Q.In which of the following processes is nitric acid manufactured from ammonia ?

Ammonia and Nitric Acid: From Air to Fertiliser to Explosives

You already know that plants need nitrogen to grow, but the air around us — 78% nitrogen gas — is useless to them in that form. The nitrogen molecule is incredibly stable; two nitrogen atoms triple-bonded together, $N \equiv N$, simply won't react with anything mild. To make nitrogen useful, we must first break that bond and force it to combine with other elements. That is the entire point of ammonia and nitric acid production: we take inert atmospheric nitrogen and turn it into reactive chemical forms that can feed the world or, in the case of nitric acid, make explosives and fertilisers.

Ammonia by the Haber Process

The Haber process is the industrial method for fixing nitrogen — turning $N_2$ from the air into ammonia, $NH_3$. The reaction is deceptively simple:

The hydrogen comes from natural gas (methane) via steam reforming, and the nitrogen is obtained by fractional distillation of liquid air. The challenge is that this reaction is reversible and exothermic — it releases heat. Le Chatelier's principle tells us that low temperature would favour ammonia formation (since the forward reaction is exothermic), but low temperature also makes the reaction painfully slow because breaking that $N \equiv N$ triple bond requires a huge activation energy.

The solution is a compromise: a temperature around 450–500°C, a very high pressure of 150–200 atm, and an iron catalyst (with promoters like $K_2O$ and $Al_2O_3$) to speed things up. Under these conditions, about 15–20% of the reactants convert to ammonia per pass. The unreacted gases are recycled, so overall conversion is nearly 100%.

The ammonia is removed by cooling the gas mixture — ammonia liquefies at about -33°C at atmospheric pressure, while nitrogen and hydrogen remain gases — and the unreacted gases are pumped back into the reactor.

Nitric Acid by the Ostwald Process

Now take that ammonia and oxidise it. That is the Ostwald process: burning ammonia in air over a platinum-rhodium catalyst to produce nitric oxide, which then goes through a series of spontaneous reactions to become nitric acid.

The first step is the catalytic oxidation of ammonia:

This is done at about 900°C and just above atmospheric pressure. The hot gases are then cooled rapidly to prevent the NO from decomposing back. The nitric oxide then reacts with more oxygen from the air to form nitrogen dioxide:

This happens spontaneously as the gases cool. Finally, the nitrogen dioxide is absorbed in water to give nitric acid:

Notice that NO is regenerated in this last step — it gets recycled back to be oxidised again. The overall reaction from ammonia to nitric acid is: …