Chemistry · Ch 5 — Surface Chemistry
Catalysis
5.2
Catalysis
Some substances can dramatically change the speed of a reaction without being consumed. Heating potassium chlorate decomposes it only slowly, over 653–873 K:
Add a little manganese dioxide and the same decomposition runs much faster and at a lower temperature (473–633 K) — yet the comes out unchanged in mass and composition.
The systematic study of such effects was begun by Berzelius in 1835, who coined the term catalyst.
- A catalyst is a substance that accelerates a chemical reaction while itself remaining chemically and quantitatively unchanged afterwards; the phenomenon is catalysis.
Promoters and poisons
- Promoters enhance a catalyst's activity.
- Poisons reduce a catalyst's activity. …