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Q.Write the name of different serieses of emission spectrum of Hydrogen and represent them by the formulae.

Uttarakhand UbseUttarakhand Board Intermediate (Class 12) 2018Subjective· 3mImportance★★★★★
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Hydrogen spectral series: Lyman (n1=1n_1=1), Balmer (n1=2n_1=2), Paschen (n1=3n_1=3), Brackett (n1=4n_1=4), Pfund (n1=5n_1=5), all from 1λ=R(1n12−1n22)\frac1\lambda=R\left(\frac{1}{n_1^2}-\frac{1}{n_2^2}\right).

Concept. When electrons in excited hydrogen atoms fall to lower orbits they emit photons; the wavelengths group into distinct series according to the final orbit n1n_1. All are described by the Rydberg formula

1λ=R(1n12−1n22),n2>n1, R=1.097×107 m−1\frac{1}{\lambda} = R\left(\frac{1}{n_1^{2}} - \frac{1}{n_2^{2}}\right),\quad n_2>n_1,\ R=1.097\times10^{7}\,\text{m}^{-1}

The series.

  1. Lyman series — transitions to n1=1n_1=1, from n2=2,3,4,…n_2=2,3,4,\dots; lies in the ultraviolet. 1λ=R(112−1n22)\frac{1}{\lambda}=R\left(\frac{1}{1^{2}}-\frac{1}{n_2^{2}}\right)
  2. Balmer series — n1=2n_1=2, n2=3,4,5,…n_2=3,4,5,\dots; lies in the visible region. 1λ=R(122−1n22)\frac{1}{\lambda}=R\left(\frac{1}{2^{2}}-\frac{1}{n_2^{2}}\right)
  3. Paschen series — n1=3n_1=3, n2=4,5,…n_2=4,5,\dots; infrared. 1λ=R(132−1n22)\frac{1}{\lambda}=R\left(\frac{1}{3^{2}}-\frac{1}{n_2^{2}}\right) …

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