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Chemistry · Class 11 Science

Ch 12Basic Concepts of Organic Reactions — Class 11 Chemistry, concept-first.

Knowing WHAT an organic reaction produces is only half the story -- this unit is about HOW it gets there: which bonds break, which electrons move, and what fleeting species form along the way.

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Key concepts

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Chapter contents

The NCERT structure, section by section. Open a section to see its questions, then read the concept-first solution.

Introduction

Knowing WHAT an organic reaction produces is only half the story -- this unit is about HOW it gets there: which bonds break, which electrons move, and what fleeting species form along the way.

12.1

Introduction

A chemical reaction is, at its core, a process in which some of the bonds already present in the reacting molecules break while new bonds form -- the reactant is converted into the product, and this c…

12.1.1

Fundamental Concepts in Organic Reaction Mechanism

To actually use the idea of a mechanism, this unit builds up a small toolkit of fundamental concepts that recur in every organic reaction from here on.

12.1.2

Fission of a Covalent Bond

All organic molecules are built from covalent bonds, formed by two atoms mutually sharing a pair of electrons.

Homolytic Cleavage

Homolytic cleavage is the process in which a covalent bond breaks symmetrically, so that each of the two previously bonded atoms keeps exactly one of the shared electrons.

Heterolytic Cleavage

Heterolytic cleavage is the process in which a covalent bond breaks unsymmetrically -- one of the two bonded atoms keeps both electrons of the bonding pair, while the other keeps none.

12.1.3

Nucleophiles and Electrophiles

Once a bond has broken -- homolytically into free radicals, or heterolytically into a carbocation-type or carbanion-type fragment -- the reacting species that come together to form new bonds fall into…

12.1.4

Electron Movement in Organic Reactions

Beyond simply classifying a species as a nucleophile or electrophile, every organic reaction can be understood in a deeper, unified way by following the movement of electrons -- that is, tracking how…

12.1.5

Electron Displacement Effects in Co-valent Bonds

So far, the unit has looked at electron movement during a reaction. But even before any reagent arrives, an organic molecule's own covalent bonds are not electronically neutral or static -- properties…

Inductive Effect (I)

The inductive effect (I) is defined as the change in the polarisation of a covalent bond caused by the presence of an adjacent bond, atom or group elsewhere in the molecule.

Electromeric Effect (E)

The electromeric effect (E) is a temporary effect -- unlike the inductive, resonance and hyperconjugation effects covered elsewhere in this unit, it exists only while a reagent is actually attacking,…

Resonance or Mesomeric Effect

Resonance (also called mesomerism or the mesomeric effect) is a phenomenon seen in certain organic compounds that carry a double bond at a suitable position, and in which the true structure cannot be…

Hyperconjugation

Hyperconjugation is the delocalisation of electrons from a sigma bond (typically a C-H or C-C bond) into an adjacent, empty non-bonding p-orbital, or into an adjacent anti-bonding or -orbital -- in ef…

12.2

Different Types of Organic Reactions

Individual organic compounds can undergo an enormous number of specific named reactions, but almost the entire universe of organic reactions can be sorted into just six broad mechanistic categories:

12.2.1

Substitution Reaction (Displacement Reaction)

A substitution reaction (also called a displacement reaction) is one in which an atom or a group of atoms already attached to a carbon is replaced by a new atom or group.

12.2.2

Addition Reactions

An addition reaction is the characteristic reaction of an unsaturated compound -- one containing a localised C=C double bond or CC triple bond.

Elimination Reactions

In an elimination reaction, two substituents are removed from the substrate -- one from each of two adjacent carbon atoms (conventionally labelled the -carbon, bearing the leaving group, and the -carb…

Oxidation and Reduction Reactions

Many oxidation and reduction reactions of organic compounds can, on close inspection, be understood as a special case of one of the four reaction types already introduced (substitution, addition, elim…

12.3

Functional Group Interconversion

Beyond classifying reactions by mechanism, organic synthesis in practice is very often about functional group interconversion -- taking a molecule that already carries one functional group and convert…

Sample & Board Papers

Sample papers and previous-year board questions for this subject.

More questions

21 Q
+Show 15 questions15 questions
  1. Q1For the following reactions (A) CH₃CH₂CH₂Br + KOH → CH₂=CH₂ + KBr + H₂O (B) (CH₃)₃CBr + KOH → (CH₃)₃COH + KBr (C) Cyclohexene + Br₂ → 1,2-di…Free
  2. Q2What is the hybridisation state of benzyl carbonium ion? (a) sp² (b) spd² (c) sp³ (d) sp²dFree
  3. Q3Decreasing order of nucleophilicity is (a) OH⁻ > NH₂⁻ > ⁻OCH₃ > RNH₂ (b) NH₂⁻ > OH⁻ > ⁻OCH₃ > RNH₂ (c) NH₂⁻ > CH₃O⁻ > OH⁻ > RNH₂ (d) CH₃O⁻ >…Free
  4. Q4Which of the following species is not electrophilic in nature? (a) Cl⁺ (b) BH₃ (c) H₃O⁺ (d) ⁺NO₂Preview
  5. Q5Homolytic fission of covalent bond leads to the formation of (a) electrophile (b) nucleophile (c) Carbocation (d) free radicalPreview
  6. Q6Hyper Conjugation is also known as (a) no bond resonance (b) Baker - nathan effect (c) both (a) and (b) (d) none of thesePreview
  7. Q7Which of the group has highest +I effect? (a) CH₃- (b) CH₃-CH₂- (c) (CH₃)₂-CH- (d) (CH₃)₃-C-Preview
  8. Q8Which of the following species does not exert a resonance effect? (a) C₆H₅OH (b) C₆H₅Cl (c) C₆H₅NH₂ (d) C₆H₅NH₃⁺Preview
  9. Q9-I effect is shown by (a) -Cl (b) -Br (c) both (a) and (b) (d) -CH₃Preview
  10. Q10Which of the following carbocation will be most stable? (a) Ph₃C-⁺ (b) CH₃-CH₂⁺ (c) (CH₃)₂-CH⁺ (d) CH₂=CH-CH₂⁺Preview
  11. Q11Assertion: Tertiary Carbocations are generally formed more easily than primary Carbocations ions. Reason: Hyper conjugation as well as induc…Preview
  12. Q12Heterolytic fission of C-Br bond results in the formation of (a) free radical (b) Carbanion (c) Carbocation (d) Carbanion and CarbocationPreview
  13. Q13Which of the following represent a set of nuclephiles? (a) BF₃, H₂O, NH₂⁻ (b) AlCl₃, BF₃, NH₃ (c) CN⁻, RCH₂⁻, ROH (d) H⁺, RNH₃⁺, :CCl₂Preview
  14. Q14Which of the following species does not acts as a nucleophile? (a) ROH (b) ROR (c) PCl₃ (d) BF₃Preview
  15. Q15The geometrical shape of carbocation is (a) Linear (b) tetrahedral (c) Planar (d) PyramidalPreview
+Show 6 questions6 questions
  1. Q1Write short notes on (a) Resonance (b) HyperconjucationFree
  2. Q2What are electrophiles and nucleophiles? Give suitable examples for each.Free
  3. Q3Show the heterolysis of covalent bond by using curved arrow notation and complete the following equations. Identify the nucleophile is each…Preview
  4. Q4Explain inductive effect with suitable example.Preview
  5. Q5Explain electromeric effect.Preview
  6. Q6Give examples for the following types of organic reactions (i) β - elimination (ii) electrophilic substitution.Preview