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Q."O3 behaves as a strong oxidising agent." Explain.

Bihar BsebBihar Board Intermediate 2025Subjective· 2mImportance★★★★★
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O3 is a strong oxidant because it easily releases reactive nascent oxygen: O3 -> O2 + [O].

Ozone is thermodynamically unstable with respect to oxygen; its decomposition is exothermic:

2O3 -> 3O2 (ΔH is negative)

During this decomposition each ozone molecule breaks up to give a stable O2 molecule and one atom of nascent (atomic) oxygen:

O3 -> O2 + [O]

The nascent oxygen [O] so produced is extremely reactive and has a strong tendency to combine with (oxidise) other species. Because ozone readily supplies this active oxygen, it behaves as a powerful oxidising agent, stronger than ordinary O2.

Examples of its oxidising action:

  • It oxidises lead sulphide to lead sulphate: PbS + 4O3 -> PbSO4 + 4O2 …

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