Q.Show that the wavelength of electromagnetic radiation is equal to the de Broglie wavelength of its quantum (photon).
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De Broglie Wavelength: When Particles Start Acting Like Waves
You already know that light behaves like a wave (interference, diffraction) and like a particle (photoelectric effect). That's wave-particle duality for light. De Broglie's radical idea in 1924 was: if light can be both, why can't matter be both too?
He proposed that every moving particle — an electron, a proton, even a cricket ball — has a wavelength associated with it. The faster it moves, the shorter that wavelength becomes.
The Intuition
Think of a wave on a string. Its wavelength is the distance between two consecutive crests. Now imagine an electron moving through space. De Broglie said that the electron's motion itself creates a "matter wave" — a wave of probability that guides where the electron is likely to be found.
You never see this wavelength in everyday life because for large objects it's unimaginably tiny. A cricket ball moving at 30 m/s has a de Broglie wavelength of about 10−34 m — far smaller than an atomic nucleus. That's why macroscopic objects behave like particles.
The Precise Statement
The de Broglie wavelength λ of a particle is given by:
λ=ph
where:
- h is Planck's constant (6.626×10−34 J⋅s)
- p is the momentum of the particle (p=mv for non-relativistic speeds)
Key point: The wavelength depends only on momentum, not on charge, mass, or any other property. A fast electron and a slow proton can have the same wavelength if their momenta are equal.
What This Means Physically
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For electrons in atoms: The de Broglie wavelength of an electron in a hydrogen atom is roughly the size of the atom itself (≈10−10 m). This is why electrons form standing waves around the nucleus — only certain wavelengths "fit" into the orbit, which explains quantised energy levels.
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For experiments: If you fire electrons through a crystal, they diffract just like X-rays. This was confirmed by Davisson and Germer in 1927 — a Nobel-winning experiment that proved de Broglie right.
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For large objects: The wavelength is so small that wave behaviour is undetectable. A car moving at 100 km/h has λ≈10−38 m — you'd need a slit smaller than an atom to see diffraction.
A common mistake is to think the de Broglie wavelength is the size of the particle. It is not. It is the wavelength of the probability wave associated with the particle. The particle itself remains point-like.
Worked Example
Question: What is the de Broglie wavelength of an electron moving at 2.0×106 m/s? (Mass of electron me=9.11×10−31 kg)
Solution:
First, find momentum:
p=mv=(9.11×10−31)(2.0×106)=1.822×10−24 kg⋅m/s
Then apply de Broglie's formula: …
Why this formula?
De Broglie Wavelength: Why Matter Has a Wave Nature
The idea that a moving particle has a wavelength is one of the most radical shifts in physics. It came from Louis de Broglie in 1924, who asked a simple question: if light — which we thought was a wave — can behave like a particle (the photon), then why can't a particle behave like a wave?
The Core Insight: Symmetry in Nature
De Broglie started from Einstein's relation for a photon. For light, the energy E and momentum p of a photon are linked to its wave properties — frequency f and wavelength λ — by:
E=hfandp=λh
where h is Planck's constant. These are not arbitrary; they come from the fact that light is an electromagnetic wave, and Planck had already shown that energy comes in quanta hf.
De Broglie's reasoning was a leap of symmetry: if nature treats light and matter on equal footing (as Einstein's special relativity suggests), then any moving particle should also have a wavelength associated with it. He proposed that the same relation holds for matter:
λ=ph
where p=mv is the momentum of the particle (for non-relativistic speeds). This is the de Broglie wavelength.
Why This Formula Makes Sense: A Simple Derivation
There is no rigorous "derivation" from first principles — de Broglie's hypothesis was a postulate. But we can see why it is plausible by combining two key ideas from relativity and quantum theory.
Step 1: Energy of a particle from relativity
For a particle with rest mass m0, the total energy in special relativity is:
E=p2c2+m02c4
For a photon, m0=0, so E=pc. This matches the photon's wave relation E=hf and p=h/λ.
Step 2: Assume the same wave-particle duality for matter
If a massive particle also has a wave associated with it, then its energy should also be E=hf, where f is the frequency of the matter wave. Equating the relativistic energy with the quantum energy:
hf=p2c2+m02c4
For a particle moving at non-relativistic speeds (v≪c), the momentum p=mv is small compared to m0c, so we can expand:
E≈m0c2+2m0p2
The first term is rest energy, which is constant. The second term is kinetic energy K=p2/(2m). The wave frequency f then corresponds to the kinetic part (since rest energy doesn't contribute to motion). But the key relation we want is between wavelength and momentum.
Step 3: The wavelength from the wave speed
For any wave, the speed vwave=fλ. For a matter wave, de Broglie proposed that the wave speed equals the particle's speed v (this is the phase velocity). So:
v=fλ
Now use E=hf and E=21mv2 (non-relativistic kinetic energy). Then:
f=hE=2hmv2
Substitute into v=fλ:
v=2hmv2λ⇒λ=mv2h
This gives λ=2h/p, which is wrong by a factor of 2. The correct formula is λ=h/p. …
Concept: De Broglie Wavelength — the idea that every particle with momentum has an associated wavelength λ=h/p.
For a photon of electromagnetic radiation:
- The photon energy is E=hν, and its momentum is p=cE (from Maxwell's theory).
- Substitute E=hν into the momentum: p=chν.
- Since ν=c/λ, we get p=λh. …
The de Broglie wavelength of a photon is identical to the wavelength of the corresponding electromagnetic radiation because the photon’s momentum is p=h/λ, and de Broglie’s relation λdB=h/p directly gives λdB=λ.
Why This Works — The Core Idea
The de Broglie hypothesis extends wave-particle duality to all matter: every moving particle has an associated wavelength. For a photon — the quantum of light — this is not a separate concept. Light already behaves as a wave with wavelength λ, and as a particle with energy E=hν and momentum p=h/λ. The de Broglie relation simply recovers the same wavelength from the particle’s momentum. So the two are not just equal; they are the same physical quantity expressed from different starting points.
Step-by-Step Derivation
1. Recall the de Broglie wavelength formula
For any particle with momentum p, the de Broglie wavelength is:
λdB=ph
where h is Planck’s constant. This is the fundamental relation.
2. Find the momentum of a photon
A photon has energy E=hν, where ν is the frequency of the electromagnetic wave. For light, the wave speed is c, so ν=c/λ. Thus:
E=λhc
From special relativity, a photon’s energy and momentum are related by E=pc (since the photon is massless). Therefore:
p=cE=chc/λ=λh
Photon momentum: p=λh
3. Substitute into the de Broglie relation
Plug p=h/λ into λdB=h/p:
λdB=h/λh=λ
That’s it. The de Broglie wavelength of the photon is exactly the wavelength of the electromagnetic radiation. …
Method: Direct Substitution Using the de Broglie Relation and Photon Momentum
The idea is simple: the de Broglie wavelength formula applies to any particle with momentum — and a photon is a particle with momentum. So we just plug the photon's momentum into the de Broglie relation and see what comes out.
Steps
Step 1 — Write the de Broglie wavelength formula
For any particle, the de Broglie wavelength λ is given by:
λ=ph
where h is Planck's constant and p is the linear momentum of the particle.
Step 2 — Write the momentum of a photon
A photon of electromagnetic radiation of frequency ν (or wavelength λEM) carries energy E=hν. From special relativity, the momentum of a massless particle (like a photon) is:
p=cE
Substitute E=hν:
p=chν
Step 3 — Substitute photon momentum into de Broglie relation
Put this p into λ=h/p:
λdB=hν/ch=νc
Step 4 — Relate c/ν to the electromagnetic wavelength …
Students often treat this as a straightforward substitution, but the logic has subtle traps. Here are the most common mistakes and how to avoid each.
Mistake 1: Using the wrong expression for momentum of a photon
Many students write p=mv and then try to plug in m=0 for a photon. That leads to p=0, which makes the de Broglie wavelength λ=h/p undefined — and the proof collapses.
How to avoid: Remember that for a photon, momentum is not mv. The correct relation comes from electromagnetic theory: p=cE. Since E=hν and ν=c/λ, you get p=λh. This is the only valid starting point for a photon.
Mistake 2: Confusing the two different λ symbols
In the question, "wavelength of electromagnetic radiation" (call it λEM) and "de Broglie wavelength" (call it λdB) are conceptually distinct. Students often assume they are the same symbol and skip the derivation, writing λ=h/p and then p=h/λ — which is circular.
How to avoid: Write them separately at the start. Let λEM be the radiation wavelength from c=νλEM. Let λdB be the de Broglie wavelength h/p. Your goal is to show λEM=λdB.
Mistake 3: Forgetting that E=hν applies to the photon
Some students try to use E=mc2 for the photon, which again hits the m=0 problem. Others use E=21mv2, which is completely wrong for a photon.
How to avoid: Anchor yourself: a photon's energy is only given by E=hν (or E=hc/λEM). Never substitute mass-based formulas for a photon.
Mistake 4: Mixing up c and v in the de Broglie relation
For a massive particle, de Broglie wavelength is λ=h/(mv). Some students carry this over and write p=mc for a photon, which is technically correct only if you treat m as relativistic mass — but that introduces unnecessary confusion and is not standard in most Indian board syllabi.
How to avoid: Stick to the photon-specific momentum p=E/c. It's cleaner and exam-safe. If your syllabus uses relativistic mass, mention it only as an alternative, but lead with p=E/c.
Mistake 5: Not showing the final equality clearly
After deriving λdB=h/(E/c)=hc/E and E=hc/λEM, students sometimes stop without substituting, or they write λdB=λEM without showing the cancellation.
How to avoid: Write the full chain:
λdB=ph=E/ch=Ehc …
- GUJCET 2025Set 031 markMCQQ.What is the de-Broglie wavelength of a bullet of mass 0.033 kg travelling at the speed of 1 km/s? (h=6.6×10−34 Js) (A) 3×10−25 m (B) 2×10−35 m (C) 1.1×10−32 m (D) 1.7×10−35 m
›Reveal solutionSolution
[!TLDR]
λ=h/(mv)=2×10−35 m.
Concept
Every moving particle has an associated de Broglie wavelength λ=ph=mvh.
Solution
Given m=0.033 kg, v=1 km/s=103 m/s, h=6.6×10−34 Js. …
- GUJCET 2024Set 131 markMCQQ.A ball of mass 0.12 kg moving with a speed of 20 ms−1 has de-Broglie wavelength ________. (h=6.63×10−34 Js) (A) 4.76×10−34 m (B) 2.76×10−34 m (C) 3.76×10−34 m (D) 1.76×10−34 m
›Reveal solutionSolution
de Broglie wavelength λ=h/(mv).
Steps. …
- GUJCET 2023Set 091 markMCQQ.What is the de Broglie wavelength associated with an electron accelerated through a potential difference of 64 volts? (A) 1.43A˚ (B) 1.23A˚ (C) 1.53A˚ (D) 1.33A˚
›Reveal solutionSolution
[!TLDR]
Using λ=V12.27 A˚ with V=64 V gives λ≈1.53 A˚ — option (C).
Concept
An electron of charge e accelerated through a potential difference V gains kinetic energy eV=21mv2, so its momentum is p=2meV. Its de Broglie wavelength is
λ=ph=2meVh.
Substituting the constants for an electron gives the convenient form …
- GUJCET 2023Set 091 markMCQQ.An electron, an α-particle and a proton have the same kinetic energy. Which of these have longest de Broglie wavelength? (A) α-particle (B) proton (C) electron (D) both α-particle and proton
›Reveal solutionSolution
[!TLDR] λ∝1/m at fixed K; lightest = electron → (C).
Concept
The de Broglie wavelength is λ=ph. For a particle of mass m and kinetic energy K, momentum p=2mK, so λ=2mKh. (NCERT Dual Nature of Radiation and Matter.)
Solution …
- GUJCET 2022Set 171 markMCQQ.What is the de-Broglie wavelength associated with an electron moving with a speed of 6.4×106 m/s? [Mass of electron me=9.11×10−31 kg, Planck's constant h=6.63×10−34 J.s.] (A) 0.124 nm (B) 0.114 nm (C) 0.135 nm (D) 0.145 nm
›Reveal solutionSolution
de-Broglie wavelength λ=mvh.
Steps.
- mv=9.11×10−31×6.4×106=5.83×10−24 kg·m/s. …
- GUJCET 2022Set 171 markMCQQ.An electron, an α-particle and a proton have the same kinetic energy. Which of these particles has the shortest de-Broglie wavelength? (A) α-particle (B) Electron (C) Proton (D) None of these
›Reveal solutionSolution
At equal KE, λ∝1/m; the heaviest particle wins.
Concept. λ=2mEh. For the same kinetic energy E, the larger the mass m, the shorter the wavelength. …
- GUJCET 2021Set 151 markMCQQ.What is the de-Broglie wavelength associated with an electron, accelerated through a potential difference of 64 volts? [h=6.63×10−34 J.s] (A) 1.23 Å (B) 1.87 Å (C) 1.53 Å (D) 1.98 Å
›Reveal solutionSolution
Electron de Broglie wavelength after V volts: lambda approx 12.27/sqrt(V) Angstrom.
Concept. λ=2meVh=V12.27 A˚. …
- GUJCET 2020Set 071 markMCQQ.How much is the De-Broglie wavelength for an electron accelerated by an 100V potential difference? (A) 12.3 nm (B) 123 nm (C) 0.123 nm (D) 0.123 cm
›Reveal solutionSolution
For an electron accelerated through V volts, λ=V12.27A˚.
Concept: de Broglie wavelength of an electron accelerated through potential V:
λ=2meVh=V12.27 A˚.
With V=100 V: …
- GUJCET 2014Set A1 markMCQQ.A body of mass 100 g moves at the speed of 36 km/hr. The de Broglie wave length related to it is of the order __________ m (h=6.626×10−34 Js) (A) 10−14 (B) 10−24 (C) 10−34 (D) 10−44
›Reveal solutionSolution
[!TLDR] λ=h/mv≈6.6×10−34 m ⇒ order 10−34 m.
Concept
The de Broglie wavelength of a moving particle is λ=mvh (NCERT Dual Nature of Matter).
Solution
Convert units: m=100 g =0.1 kg, v=36 km/hr =360036×1000=10 m/s. …
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