Q.If the concentration of glucose (C6H12O6) in blood is 0.9 g L−1, what will be the molarity of glucose in blood?
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Molality: The Concentration That Ignores Temperature
Imagine you're making a cup of sweet tea. You add sugar to hot water, stir, and taste. If you let the tea cool to room temperature, the amount of sugar hasn't changed — but the volume of the liquid has shrunk slightly. If you measured concentration as "grams of sugar per litre of solution," that number would change just because the temperature changed. That's annoying if you're a chemist who needs a reliable, temperature-independent way to describe how much solute is present.
Molality was invented to solve exactly this problem.
The Intuition
Instead of measuring the volume of the solution (which expands and contracts with temperature), molality measures the mass of the solvent. Mass doesn't change with temperature. So molality gives you a concentration that stays the same whether your solution is hot or cold.
Think of it this way:
- Molarity = moles of solute per litre of solution (temperature-sensitive)
- Molality = moles of solute per kilogram of solvent (temperature-independent)
The solvent is the substance doing the dissolving — usually water. The solute is what gets dissolved — sugar, salt, etc.
The Precise Definition
Molality (m)=kilograms of solventmoles of solute
The symbol for molality is a lowercase m (not to be confused with M for molarity).
Key points to remember:
- The denominator is solvent mass, not solution mass
- The unit is mol/kg (often written as simply "m")
- It is independent of temperature because mass doesn't change with temperature
Worked Example
Problem: 36 g of glucose (C6H12O6, molar mass = 180 g/mol) is dissolved in 500 g of water. Calculate the molality of the solution.
Step 1: Find moles of solute
Moles of glucose=180 g/mol36 g=0.2 mol
Step 2: Convert solvent mass to kilograms
500 g=0.5 kg
Step 3: Apply the formula
m=0.5 kg0.2 mol=0.4 m
The answer is 0.4 m (or 0.4 mol/kg). Notice we used the mass of water (500 g), not the mass of the solution (which would be 536 g).
Common Mistake to Avoid
Do not use the mass of the solution in the denominator. The formula specifically asks for the mass of the solvent alone. If the problem gives you the total mass of the solution, subtract the mass of the solute to find the solvent mass.
When Do You Use Molality?
Molality is the star in two important situations: …
Why this formula?
Molality Calculation: Why the Formula Works
Molality is a measure of concentration that is temperature-independent — this is its key advantage over molarity. Let's understand why the formula takes the form it does.
The Definition First
Molality (m) is defined as:
m=mass of solvent in kgmoles of solute
The unit is mol/kg, often written as m (e.g., 0.5 m glucose solution).
Why Mass of Solvent, Not Solution?
This is the critical conceptual point.
The Reasoning
- Molarity uses volume of solution → volume changes with temperature (expansion/contraction). So molarity changes with temperature.
- Molality uses mass of solvent → mass is invariant with temperature. So molality remains constant regardless of temperature changes.
Key insight: By using the solvent's mass (not the solution's volume), we eliminate temperature dependence. This is why molality is preferred for colligative properties (boiling point elevation, freezing point depression) — these properties depend on the number of solute particles, not on temperature.
Deriving the Formula Step-by-Step
Step 1: Moles of Solute
If you have wsolute grams of solute with molar mass Msolute (g/mol):
moles of solute=Msolutewsolute
Step 2: Mass of Solvent in kg
If the solvent mass is Wsolvent grams:
mass of solvent in kg=1000Wsolvent
Step 3: Putting It Together
m=1000WsolventMsolutewsolute
Simplifying:
m=Msolute×Wsolventwsolute×1000
The Final Formula (Exam-Ready)
m=Msolute×Wsolventwsolute×1000
Where:
- wsolute = mass of solute in grams
- Msolute = molar mass of solute in g/mol
- Wsolvent = mass of solvent in grams
Why the ×1000 Factor? …
The key idea is molarity calculation: molarity (M) = moles of solute per litre of solution.
Step 1: Find the molar mass of glucose (C6H12O6).
6×12+12×1+6×16=72+12+96=180 g mol−1.
Step 2: Convert the given concentration to moles per litre.
Moles of glucose in 1 L = 180 g mol−10.9 g=0.005 mol. …
Molarity is moles per litre. Given 0.9 g L−1 of glucose (molar mass 180 g mol−1), the molarity is 0.9/180=0.005 M. The correct option is (iii).
The question asks for molarity, not molality — a common point of confusion. Molarity (M) is defined as the number of moles of solute per litre of solution. Here, the concentration is already given in grams per litre (g L−1), which is a mass concentration. Converting that to molarity is straightforward: divide by the molar mass of glucose.
Glucose has the formula C6H12O6. Let’s calculate its molar mass quickly:
- Carbon: 6×12=72
- Hydrogen: 12×1=12
- Oxygen: 6×16=96
- Total: 72+12+96=180 g mol−1
Now, the given mass concentration is 0.9 g L−1. That means every litre of blood contains 0.9 grams of glucose.
-
Find moles of glucose per litre
Moles = mass / molar mass = 0.9 g/180 g mol−1=0.005 mol.
-
Molarity is moles per litre
Since we already have the mass per litre, the moles per litre is exactly 0.005 mol L−1, which is 0.005 M. …
Method: Molarity from Mass Concentration
Concept first: Molarity (M) tells us the number of moles of solute per litre of solution.
We are given mass per litre (0.9 g L−1). To convert to moles per litre, we need the molar mass of glucose.
Steps
Step 1 — Find molar mass of glucose (C6H12O6)
- Carbon: 6×12=72
- Hydrogen: 12×1=12
- Oxygen: 6×16=96
Molar mass = 72+12+96=180 g mol−1
Step 2 — Convert mass concentration to molarity
Molarity (M) = molar mass (g/mol)mass per litre (g/L) …
Step 1: Understand what is being asked
We are given:
- Solute: glucose, C6H12O6
- Concentration: 0.9 g L−1 (mass per volume)
- We need: Molarity (moles per litre)
Molarity =volume of solution in litresmoles of solute
So the first step is to convert grams per litre into moles per litre.
Step 2: Calculate molar mass of glucose
Glucose: C6H12O6
- Carbon: 6×12=72
- Hydrogen: 12×1=12
- Oxygen: 6×16=96
Molar mass =72+12+96=180 g mol−1
Step 3: Convert given concentration to molarity
Given: 0.9 g L−1
Moles per litre =1800.9=0.005 mol L−1
So molarity =0.005 M
Correct answer: (iii) 0.005 M
Common Mistakes & How to Avoid Them
✗ Mistake 1: Confusing molality with molarity
- What students do: They try to use mass of solvent or density, which is not given.
- Why it’s wrong: Molarity uses volume of solution (given as 1 L here). Molality uses mass of solvent (in kg).
- How to avoid: Read the unit carefully — g L−1 is a mass/volume concentration, directly convertible to molarity.
✗ Mistake 2: Forgetting to convert grams to moles
- What students do: They take 0.9 g L−1 and think it’s already moles.
- Why it’s wrong: Molarity is moles per litre, not grams per litre.
- How to avoid: Always ask: “Is this in grams or moles?” If grams, divide by molar mass.
✗ Mistake 3: Incorrect molar mass of glucose
- What students do: Use C6H12O6 as 6+12+6=24 or forget to multiply atomic masses.
- Why it’s wrong: Each element’s atomic mass must be multiplied by its subscript.
- How to avoid: Write out the calculation step-by-step: 6×12=72, 12×1=12, 6×16=96, then sum.
✗ Mistake 4: Decimal error in division
- What students do: 0.9÷180=0.005 but they write 0.05 or 0.5.
- Why it’s wrong: Misplacing the decimal changes the answer by a factor of 10 or 100. …
- GUJCET 2024Set 131 markMCQQ.Calculate the mass of Glucose (C6H12O6) required in making 2.5 kg of 0.25 molal aqueous solution. [Atomic wt : H = 1, O = 16, C = 12 amu] (A) 135.0 g (B) 107.65 g (C) 90.0 g (D) 112.5 g
›Reveal solutionSolution
Molality is moles solute per kg solvent; set up the equation with (solution − solute) as solvent mass and solve for the solute mass.
Concept: Molar mass of glucose C6H12O6=6(12)+12(1)+6(16)=180 g/mol. Molality m=kg solventmoles solute.
Let mass of glucose =w g. Solvent mass =(2500−w) g =10002500−w kg.
0.25=(2500−w)/1000w/180
0.25×10002500−w=180w …
- GSEB Higher Secondary Certificate (HSC) Examination 2022Set ANNUAL1 markMCQQ.What is the molality of a 10% w/w aqueous solution of NaOH? (Molecular mass of NaOH = 40 g mol-1)(a) 2.78 m(b) 2.87 m(c) 2.5 m(d) 2.05 m
›Reveal solutionSolution
Molality = moles of solute / mass of solvent in kg; for 10% w/w NaOH, take 100 g solution = 10 g NaOH + 90 g water.
Moles of NaOH = 10 g / 40 g mol-1 = 0.25 mol. …
- GUJCET 2021Set 151 markMCQQ.3.0 gram ethanoic acid in 50 gram benzene having ___ molality? (Atomic weights : H = 1, C = 12, O = 16). (A) 0.1 (B) 1.0 (C) 0.6 (D) 0.06
›Reveal solutionSolution
m=kg solventmol solute=0.0500.05=1.0.
Concept: Molality = moles of solute per kg of solvent.
Moles of CH3COOH (M = 60): 603.0=0.05 mol. …
- GSEB Higher Secondary Certificate (HSC) Examination 2020Set ANNUAL1 markMCQQ.Molality of 30% w/w aqueous solution of NaOH is -(a) 7.5 m(b) 8.32 m(c) 10.71 m(d) 9.17 m
›Reveal solutionSolution
Taking a 100 g basis for a 30% w/w solution gives 30 g NaOH in 70 g water; converting to moles and dividing by the mass of water in kg gives the molality.
Basis: 100 g of solution contains 30 g NaOH and (100-30) = 70 g water = 0.070 kg. …
- GUJCET 2019Set 131 markMCQQ.The value of which of the following unit of concentration will not change with the change in temperature? (A) Formality (B) Normality (C) Molality (D) Molarity
›Reveal solutionSolution
Molality uses mass, not volume, so it is independent of temperature.
Concept: Concentration units defined using volume (molarity, normality, formality expressed per litre) change with temperature because volume expands or contracts. Molality is defined per kilogram of solvent (mass), and mass does not vary with temperature, so molality is temperature-independent.
Steps: …
- GUJCET 2014Set A1 markMCQQ.What will be the value of molality for an aqueous solution of 10% w/w NaOH. (Na = 23, O = 16, H = 1) (A) 2.778 (B) 5 (C) 10 (D) 2.5
›Reveal solutionSolution
[!TLDR]
Molality =2.778 mol kg−1.
Concept
Molality m=mass of solvent (kg)moles of solute. For a w/w percentage, the stated mass is per 100 g of solution, so the solvent mass is 100−(solute mass).
Solution
M(NaOH)=23+16+1=40 g mol−1. …
- GUJCET 2014Set A1 markMCQQ.If 10 ml of 0.1 M aqueous solution of NaCl is divided in to 1000 drops of equal volume, what will be the concentration of one drop? (A) 0.01 M (B) 0.10 M (C) 0.001 M (D) 0.0001 M
›Reveal solutionSolution
[!TLDR] Concentration is an intensive property; dividing a solution into drops does not change its molarity, so each drop is 0.10 M.
Concept
Molarity =volume of solution (L)moles of solute. Both the moles of solute and the volume scale down together when you take a small portion, so their ratio — the concentration — stays the same. Concentration does not depend on how much of the solution you take.
Solution
Total moles =0.1 M×10×10−3 L=1×10−3 mol in 10 mL. …
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