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NCERT Exemplar · Q7

Q.Temperature dependence of resistivity ρ(T)\rho(T) of semiconductors, insulators and metals is significantly based on the following factors:

(a) number of charge carriers can change with temperature T.
(b) time interval between two successive collisions can depend on T.
(c) length of material can be a function of T.
(d) mass of carriers is a function of T.
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Resistivity is ρ=mne2τ\rho = \dfrac{m}{ne^2\tau}, so it can only depend on temperature through quantities that genuinely change with TT: the carrier number density nn (a) and the mean time between collisions τ\tau (b). Sample length (c) and carrier mass (d) are not temperature-dependent physical mechanisms.

Starting point: what ρ\rho actually depends on

From the microscopic (Drude) model of conduction,

ρ=1neμ=mne2τ,\rho = \frac{1}{ne\mu} = \frac{m}{ne^2\tau},

where nn is the number density of charge carriers, ee the carrier charge, mm the carrier mass, and τ\tau the average time between two successive collisions (relaxation time). Since ee and mm are fixed constants of the carrier, any temperature dependence of ρ\rho must come through nn and/or τ\tau.

(a) Number of charge carriers, nn — genuinely TT-dependent

In a metal, essentially all the free electrons are already in the conduction band, so nn barely changes with TT. But in a semiconductor or insulator, the valence band is full and the conduction band is empty at T=0T=0; carriers appear only when thermal energy excites an electron across the band gap EgE_g:

n∝e−Eg/2kBT.n \propto e^{-E_g/2k_BT}.

As TT rises, nn increases sharply (exponentially), which is exactly why semiconductor/insulator resistivity falls so fast with temperature. This makes (a) a real, significant temperature-dependence mechanism.

(b) Time between successive collisions, τ\tau — genuinely TT-dependent

In a metal, nn is fixed, but the lattice ions vibrate more vigorously as TT increases, scattering the drifting electrons more often. This shortens the mean free time τ\tau between collisions (roughly τ∝1/T\tau \propto 1/T at ordinary temperatures), which is exactly why metallic resistivity rises with temperature. This makes (b) the dominant mechanism for metals.

(c) Length of material — not a real mechanism …

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