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NCERT Exemplar · Q36

Q.Match the following:

(i) 88 g of CO2CO_2
(ii) 6.022×10236.022 \times 10^{23} molecules of H2OH_2O
(iii) 5.6 litres of O2O_2 at STP
(iv) 96 g of O2O_2
(v) 1 mol of any gas
with
(a) 0.25 mol
(b) 2 mol
(c) 1 mol
(d) 6.022×10236.022 \times 10^{23} molecules
(e) 3 mol
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This matching problem is about converting mass, number of molecules, and volume at STP into moles, then pairing equal quantities. The correct matches are: (i)→(b), (ii)→(c), (iii)→(a), (iv)→(e), (v)→(d).

The entire exercise hinges on one idea: mole is the bridge between mass, number of particles, and gas volume. Once you convert every given quantity into moles, matching becomes trivial — you're just pairing equal numbers.

Let’s go through each item one by one.


  1. (i) 88 g of CO₂

    Molar mass of CO₂ = 12+2×16=4412 + 2 \times 16 = 44 g/mol.

    Moles = 8844=2\frac{88}{44} = 2 mol.

    So (i) matches with (b) 2 mol.

  2. (ii) 6.022×10236.022 \times 10^{23} molecules of H₂O

    That number is Avogadro’s constant — exactly 1 mole of anything.

    So (ii) matches with (c) 1 mol.

  3. (iii) 5.6 litres of O₂ at STP

    At STP, 1 mole of any gas occupies 22.4 L.

    Moles = 5.622.4=0.25\frac{5.6}{22.4} = 0.25 mol.

    So (iii) matches with (a) 0.25 mol.

  4. (iv) 96 g of O₂

    Molar mass of O₂ = 2×16=322 \times 16 = 32 g/mol.

    Moles = 9632=3\frac{96}{32} = 3 mol.

    So (iv) matches with (e) 3 mol.

  5. (v) 1 mol of any gas

    By definition, 1 mole of any substance contains 6.022×10236.022 \times 10^{23} particles.

    So (v) matches with (d) 6.022×10236.022 \times 10^{23} molecules. …

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