Q.An electron (mass m) with an initial velocity v=v0i^ is in an electric field E=E0j^. If λ0=h/mv0, its de Broglie wavelength at time t is given by
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De Broglie Wavelength: When Particles Start Acting Like Waves
Imagine you're holding a cricket ball. You know exactly where it is, and if you throw it, you can predict its path. That's a particle — localised, definite, following Newton's laws. Now think of light. You can't "hold" a beam of light; it spreads out, bends around corners, creates interference patterns. That's a wave — spread out, not localised.
For centuries, physics kept these two worlds separate. Particles were particles. Waves were waves. Never the twain shall meet.
Then came a young French physicist, Louis de Broglie, in 1924. He asked a question that seemed almost absurd: If light — which we thought was a wave — can behave like a particle (the photoelectric effect), then why can't a particle — say, an electron — behave like a wave?
That question turned physics upside down.
The Core Idea
De Broglie proposed that every moving particle has a wave associated with it. The wavelength of that wave depends on the particle's momentum. The faster or heavier the particle, the shorter the wavelength.
λ=ph=mvh
Where:
- λ = de Broglie wavelength (in metres)
- h = Planck's constant (6.626×10−34 J⋅s)
- p = momentum of the particle (mv for non-relativistic speeds)
This is not a mathematical trick. It's a physical reality. An electron moving through a crystal actually behaves like a wave of this wavelength — it can diffract, interfere, and form patterns just like light does.
Why You Don't See It in Daily Life
Here's the crucial point: the de Broglie wavelength is incredibly tiny for everyday objects.
Take a cricket ball of mass 0.16 kg moving at 30 m/s. Its de Broglie wavelength is:
λ=0.16×306.626×10−34≈1.38×10−34 m
That's about a hundred trillion trillion times smaller than the nucleus of an atom. No experiment can detect such a wave — it's effectively zero for all practical purposes.
Now take an electron (mass 9.1×10−31 kg) accelerated through 100 volts. Its speed is about 5.9×106 m/s. Its de Broglie wavelength:
λ=9.1×10−31×5.9×1066.626×10−34≈1.23×10−10 m
That's about 0.12 nanometres — comparable to the spacing between atoms in a crystal. This is measurable. And indeed, in 1927, Davisson and Germer fired electrons at a nickel crystal and observed diffraction — the unmistakable signature of a wave.
The de Broglie wavelength is only observable when it is comparable to the size of objects the particle interacts with. For macroscopic objects, it's far too small to matter. For subatomic particles, it's the key to understanding their behaviour.
What This Means Physically
The wave is not a physical wave in space like a water wave. It's a probability wave — its amplitude at any point tells you the probability of finding the particle there. Where the wave amplitude is large, you're likely to find the particle; where it's zero, you won't.
This wave-particle duality is not a compromise. It's the actual nature of reality. An electron is neither a pure particle nor a pure wave — it's something that shows particle-like behaviour in some experiments (like hitting a screen at a point) and wave-like behaviour in others (like passing through two slits and interfering with itself). …
Why this formula?
De Broglie Wavelength: Why the Formula Holds
Let's build this from the ground up — understanding why matter has a wavelength, not just memorizing λ=ph.
The Core Insight: Nature's Symmetry
Before de Broglie, physics had two separate worlds:
- Light — showed wave behaviour (diffraction, interference) but also particle behaviour (photoelectric effect)
- Matter — showed particle behaviour (momentum, collisions) but no wave behaviour yet
De Broglie asked a daring question in his 1924 PhD thesis:
If light (a wave) can behave like a particle, why can't a particle (like an electron) behave like a wave?
Nature should be symmetric — what applies to one should apply to the other.
Step 1: Start with Light (What We Already Knew)
For a photon, Einstein had given us two key relations:
- Energy: E=hf (Planck's relation)
- Momentum: p=λh (from E=pc for light, combined with c=fλ)
So for light:
λ=ph
This was experimentally verified for photons.
Step 2: De Broglie's Bold Hypothesis
De Broglie said: This relation is not special to light. It is universal.
For any particle with momentum p:
λ=ph
Where:
- λ = de Broglie wavelength
- h = Planck's constant (6.626×10−34 J⋅s)
- p = momentum of the particle
Step 3: Why Momentum and Not Velocity?
This is crucial. The formula uses momentum (p=mv), not just velocity.
For a non-relativistic particle (slow compared to light):
λ=mvh
For a relativistic particle (like an electron at high speed):
p=γmvwhereγ=1−v2/c21
λ=γmvh
Why momentum? Because momentum is the more fundamental quantity — it's conserved, it's frame-independent in a deeper sense, and it connects directly to the wave's phase.
Step 4: The Deeper Reasoning — Wave-Particle Duality
De Broglie didn't just guess. He reasoned:
- Every moving particle has an associated wave — called the "matter wave" or "pilot wave"
- The frequency of this wave comes from energy: f=hE
- The wavelength comes from momentum: λ=ph
These two relations are linked by the phase velocity of the wave:
vphase=fλ=hE⋅ph=pE
For a free particle with kinetic energy E=2mp2:
vphase=2mp=2v
This is half the particle's speed — a strange but mathematically consistent result.
Step 5: Experimental Confirmation (Why We Believe It)
De Broglie's idea was confirmed when electrons showed wave behaviour: …
The electron (charge −e) in field E=E0j^ feels force F=−eE0j^, giving vy(t)=−meE0t while vx=v0 stays fixed.
- Speed: v(t)=v02+(meE0t)2=v01+m2v02e2E02t2.
- De Broglie wavelength: λ(t)=mv(t)h=1+m2v02e2E02t2λ0, using λ0=h/mv0. …
The electron's charge is −e, so the field E=E0j^ pushes it in the −j^ direction, building up a growing y-component of velocity. Its speed - and hence its de Broglie wavelength - changes with time as λ(t)=1+m2v02e2E02t2λ0, matching option (C).
Setting up the motion
The electron has charge −e (with e>0 the elementary charge) and starts with velocity v(0)=v0i^. In the field E=E0j^, the force on it is
F=(−e)E=−eE0j^,
so the acceleration is a=−meE0j^ - the electron is pushed in the −j^ direction (opposite to E, since the charge is negative).
Velocity at time t
No force acts along i^, so vx(t)=v0 stays constant. Along j^:
vy(t)=−meE0t.
Speed (magnitude of velocity)
v(t)=vx2+vy2=v02+(meE0t)2.
(Note that the sign of vy doesn't matter here - only vy2 enters the speed, so whether the force pushes the electron in +j^ or −j^, the final speed formula is identical. What matters for correctness is simply using the electron's true charge, −e, in setting up the force in the first place.)
De Broglie wavelength …
Method: Finding λ(t) When a Force Acts Perpendicular to the Initial Velocity
This is the companion method to the collinear-force case: here the force adds a new component of velocity at right angles to the original one, so you must combine components as vectors rather than just adding magnitudes.
Steps
Step 1: Split the motion into two independent directions
Along the original velocity direction, no force acts, so that component of velocity is unchanged: v∥(t)=v0. Along the direction of the force, the particle starts from rest (in that direction) and accelerates uniformly.
Step 2: Find the growing component from the force, with the correct sign of charge
v⊥(t)=m∣q∣E0t
using the particle's actual charge to get the force direction — though note the magnitude of the final speed won't depend on that sign, since only v⊥2 ever enters.
Step 3: Combine the components as a vector magnitude, not a sum
Because the two velocity components are perpendicular, the speed is
v(t)=v∥2+v⊥2=v01+(v0v⊥(t))2 …
- AHSEC Higher Secondary (HS) Final Examination 2023Set ANNUAL1 markMCQQ.If λp and λα be the wavelength of de Broglie waves for a proton and an alpha particle then which of the following is correct? (Choose the correct option)(i) λp = λα(ii) λp > λα(iii) λp < λα
›Reveal solutionSolution
When accelerated through the same potential difference, the de Broglie wavelength of a proton is larger than that of an alpha particle, i.e. λp > λα.
The de Broglie wavelength of a particle of charge q and mass m, accelerated from rest through potential difference V, is λ = h/p = h/√(2mqV) (since qV = ½mv² = p²/2m).
For a proton: mass mp, charge e: λp = h/√(2mp·e·V).
For an alpha particle: mass ≈ 4mp, charge 2e: λα = h/√(2·4mp·2e·V) = h/√(16mp·e·V).
Taking the ratio: λp/λα = √(16mp·e·V / 2mp·e·V) = √8 ≈ 2.83.
…
- AHSEC Higher Secondary (HS) Final Examination 2022Set ANNUAL1 markQ.de Broglie in 1924 reasoned that nature was symmetrical and that the two basic physical entities ___ and ___ must have symmetrical character. (Fill in the blanks)
›Reveal solutionSolution
De Broglie argued that since radiation (energy) shows dual particle-wave behaviour, matter should too, by symmetry of nature.
By 1924, it was firmly established that radiation (light) has a dual character — behaving as a wave in phenomena like interference and diffraction, and as a particle (photon) in phenomena like the photoelectric effect and Compton effect.
Louis de Broglie extended this idea by a bold hypothesis: nature loves symmetry, and if radiation (energy) can behave as both wave and particle, then matter (which was until then thought of only as particles) should also possess an associated wave character under suitable conditions. He proposed that the two basic physical entities of nature — matter and energy/radiation — must ha …
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