notes on (a) Resonance (b) HyperconjucationFree
- Q2What are electrophiles and nucleophiles? Give suitable examples for each.Free
- Q3Show the heterolysis of covalent bond by using curved arrow notation and complete the following equations. Identify the nucleophile is each…Preview
- Q4Explain inductive effect with suitable example.Preview
- Q5Explain electromeric effect.Preview
- Q6Give examples for the following types of organic reactions (i) β - elimination (ii) electrophilic substitution.Preview