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Chemistry · Class 11 Science

Ch 3Classification of Elements and Periodicity in Properties — Class 11 Chemistry, concept-first.

Nobel laureate Glenn T. Seaborg once described the Periodic Table as one of the most important ideas in all of chemistry — not just a reference chart, but a map that reveals how chemical elements are organised into families with recurring, predictable properties.

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Introduction

Nobel laureate Glenn T. Seaborg once described the Periodic Table as one of the most important ideas in all of chemistry — not just a reference chart, but a map that reveals how chemical elements are…

3.1

Why do we need to Classify Elements?

By 1800, chemists knew only 31 elements. By 1865, that number had jumped to 63. Today, we know 114 elements, and the most recent ones are man-made — created in laboratories through nuclear reactions.

3.2

Genesis of Periodic Classification

The modern Periodic Table did not appear overnight. It is the product of nearly a century of observations, guesses, corrections, and bold predictions by several scientists.

3.3

Modern Periodic Law and the Present Form of the Periodic Table

Mendeleev's periodic law stated that the properties of elements are a periodic function of their atomic masses.

3.4

Nomenclature of Elements with Atomic Numbers > 100

For most of chemistry's history, the discoverer of a new element had the privilege of naming it, subject to ratification by the International Union of Pure and Applied Chemistry (IUPAC).

3.5

Electronic Configurations of Elements and the Periodic Table

The distribution of electrons into the orbitals of an atom is called its electronic configuration. The position of an element in the Periodic Table is directly linked to the quantum numbers of the las…

3.6

Electronic Configurations and Types of Elements: s-, p-, d-, f-Blocks

The Aufbau principle and each element's electronic configuration give a solid theoretical footing for periodic classification.

3.6.1

The s-Block Elements

The s-block of the periodic table consists of two groups: Group 1 (the alkali metals) and Group 2 (the alkaline earth metals).

3.6.2

The p-Block Elements

The p-block is the right-hand block of the periodic table, spanning Groups 13 through 18. Together with the s-block elements (Groups 1 and 2), these are called the Representative Elements or Main Grou…

3.6.3

The d-Block Elements (Transition Elements)

The d-block elements occupy Groups 3 through 12 in the centre of the Periodic Table. Their defining feature is the filling of inner d orbitals with electrons — specifically, the subshell.

3.6.4

The f-Block Elements (Inner-Transition Elements)

The periodic table places two rows of elements separately at the bottom: the Lanthanoids (Cerium, Z = 58, to Lutetium, Z = 71) and the Actinoids (Thorium, Z = 90, to Lawrencium, Z = 103).

3.6.5

Metals, Non-metals and Metalloids

The periodic table groups elements not only into s, p, d, and f blocks, but also into three broad categories based on their physical and chemical properties: metals, non-metals, and metalloids (also c…

3.7

Periodic Trends in Properties of Elements

The periodic table is not just a catalogue of elements — it is a map of repeating patterns. As you move down a group or across a period, physical and chemical properties change in predictable ways.

3.7.1

Trends in Physical Properties

The periodic table is not just a list of elements; it is a map of how atoms behave. The physical properties of elements — their size, the energy needed to remove an electron, the energy released when…

3.7.1(a)

(a) Atomic Radius

Measuring the size of an atom is not like measuring the radius of a ball. There are two fundamental difficulties. First, an atom is incredibly small — its radius is on the order of m (or 1.2 Å).

3.7.1(b)

(b) Ionic Radius

When an atom loses an electron to form a cation (a positive ion), its size decreases. The nuclear charge remains the same, but there are now fewer electrons.

3.7.1(c)

(c) Ionization Enthalpy

Ionization enthalpy () is a quantitative measure of the tendency of an element to lose an electron. It is defined as the energy required to remove the most loosely bound electron from an isolated gase…

3.7.1(d)

(d) Electron Gain Enthalpy

Electron gain enthalpy () is the enthalpy change that occurs when an electron is added to a neutral, isolated gaseous atom to form a negative ion.

3.7.1(e)

(e) Electronegativity

Electronegativity is a qualitative measure of the ability of an atom in a chemical compound to attract shared electrons to itself.

3.7.2

Periodic Trends in Chemical Properties

The chemical behaviour of elements follows predictable patterns across the periodic table. Two major themes emerge: the periodicity of valence (or oxidation states), and the anomalous properties of th…

3.7.2(a)

(a) Periodicity of Valence or Oxidation States

Valence is the most characteristic property of an element. For representative (s- and p-block) elements, the valence is usually equal to either the number of electrons in the outermost shell or eight…

3.7.2(b)

(b) Anomalous Properties of Second Period Elements

The first element of each group — lithium (group 1), beryllium (group 2), and boron through fluorine (groups 13–17) — differs significantly from the other members of its group.

3.7.3

Periodic Trends and Chemical Reactivity

The periodic table is not just an arrangement of elements — it is a map of chemical behaviour. Every physical and chemical property of an element ultimately stems from its electronic configuration.

Summary

- Moseley’s law established that atomic number (), not atomic mass, is the fundamental property determining element identity.

Exercises

This closing exercise set gives you 40 questions covering everything in the unit — from the historical development of the Periodic Table and the IUPAC naming of superheavy elements, to electronic conf…

+Exercisesi40 questions
  1. 3.1What is the basic theme of organisation in the periodic table?Free
  2. 3.2Which important property did Mendeleev use to classify the elements in his periodic table and did he stick to that?Free
  3. 3.3What is the basic difference in approach between the Mendeleev's Periodic Law and the Modern Periodic Law?Free
  4. 3.4On the basis of quantum numbers, justify that the sixth period of the periodic table should have 32 elements.Preview
  5. 3.5In terms of period and group where would you locate the element with $Z = 114$?Preview
  6. 3.6Write the atomic number of the element present in the third period and seventeenth group of the periodic table.Preview
  7. 3.7Which element do you think would have been named by (i) Lawrence Berkeley Laboratory (ii) Seaborg's group?Preview
  8. 3.8Why do elements in the same group have similar physical and chemical properties?Preview
  9. 3.9What does atomic radius and ionic radius really mean to you?Preview
  10. 3.10How do atomic radius vary in a period and in a group? How do you explain the variation?Preview
  11. 3.11What do you understand by isoelectronic species? Name a species that will be isoelectronic with each of the following atoms or ions. (i) $F^…Preview
  12. 3.12Consider the following species: $N^{3-}, O^{2-}, F^-, Na^+, Mg^{2+}$ and $Al^{3+}$. (a) What is common in them? (b) Arrange them in the orde…Preview
  13. 3.13Explain why cations are smaller and anions larger in radii than their parent atoms?Preview
  14. 3.14What is the significance of the terms — 'isolated gaseous atom' and 'ground state' while defining the ionization enthalpy and electron gain…Preview
  15. 3.15Energy of an electron in the ground state of the hydrogen atom is $-2.18 \times 10^{-18}$ J. Calculate the ionization enthalpy of atomic hyd…Preview
  16. 3.16Among the second period elements the actual ionization enthalpies are in the order Li < B < Be < C < O < N < F < Ne. Explain why (i) Be has…Preview
  17. 3.17How would you explain the fact that the first ionization enthalpy of sodium is lower than that of magnesium but its second ionization enthal…Preview
  18. 3.18What are the various factors due to which the ionization enthalpy of the main group elements tends to decrease down a group?Preview
  19. 3.19The first ionization enthalpy values (in kJ mol$^{-1}$) of group 13 elements are: B 801, Al 577, Ga 579, In 558, Tl 589. How would you expla…Preview
  20. 3.20Which of the following pairs of elements would have a more negative electron gain enthalpy? (i) O or F (ii) F or ClPreview
  21. 3.21Would you expect the second electron gain enthalpy of O as positive, more negative or less negative than the first? Justify your answer.Preview
  22. 3.22What is the basic difference between the terms electron gain enthalpy and electronegativity?Preview
  23. 3.23How would you react to the statement that the electronegativity of N on Pauling scale is 3.0 in all the nitrogen compounds?Preview
  24. 3.24Describe the theory associated with the radius of an atom as it (a) gains an electron (b) loses an electron.Preview
  25. 3.25Would you expect the first ionization enthalpies for two isotopes of the same element to be the same or different? Justify your answer.Preview
  26. 3.26What are the major differences between metals and non-metals?Preview
  27. 3.27Use the periodic table to answer the following questions. (a) Identify an element with five electrons in the outer subshell. (b) Identify an…Preview
  28. 3.28The increasing order of reactivity among group 1 elements is Li < Na < K < Rb < Cs whereas that among group 17 elements is F > Cl > Br > I.…Preview
  29. 3.29Write the general outer electronic configuration of s-, p-, d- and f-block elements.Preview
  30. 3.30Assign the position of the element having outer electronic configuration (i) $ns^2 np^4$ for $n=3$ (ii) $(n-1)d^2 ns^2$ for $n=4$, and (iii)…Preview
  31. 3.31The first ($\Delta_i H_1$) and the second ($\Delta_i H_2$) ionization enthalpies (in kJ mol$^{-1}$) and the ($\Delta_{eg}H$) electron gain e…Preview
  32. 3.32Predict the formulas of the stable binary compounds that would be formed by the combination of the following pairs of elements. (a) Lithium…Preview
  33. 3.33In the modern periodic table, the period indicates the value of: (a) atomic number (b) atomic mass (c) principal quantum number (d) azimutha…Preview
  34. 3.34Which of the following statements related to the modern periodic table is incorrect? (a) The p-block has 6 columns, because a maximum of 6 e…Preview
  35. 3.35Anything that influences the valence electrons will affect the chemistry of the element. Which one of the following factors does not affect…Preview
  36. 3.36The size of isoelectronic species — $F^-$, Ne and $Na^+$ is affected by (a) nuclear charge (Z) (b) valence principal quantum number (n) (c)…Preview
  37. 3.37Which one of the following statements is incorrect in relation to ionization enthalpy? (a) Ionization enthalpy increases for each successive…Preview
  38. 3.38Considering the elements B, Al, Mg, and K, the correct order of their metallic character is: (a) B > Al > Mg > K (b) Al > Mg > B > K (c) Mg…Preview
  39. 3.39Considering the elements B, C, N, F, and Si, the correct order of their non-metallic character is: (a) B > C > Si > N > F (b) Si > C > B > N…Preview
  40. 3.40Considering the elements F, Cl, O and N, the correct order of their chemical reactivity in terms of oxidizing property is: (a) F > Cl > O >…Preview

Exemplar Problems

Higher-order thinking / exemplar-style practice problems.

+Show 59 questions59 questions
  1. Q1Consider the isoelectronic species, Na^+, Mg^2+, F^- and O^2-. The correct order of increasing length of their radii is _________. (i) F^- <…Free
  2. Q2Which of the following is not an actinoid? (i) Curium (Z = 96) (ii) Californium (Z = 98) (iii) Uranium (Z = 92) (iv) Terbium (Z = 65)Free
  3. Q3The order of screening effect of electrons of s, p, d and f orbitals of a given shell of an atom on its outer shell electrons is: (i) s > p…Free
  4. Q4The first ionisation enthalpies of Na, Mg, Al and Si are in the order: (i) Na < Mg > Al < Si (ii) Na > Mg > Al > Si (iii) Na < Mg < Al < Si…Preview
  5. Q5The electronic configuration of gadolinium (Atomic number 64) is (i) [Xe] 4f^3 5d^5 6s^2 (ii) [Xe] 4f^7 5d^2 6s^1 (iii) [Xe] 4f^7 5d^1 6s^2…Preview
  6. Q6The statement that is not correct for periodic classification of elements is: (i) The properties of elements are periodic function of their…Preview
  7. Q7Among halogens, the correct order of amount of energy released in electron gain (electron gain enthalpy) is: (i) F > Cl > Br > I (ii) F < Cl…Preview
  8. Q8The period number in the long form of the periodic table is equal to (i) magnetic quantum number of any element of the period. (ii) atomic n…Preview
  9. Q9The elements in which electrons are progressively filled in 4f-orbital are called (i) actinoids (ii) transition elements (iii) lanthanoids (…Preview
  10. Q10Which of the following is the correct order of size of the given species: (i) I > I^- > I^+ (ii) I^+ > I^- > I (iii) I > I^+ > I^- (iv) I^-…Preview
  11. Q11The formation of the oxide ion, O^2- (g), from oxygen atom requires first an exothermic and then an endothermic step as shown below: O (g) +…Preview
  12. Q12Comprehension given below is followed by some multiple choice questions. Each question has one correct option. Choose the correct option. In…Preview
  13. Q13(b) The last element of the p-block in 6th period is represented by the outermost electronic configuration. (i) 7s^2 7p^6 (ii) 5f^14 6d^10 7…Preview
  14. Q14(c) Which of the elements whose atomic numbers are given below, cannot be accommodated in the present set up of the long form of the periodi…Preview
  15. Q15(d) The electronic configuration of the element which is just above the element with atomic number 43 in the same group is ________. (i) 1s^…Preview
  16. Q16(e) The elements with atomic numbers 35, 53 and 85 are all ________. (i) noble gases (ii) halogens (iii) heavy metals (iv) light metalsPreview
  17. Q17Electronic configurations of four elements A, B, C and D are given below: (A) 1s^2 2s^2 2p^6 (B) 1s^2 2s^2 2p^4 (C) 1s^2 2s^2 2p^6 3s^1 (D)…Preview
  18. Q18Which of the following elements can show covalency greater than 4? (Note: more than one of the given options may be correct.) (i) Be (ii) P…Preview
  19. Q19Those elements impart colour to the flame on heating in it, the atoms of which require low energy for the ionisation (i.e., absorb energy in…Preview
  20. Q20Which of the following sequences contain atomic numbers of only representative elements? (Note: more than one of the given options may be co…Preview
  21. Q21Which of the following elements will gain one electron more readily in comparison to other elements of their group? (Note: more than one of…Preview
  22. Q22Which of the following statements are correct? (Note: more than one of the given options may be correct.) (i) Helium has the highest first i…Preview
  23. Q23Which of the following sets contain only isoelectronic ions? (Note: more than one of the given options may be correct.) (i) Zn^2+, Ca^2+, Ga…Preview
  24. Q24In which of the following options order of arrangement does not agree with the variation of property indicated against it? (Note: more than…Preview
  25. Q25Which of the following have no unit? (Note: more than one of the given options may be correct.) (i) Electronegativity (ii) Electron gain ent…Preview
  26. Q26Ionic radii vary in (Note: more than one of the given options may be correct.) (i) inverse proportion to the effective nuclear charge. (ii)…Preview
  27. Q27An element belongs to 3rd period and group-13 of the periodic table. Which of the following properties will be shown by the element? (Note:…Preview
  28. Q28Explain why the electron gain enthalpy of fluorine is less negative than that of chlorine.Preview
  29. Q29All transition elements are d-block elements, but all d-block elements are not transition elements. Explain.Preview
  30. Q30Identify the group and valency of the element having atomic number 119. Also predict the outermost electronic configuration and write the ge…Preview
  31. Q31Ionisation enthalpies of elements of second period are given below: Ionisation enthalpy/ k cal mol$^{-1}$: 520, 899, 801, 1086, 1402, 1314,…Preview
  32. Q32Among the elements B, Al, C and Si, (i) which element has the highest first ionisation enthalpy? (ii) which element has the most metallic ch…Preview
  33. Q33Write four characteristic properties of p-block elements.Preview
  34. Q34Choose the correct order of atomic radii of fluorine and neon (in pm) out of the options given below and justify your answer. (i) 72, 160 (i…Preview
  35. Q35Illustrate by taking examples of transition elements and non-transition elements that oxidation states of elements are largely based on elec…Preview
  36. Q36Nitrogen has positive electron gain enthalpy whereas oxygen has negative. However, oxygen has lower ionisation enthalpy than nitrogen. Expla…Preview
  37. Q37First member of each group of representative elements (i.e., s and p-block elements) shows anomalous behaviour. Illustrate with two examples…Preview
  38. Q38p-Block elements form acidic, basic and amphoteric oxides. Explain each property by giving two examples and also write the reactions of thes…Preview
  39. Q39How would you explain the fact that first ionisation enthalpy of sodium is lower than that of magnesium but its second ionisation enthalpy i…Preview
  40. Q40What do you understand by exothermic reaction and endothermic reaction? Give one example of each type.Preview
  41. Q41Arrange the elements N, P, O and S in the order of- (i) increasing first ionisation enthalpy. (ii) increasing non metallic character. Give r…Preview
  42. Q42Explain the deviation in ionisation enthalpy of some elements from the general trend by using Fig. 3.2. ![Complete labelled graph of first i…Preview
  43. Q43Explain the following: (a) Electronegativity of elements increase on moving from left to right in the periodic table. (b) Ionisation enthalp…Preview
  44. Q44How does the metallic and non metallic character vary on moving from left to right in a period?Preview
  45. Q45The radius of Na^+ cation is less than that of Na atom. Give reason.Preview
  46. Q46Among alkali metals which element do you expect to be least electronegative and why?Preview
  47. Q47Match the correct atomic radius with the element. Element | Atomic radius (pm) Be | 74 C | 88 O | 111 B | 77 N | 66Preview
  48. Q48Match the correct ionisation enthalpies and electron gain enthalpies of the following elements. Elements: (i) Most reactive non metal (ii) M…Preview
  49. Q49Electronic configuration of some elements is given in Column I and their electron gain enthalpies are given in Column II. Match the electron…Preview
  50. Q50Assertion (A): Generally, ionisation enthalpy increases from left to right in a period. Reason (R): When successive electrons are added to t…Preview
  51. Q51Assertion (A): Boron has a smaller first ionisation enthalpy than beryllium. Reason (R): The penetration of a 2s electron to the nucleus is…Preview
  52. Q52Assertion (A): Electron gain enthalpy becomes less negative as we go down a group. Reason (R): Size of the atom increases on going down the…Preview
  53. Q53Discuss the factors affecting electron gain enthalpy and the trend in its variation in the periodic table.Preview
  54. Q54Define ionisation enthalpy. Discuss the factors affecting ionisation enthalpy of the elements and its trends in the periodic table.Preview
  55. Q55Justify the given statement with suitable examples— "the Properties of the elements are a periodic function of their atomic numbers".Preview
  56. Q56Write down the outermost electronic configuration of alkali metals. How will you justify their placement in group 1 of the periodic table?Preview
  57. Q57Write the drawbacks in Mendeleev's periodic table that led to its modification.Preview
  58. Q58In what manner is the long form of periodic table better than Mendeleev's periodic table? Explain with examples.Preview
  59. Q59Discuss and compare the trend in ionisation enthalpy of the elements of group 1 with those of group 17 elements.Preview