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Question of 46

Q.Complete the following reaction :

(a) Al + NaOH + H_2O --boil-->
(b) Al_4C_3 + H_2O →
Bihar BsebBihar Board Intermediate 1st Year 2023Subjective· 2mImportance★★★★★
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(a) Al + NaOH gives sodium aluminate + H2; (b) Al4C3 + water gives Al(OH)3 + methane.

(a) Aluminium is amphoteric; on boiling with sodium hydroxide solution it dissolves, liberating hydrogen gas and forming sodium meta-aluminate:

2Al + 2NaOH + 2H2O -> 2NaAlO2 + 3H2 (up)

(b) Aluminium carbide is a methanide; it is hydrolysed by water to give aluminium hydroxide and methane:

Al4C3 + 12H2O -> 4Al(OH)3 + 3CH4 (up)

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