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Intext · Q4

Q.Write the chemical equation for preparing sodium soap from glyceryl oleate and glyceryl palmitate. Structural formulae of these compounds are given below.

(i) (C15H31COO)3C3H5 – Glyceryl palmitate
(ii) (C17H32COO)3C3H5 – Glyceryl oleate
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Soaps are prepared by the alkaline hydrolysis of fats and oils, which are esters of glycerol with long-chain fatty acids — this reaction is called saponification. Each glyceryl ester has three ester linkages, so it reacts with 3 molecules of NaOH to give 3 molecules of the sodium salt of the fatty acid (soap) and 1 molecule of glycerol.

  • Glyceryl palmitate is the ester of glycerol with palmitic acid (C15H31COOHC_{15}H_{31}COOH):

    (C15H31COO)3C3H5+3NaOH→3C15H31COO−Na++C3H5(OH)3(C_{15}H_{31}COO)_3C_3H_5 + 3NaOH → 3C_{15}H_{31}COO^-Na^+ + C_3H_5(OH)_3

    (glyceryl palmitate) + (sodium hydroxide) → (sodium palmitate, a soap) + (glycerol)

  • Glyceryl oleate is the ester of glycerol with oleic acid. Oleic acid is an unsaturated (mono-unsaturated) fatty acid with the formula C17H33COOHC_{17}H_{33}COOH, so its glyceryl triester is (C17H33COO)3C3H5(C_{17}H_{33}COO)_3C_3H_5: …

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