Write the reactions occurring at the anode and the cathode in a dry cell and in a lead storage (accumulator) c

Question of 115

Q. Write the reactions occurring at the anode and the cathode in a dry cell and in a lead storage (accumulator) cell.

Gujarat GsebGSEB Higher Secondary Certificate (HSC) Examination 2022Subjective· 4mImportance★★★★★

0% · 0/115 Questions

🔒 Locked · start free trial →

You're viewing a preview — the full solution, concept, methods & PYQ mapping are locked.

Start your 14-day free trial to unlock the full solution →

Both are common primary/secondary galvanic cells; each has a distinct pair of anode and cathode half-reactions.

Dry cell (Leclanché-type cell):

Anode - a zinc container is oxidised: Zn(s) -> Zn2+(aq) + 2e-.

Cathode - a carbon (graphite) rod surrounded by a moist paste of MnO2, NH4Cl and ZnCl2; MnO2 is reduced: 2MnO2(s) + 2NH4+(aq) + 2e- -> Mn2O3(s) + 2NH3(aq) + H2O(l).

Lead storage battery (during discharge):

Anode - the spongy lead plate is oxidised: Pb(s) + SO4^2-(aq) -> PbSO4(s) + 2e-.

Cathode - the lead dioxide (PbO2) plate is reduced: PbO2(s) + SO4^2-(aq) + 4H+(aq) + 2e- -> PbSO4(s) + 2H2O(l). …

Start your 14-day free trial to unlock the full solution →

Same / Similar Concept — real previous-year questions on the same or a closely similar concept, not this exact question.

CBSE 2025Set 56/5/11 markMCQ
$Q. Match the type of cell given in Column I with their use given in Column II. Column I | Column II i. Lead storage cell | a. Wall clock ii. Mercury cell | b. Apollo Space Programme iii. Dry cell | c. Wrist watch iv. Fuel cell | d. Inverter (A) i-a, ii-b, iii-c, iv-d (B) i-d, ii-c, iii-a, iv-b (C) i-c, ii-d, iii-b, iv-a (D) i-b, ii-a, iii-d, iv-c$
›Reveal solutionSolution
This is a matching problem linking battery types to their real-world applications. The correct pairing is: Lead storage cell → Inverter (d), Mercury cell → Wrist watch (c), Dry cell → Wall clock (a), Fuel cell → Apollo Space Programme (b). So the answer is option (B).

The key here is to connect each cell's chemistry and design to the power requirement and portability of the device it powers. You don't need to memorise random facts — just think about what each battery is good at.

Lead storage cell (i) — This is a heavy, rechargeable battery that delivers a high current. It's used where you need a lot of power and weight isn't a problem, like in car starters or inverters (backup power for homes). So it matches d. Inverter.

Mercury cell (ii) — This is a small, compact button cell with a very stable voltage and long shelf life. It was traditionally used in devices that need a tiny, reliable power source for years — like c. Wrist watch (and hearing aids, calculators). Note: modern watches often use silver oxide or lithium cells, but mercury cells were the classic choice.

Dry cell (iii) — The common Leclanché cell (zinc-carbon) is cheap, moderate in power, and non-rechargeable. It's perfect for low-drain, intermittent-use devices like a a. Wall clock (or a torch, remote control). It's not suited for high-drain or continuous heavy use. …
Start your 14-day free trial to see the full solution →
CBSE 2025Set ANNUAL1 mark
$Q. Write overall reaction of mercury cell.$
›Reveal solutionSolution

The mercury cell has a zinc-mercury amalgam anode and an HgO/carbon cathode paste in an alkaline (KOH/ZnO) electrolyte; because the electrolyte composition never changes as the cell discharges, it gives a remarkably steady voltage throughout its life.

At the anode (oxidation): Zn(Hg) + 2OH- → ZnO(s) + H2O + 2e-

At the cathode (reduction): HgO(s) + H2O + 2e- → Hg(l) + 2OH-

Adding the two half-reactions (the H2O and OH- cancel):

Zn(Hg) + HgO(s) → ZnO(s) + Hg(l)

…

Start your 14-day free trial to see the full solution →
CBSE 2023Set TERM21 mark
$Q. In the mercury cell, the anode is made of \dots\dots\dots\dots\dots$
›Reveal solutionSolution
The mercury cell's anode is a zinc-mercury amalgam; the cathode is a paste of HgO and carbon.

The mercury cell (used in hearing aids, watches) is a primary cell with:

Anode: Zinc mercury amalgam (Zn–Hg), i.e. zinc metal amalgamated with mercury

Cathode: a paste of HgO and carbon

Electrolyte: a paste of KOH and ZnO

Electrode reactions:

Anode: $Zn(Hg) + 2OH^- \rightarrow ZnO(s) + H_2O + 2e^-$

Cathode: $HgO + H_2O + 2e^- \rightarrow Hg(l) + 2OH^-$

…
Start your 14-day free trial to see the full solution →

←Previous chapterCh 1Solutions

Q.Write the reactions occurring at the anode and the cathode in a dry cell and in a lead storage (accumulator) cell.

Concept understanding — Commercial Cells and Batteries

Commercial Cells and Batteries

Q.Write the reactions occurring at the anode and the cathode in a dry cell and in a lead storage (accumulator) cell.

🎓Unlock everything free for 14 days

Unlock everything free for 14 days