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Example · Example 8

Q.Aluminium is described as an amphoteric metal. Write balanced equations for its reaction with

(a) dilute hydrochloric acid and
(b) aqueous sodium hydroxide, naming the aluminium-containing product in each case.
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Aluminium's amphoteric character means it reacts with both acids and bases, dissolving and liberating hydrogen gas in each case, though forming a different aluminium-containing product depending on which reagent is used. With dilute hydrochloric acid, aluminium is oxidised while H+\text{H}^+ is reduced to H2\text{H}_2, giving aluminium chloride in solution:\n2Al+6HCl⟶2AlCl3+3H22\text{Al} + 6\text{HCl} \longrightarrow 2\text{AlCl}_3 + 3\text{H}_2\nWith aqueous sodium hydroxide, aluminium again dissolves with the liberation of hydrogen gas, but here the aluminium ends up as the aluminate ion rather than a simple chloride salt:\n2Al+2NaOH+2H2O⟶2NaAlO2+3H22\text{Al} + 2\text{NaOH} + 2\text{H}_2\text{O} \longrightarrow 2\text{NaAlO}_2 + 3\text{H}_2\n(the aluminate can equally be written as the hydrated complex Na[Al(OH)4]\text{Na}[\text{Al(OH)}_4], obtained by writing the reaction with one extra equivalent of water per aluminium: 2Al+2NaOH+6H2O→2Na[Al(OH)4]+3H22\text{Al}+2\text{NaOH}+6\text{H}_2\text{O}\rightarrow 2\text{Na}[\text{Al(OH)}_4]+3\text{H}_2). In ordinary conditions, aluminium metal is protected by an extremely thin, tough, self-healing oxide lay …

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