Q.What is heavy water? Describe the methods of preparation.
You're viewing a preview — the full solution, concept, methods & PYQ mapping are locked.
Start your 14-day free trial to unlock the full solution →Heavy water = D₂O (deuterium oxide); it is prepared mainly by prolonged electrolysis of water (D₂O concentrates in the residue) and by fractional distillation/exchange.
From NCERT Class 11 Chemistry (Hydrogen):
What is heavy water?
Heavy water is deuterium oxide, D₂O, in which each ordinary hydrogen atom (protium, ¹H) of water is replaced by its heavier isotope deuterium (²H or D). Ordinary water contains about 1 part of D₂O in ~6000 parts of H₂O. D₂O has a higher density (1.10 g/cm³), higher boiling point (101.4 °C) and higher freezing point (3.8 °C) than ordinary water. It is used as a moderator in nuclear reactors and as a source of deuterium.
Methods of preparation:
-
By prolonged (exhaustive) electrolysis of water:
When ordinary water containing a little alkali (e.g. NaOH) is electrolysed for a long time, ordinary water (H₂O) is decomposed faster than heavy water (D₂O), because the O–H bond breaks more easily than the O–D bond. As electrolysis continues, the residual liquid becomes richer in D₂O. Starting from a large volume and reducing it in successive stages, almost pure D₂O is finally obtained in the residue.
-
By fractional distillation of water: …
Unlock everything free for 14 days
- Full step-by-step solutions
- Concept-first explanations
- Methods, shortcuts & mistakes
- PYQ mapping + timed mock tests
Full access for 14 days. No credit card required.