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NCERT Exemplar · Q10

Q.The relaxation time τ\tau is nearly independent of applied EE field whereas it changes significantly with temperature TT. First fact is (in part) responsible for Ohm's law whereas the second fact leads to variation of ρ\rho with temperature. Elaborate why?

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Drift velocity depends on relaxation time τ\tau and applied field EE; Ohm’s law (J∝EJ \propto E) follows because τ\tau is independent of EE, while resistivity ρ\rho varies with temperature because τ\tau changes significantly with TT due to increased lattice vibrations.

The key to understanding both Ohm’s law and the temperature dependence of resistivity lies in the microscopic picture of electron motion inside a conductor — specifically, the concept of drift velocity and the relaxation time τ\tau.

When no electric field is applied, free electrons in a metal move randomly with high speeds (about 10610^6 m/s at room temperature) but with zero net drift. The average time between successive collisions of an electron with the lattice ions (or other electrons) is called the relaxation time τ\tau. This τ\tau is determined by how often an electron’s path is interrupted — and that depends on the lattice vibrations (phonons) and impurities, not on the applied field.

Now, when a small electric field EE is applied, each electron experiences a constant force F=−eEF = -eE, giving it a small acceleration a=−eE/ma = -eE/m between collisions. But because collisions reset the electron’s velocity randomly, the net effect is a tiny drift velocity superimposed on the random thermal motion.

vd=−eEmτv_d = -\frac{eE}{m} \tau

This is the average velocity an electron gains in the direction opposite to the field. The negative sign just indicates direction — we often write vd=eEmτv_d = \frac{eE}{m}\tau in magnitude.

The current density JJ is then:

J=nevd=ne2τmEJ = n e v_d = \frac{n e^2 \tau}{m} E

where nn is the number density of free electrons. This is Ohm’s law in microscopic form: J=σEJ = \sigma E, with conductivity σ=ne2τm\sigma = \frac{n e^2 \tau}{m}.

Now let’s address the two facts given in the question.

  1. Why τ\tau independent of EE leads to Ohm’s law

    The relaxation time τ\tau depends on the scattering mechanisms in the metal — primarily collisions with vibrating lattice ions. The applied electric field EE (even a strong one, within normal limits) is far too weak to significantly alter the random thermal speeds of electrons. The thermal speed vth≈3kT/mv_{th} \approx \sqrt{3kT/m} is on the order of 10510^5–10610^6 m/s, while the drift speed vdv_d is typically only a few mm/s. So the time between collisions is essentially determined by the thermal motion, not by the tiny drift. Hence τ\tau is independent of EE.

    Because τ\tau does not change with EE, the conductivity σ=ne2τ/m\sigma = n e^2 \tau / m is a constant for a given temperature. Then J=σEJ = \sigma E gives a linear relationship — that is Ohm’s law. If τ\tau depended on EE, the JJ–EE graph would curve, and Ohm’s law would fail.

    Watch out

    A common mistake is to think that vdv_d itself is proportional to EE because of F=maF = ma. That’s true, but the deeper reason Ohm’s law holds is that τ\tau stays constant — otherwise the proportionality constant σ\sigma would change with EE.

  2. Why τ\tau changes with TT leads to variation of ρ\rho with temperature …

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