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NCERT Exemplar · Q25

Q.Two particles A1A_1 and A2A_2 of masses m1,m2m_1, m_2 (m1>m2m_1 > m_2) have the same de Broglie wavelength. Then

(a) their momenta are the same.
(b) their energies are the same.
(c) energy of A1A_1 is less than the energy of A2A_2.
(d) energy of A1A_1 is more than the energy of A2A_2.
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Equal de Broglie wavelength forces equal momentum (p1=p2p_1=p_2), so statement (A) is true; and since E=p2/2mE=p^2/2m at fixed momentum makes E∝1/mE\propto 1/m, the heavier particle A1A_1 has the smaller energy, so statement (C) is also true. Both (A) and (C) are correct.

The link between wavelength and momentum

The de Broglie relation is

λ=hp,\lambda = \frac{h}{p},

which depends only on momentum — mass doesn't appear in it directly. If A1A_1 and A2A_2 share the same wavelength, they must share the same momentum:

λ1=λ2  ⇒  hp1=hp2  ⇒  p1=p2.\lambda_1=\lambda_2 \;\Rightarrow\; \frac{h}{p_1}=\frac{h}{p_2} \;\Rightarrow\; p_1=p_2.

This follows directly from the definition of λ\lambda, not as an approximation or special case. So statement (A), "their momenta are the same," is unambiguously true.

Comparing the energies

For a non-relativistic particle, kinetic energy written in terms of momentum is

E=p22m.E = \frac{p^2}{2m}.

With p1=p2=pp_1=p_2=p,

E1=p22m1,E2=p22m2,E_1 = \frac{p^2}{2m_1}, \qquad E_2 = \frac{p^2}{2m_2},

so at fixed momentum, E∝1/mE \propto 1/m. Because m1>m2m_1 > m_2, the denominator is larger for A1A_1, so

E1<E2.E_1 < E_2. …

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