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Q.Explain the following:

(i) Why is the atomic size of noble gases comparatively larger?
(ii) Being almost equal in electronegativity, Nitrogen forms hydrogen bond while chlorine does not.
Uttar Pradesh UpmspUP Board (UPMSP) Intermediate 2023Subjective· 2mImportance★★★★★
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Noble gases show larger atomic radii because their radius is measured as a van der Waals (non-bonded) radius; nitrogen forms hydrogen bonds while chlorine (of similar electronegativity) does not because nitrogen is a much smaller atom with a compact, high-charge-density lone pair.

(i) Larger atomic size of noble gases: Noble gases are monatomic and do not form covalent bonds, so their atomic radius cannot be a covalent radius. It is instead the van der Waals radius, which is measured up to the point of closest non-bonded approach and is always larger than a covalent radius. Since the radii of neighbouring elements are quoted as covalent radii, the noble gases appear to have anomalously large atomic sizes.

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