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Q.In the Lyman series of hydrogen atom, what is the range of maximum and minimum wavelength?

Chhattisgarh CgbseCGBSE Intermediate Board 2022Subjective· 1mImportance★★★★★
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The maximum wavelength corresponds to the n=2→1 transition, and the minimum (series limit) corresponds to n=∞→1.

Using the Rydberg formula for the Lyman series, 1λ=R(1−1n2)\dfrac{1}{\lambda} = R\left(1 - \dfrac{1}{n^2}\right) with R = 1.097 × 10⁷ m⁻¹:

Maximum wavelength occurs for the smallest jump, n = 2 → 1:

1λmax=R(1−14)=3R4\frac{1}{\lambda_{max}} = R\left(1-\frac{1}{4}\right) = \frac{3R}{4}

λmax=43R=43×1.097×107≈1.215×10−7 m=1215 A˚\lambda_{max} = \frac{4}{3R} = \frac{4}{3\times1.097\times10^7} \approx 1.215\times10^{-7}\ \text{m} = 1215\ \text{Å}

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