Q.An atom having atomic mass number 13 has 7 neutrons. What is the atomic number of the atom?
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Atomic Notation: The ID Card of an Atom
Imagine you're at a huge stadium filled with people. To identify any one person, you'd need more than just a name — you'd need their jersey number, their team, maybe their position. An atom is the same way. Just saying "carbon" or "oxygen" tells you the kind of atom, but not the full story. Atomic notation is the shorthand that gives you the complete identity.
The Intuition: Three Numbers, One Symbol
Every atom is built from three key particles:
- Protons (positive charge) — these define what element it is.
- Neutrons (no charge) — these add mass and stability.
- Electrons (negative charge) — these orbit the nucleus and determine chemical behaviour.
Atomic notation packs all this information around the element's symbol. Think of it as a label with two numbers attached:
ZAX
Where:
- X is the element symbol (e.g., C for carbon, O for oxygen).
- Z is the atomic number (number of protons).
- A is the mass number (protons + neutrons).
The atomic number Z is what makes an atom that element. Change Z, and you change the element entirely. Carbon always has Z=6; if you change it to 7, it's nitrogen.
The Precise Statement
For any atom represented as ZAX:
- Atomic number Z = number of protons = number of electrons (in a neutral atom).
- Mass number A = number of protons + number of neutrons.
- Number of neutrons N=A−Z.
A neutral atom has equal protons and electrons. If the atom gains or loses electrons, it becomes an ion — but the notation for the nucleus stays the same.
Example: Carbon-12
The most common carbon atom is written as:
612C
From this:
- Z=6 → 6 protons, and in a neutral atom, 6 electrons.
- A=12 → total nucleons (protons + neutrons) = 12.
- Neutrons N=12−6=6.
Why Two Numbers? Why Not Just One?
If you only knew the mass number A, you wouldn't know the element — because different elements can have the same mass number (e.g., 14C and 14N both have A=14). If you only knew the atomic number Z, you wouldn't know how many neutrons are present — and that matters for isotopes.
Isotopes are atoms of the same element (same Z) with different numbers of neutrons (different A). For example:
- 612C (6 neutrons)
- 613C (7 neutrons)
- 614C (8 neutrons) All are carbon, but they have different masses and some are radioactive.
A Quick Table for Clarity
| Notation | Element | Protons (Z) | Neutrons (N) | Mass Number (A) |
|---|---|---|---|---|
| 11H | Hydrogen | 1 | 0 | 1 |
| 24He | Helium | 2 | 2 | 4 |
| 1123Na | Sodium | 11 | 12 | 23 |
Concept: Atomic Notation
The mass number A of an atom equals the total number of nucleons (protons + neutrons) in its nucleus. The atomic number Z counts only the protons, which defines the element's identity.
The relationship is:
A=Z+N
where N is the number of neutrons. …
Atomic number equals the number of protons, which we find by subtracting neutrons from the mass number: 13−7=6.
Understanding Atomic Notation
Every atom is built from three particles: protons, neutrons, and electrons. The atomic number Z counts the protons in the nucleus and defines the element's identity. The mass number A is the total count of nucleons—protons plus neutrons—in the nucleus. Electrons contribute negligibly to mass, so they don't appear in A.
The relationship connecting these quantities is straightforward:
A=Z+N
where N is the number of neutrons. This equation captures the fact that the nucleus's mass comes entirely from its protons and neutrons.
A=Z+N
Mass number = Atomic number + Number of neutrons
Finding the Atomic Number
We're given two pieces of information about this atom:
- Mass number A=13
- Number of neutrons N=7
We need to find the atomic number Z.
-
Write down the fundamental relation.
Start with A=Z+N.
-
Substitute the known values.
13=Z+7
- Solve for the atomic number. …
- AP EAPCET 2026Set eng-2026-05-18-AN1 markMCQQ.The total number of electrons, protons and neutrons present in the three isotopes of hydrogen is (A) 3 (B) 5 (C) 6 (D) 9
›Reveal solutionSolution
Add up protons + electrons + neutrons for protium, deuterium, and tritium separately, then sum all three totals to get 9.
Concept and Intuition
All three isotopes of hydrogen have the same atomic number (1 proton, 1 electron in the neutral atom) but differ in neutron number: protium has none, deuterium has one, and tritium has two. Summing every subatomic particle across all three isotopes is a simple counting exercise once the neutron counts are known.
Step-by-Step Solution
- Protium (11H): 1 proton + 1 electron + 0 neutrons = 2.
- Deuterium (12H): 1 proton + 1 electron + 1 neutron = 3.
- Tritium (13H): 1 proton + 1 electron + 2 neutrons = 4. …
- AP EAPCET 2023Set ap-2023-05-22-AN1 markMCQQ.Which of the following contains 10 electrons, 11 protons and 12 neutrons? (A) 23Na+ (B) 23Na (C) 22Na (D) 20Ne+
›Reveal solutionSolution
11 protons fixes the element as sodium; 12 neutrons gives mass number 23; 10 electrons (one fewer than protons) means it's the +1 cation, Na⁺.
Concept and Intuition
The number of protons defines the element (atomic number Z). The mass number A=Z+ neutrons. If the number of electrons differs from the number of protons, the species is an ion, with charge =(protons)−(electrons).
Step-by-Step Solution
- Protons =11⇒ element is sodium (Na, Z=11).
- Mass number A= protons + neutrons =11+12=23.
- Electrons =10, protons =11: charge =+1 (11 positive charges, 10 negative charges).
- So the species is 23Na+.
Common Mistakes …
- AP EAPCET 2022Set ap-2022-07-11-AN1 markMCQQ.Identify the group number of the element X which has 1.44% more number of neutrons than the protons. (Mass number of X is 127) (A) group 15 (B) group 16 (C) group 17 (D) group 14
›Reveal solutionSolution
Solving Z+1.44Z=127 for the proton count gives Z≈52 (with N=75, matching the stated neutron-proton relationship almost exactly), placing element X in group 16.
Concept and Intuition
For a nuclide of known mass number A=N+Z, if the neutron count is a known multiple/percentage-relation of the proton count, the two can be combined into a single equation in one unknown (Z), pinning down the element uniquely from the periodic table, and hence its period and group.
Step-by-Step Solution
- Let Z = number of protons, N = number of neutrons, with N≈1.44Z (neutrons in a 1.44 : 1 relation to protons) and N+Z=127.
- Substitute: Z+1.44Z=127⇒2.44Z=127⇒Z≈52.05, so Z=52.
- Check: N=127−52=75, and 75/52=1.442, consistent with the given relation.
- Atomic number 52 corresponds to tellurium (Te), a p-block element. …
- AP EAPCET 2022Set ap-2022-07-12-AN1 markMCQQ.Which of the following statement is correct about the isotopes of hydrogen? (A) Internuclear distance in hydrogen and deuterium is same (B) Enthalpy of bond dissociation of deuterium is less than hydrogen. (C) Order of relative abundance of isotopes is H > T > D (D) Ratio of neutrons to protons is greater for D than T.
›Reveal solutionSolution
Bond length is set by electron distribution, not nuclear mass, so H₂ and D₂ have essentially the same internuclear distance — making (A) the only correct statement.
Concept and Intuition
Isotopes have identical electron configurations and hence nearly identical chemical/bonding behavior (bond lengths depend on electronic structure). However, the heavier isotope's nucleus has lower zero-point vibrational energy (due to larger reduced mass), making its bond dissociation enthalpy slightly higher, not lower — a classic isotope effect that trips up statement (B).
Step-by-Step Solution
- (A): Bond length in a diatomic molecule depends on the electron cloud/orbital overlap, which is essentially unchanged by isotopic substitution (protons, deuterons and tritons have the same charge and nearly the same electronic environment). So r(H2)≈r(D2). TRUE.
- (B): Because D is heavier, its zero-point energy is lower, meaning MORE energy is needed to dissociate it — so BDE(D₂) > BDE(H₂), making the statement ("enthalpy of D is less than H") FALSE.
- (C): Natural abundance is H (99.98%) ≫ D (0.02%) ≫ T (trace, radioactive), so the correct order is H > D > T, not H > T > D. FALSE. …
- AP EAPCET 2022Set eng-2022-07-07-FN1 markMCQQ.The two stable isotopes of carbon present in the naturally occurring carbon are (A) 12C and 14C (B) 12C and 13C (C) 12C and 15C (D) 11C and 12C
›Reveal solutionSolution
Natural carbon's two stable isotopes are 12C and 13C; 14C, though naturally occurring in trace amounts, is radioactive, not stable.
Concept and Intuition
Isotopes of an element share the same atomic number but differ in mass number (neutron count). Naturally occurring carbon is a mixture of isotopes, but only two of them are stable indefinitely — the rest, like 14C, undergo radioactive decay (in 14C's case, this decay is the basis of radiocarbon dating).
Step-by-Step Solution
- Carbon's naturally occurring isotopes include 12C, 13C, and trace 14C.
- 12C (about 98.9% abundance) and 13C (about 1.1% abundance) are both stable (non-radioactive).
- 14C is present only in trace amounts and is radioactive, decaying via beta emission with a half-life of about 5730 years — it is not classified as "stable." …
- AP EAPCET 2021Set ap-2021-09-03-AN1 markMCQQ.The electronic configuration of a transition element X in +3 state is [Ar]3d6. Its atomic number is ______ (A) 26 (B) 24 (C) 27 (D) 28
›Reveal solutionSolution
X3+=[Ar]3d6 has 24 electrons, so the atomic number of X is 27.
Concept and Intuition
The electronic configuration of an ion tells us its electron count directly. A +3 charge means three electrons were lost relative to the neutral atom, so the atomic number equals the ion's electron count plus 3.
Step-by-Step Solution
- Argon core [Ar] has 18 electrons.
- [Ar]3d6 therefore has 18+6=24 electrons — this is X3+.
- Since X3+ lost 3 electrons, neutral X has 24+3=27 electrons.
- Atomic number Z=27, which is cobalt (Co).
Common Mistakes
- Forgetting to add back the 3 lost electrons and reporting 24 (option B is 24). …
- AP EAPCET 2021Set eng-2021-08-20-FN1 markMCQQ.The number of protons, neutrons and electrons in 613C respectively are ____ (A) 6, 7, 6 (B) 13, 6, 6 (C) 6, 7, 13 (D) 6, 6, 13
›Reveal solutionSolution
This tests basic nuclear notation ZAX: protons =Z, neutrons =A−Z, electrons =Z for a neutral atom — giving 6, 7, 6 for 613C — answer (A).
Concept and Intuition
In the notation ZAX, the subscript Z (atomic number) is the number of protons, which also equals the number of electrons in a neutral atom, and the superscript A (mass number) is the total number of nucleons (protons + neutrons). So neutrons are simply obtained by subtracting protons from the mass number.
Step-by-Step Solution
- From 613C: Z=6 (atomic number), A=13 (mass number).
- Protons =Z=6.
- Electrons (neutral atom) =Z=6. …
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