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Exercises · 3.38

Q.Considering the elements B, Al, Mg, and K, the correct order of their metallic character is:

(a) B > Al > Mg > K
(b) Al > Mg > B > K
(c) Mg > Al > K > B
(d) K > Mg > Al > B
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Metallic character increases down a group and decreases across a period (left to right). Arranging B, Al, Mg, and K by position gives K > Mg > Al > B.

Understanding Metallic Character

Metallic character measures how readily an atom loses electrons to form positive ions. The more easily an element gives up its valence electrons, the more metallic it is. This property ties directly to ionization energy: lower ionization energy means higher metallic character.

Two periodic trends govern this behavior:

Down a group: Atomic radius increases because each successive element adds a new electron shell. The outermost electrons sit farther from the nucleus and experience greater shielding from inner electrons. Both effects weaken the nuclear attraction, making it easier to remove electrons. Metallic character increases.

Across a period (left to right): Electrons are added to the same shell while nuclear charge increases. The effective nuclear pull on valence electrons strengthens, atomic radius decreases, and ionization energy rises. Metallic character decreases.

Locating the Elements

Let's place each element on the periodic table:

ElementGroupPeriodPosition
B132Upper right region
Al133Below B
Mg23Left of Al in period 3
K14Far left, period 4

Step-by-Step Comparison

  1. K (Potassium) is the most metallic. It sits in Group 1, period 4—the farthest left and lowest among our elements. Its single valence electron in the fourth shell is extremely far from the nucleus and heavily shielded. Potassium loses this electron with minimal energy input, making it highly metallic (it's an alkali metal, after all).

  2. Comparing Mg and Al (both in period 3). Moving left to right across period 3, metallic character decreases. Magnesium (Group 2) lies to the left of aluminum (Group 13), so Mg is more metallic than Al. Magnesium's two valence electrons are easier to remove than aluminum's three, despite both being in the same shell. …

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