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NCERT Exemplar · Q7

Q.Two atoms are said to be isobars if.

(i) they have same atomic number but different mass number.
(ii) they have same number of electrons but different number of neutrons.
(iii) they have same number of neutrons but different number of electrons.
(iv) sum of the number of protons and neutrons is same but the number of protons is different.
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Isobars are atoms of different elements that have the same mass number (sum of protons and neutrons) but different atomic numbers (number of protons). The correct option is (D).

When we talk about different types of atoms, we use specific terms to classify them based on their composition of protons, neutrons, and electrons. Understanding these terms requires a clear grasp of atomic notation.

Every atom can be represented using the notation ZAX_Z^A X, where:

  • XX is the chemical symbol of the element.
  • ZZ is the atomic number, which represents the number of protons in the nucleus. This number uniquely identifies an element. For a neutral atom, ZZ also equals the number of electrons.
  • AA is the mass number, which represents the total number of protons and neutrons in the nucleus. It's essentially the total number of nucleons (particles in the nucleus).

From this, we can also determine the number of neutrons (NN) in an atom:

N=A−ZN = A - Z

Now, let's define isobars and related terms to understand the distinctions.

  1. Understand the definition of Isobars.

    Isobars are atoms of different chemical elements that have the same mass number (AA) but different atomic numbers (ZZ). Since they have different atomic numbers, they are different elements and thus have different numbers of protons. Because their mass numbers are the same, the sum of their protons and neutrons is identical.

    Important

    For isobars:

    • Same mass number (AA).
    • Different atomic number (ZZ).
    • Different number of protons.
    • Different number of neutrons (since N=A−ZN = A - Z and ZZ is different while AA is same).
    • Different chemical properties (due to different ZZ).

    Let's consider an example: Carbon-14 (614C_{6}^{14}\text{C}) and Nitrogen-14 (714N_{7}^{14}\text{N}).

    • For Carbon-14: A=14A = 14, Z=6Z = 6. Number of protons =6= 6, Number of neutrons =14−6=8= 14 - 6 = 8.
    • For Nitrogen-14: A=14A = 14, Z=7Z = 7. Number of protons =7= 7, Number of neutrons =14−7=7= 14 - 7 = 7. They both have a mass number of 1414, but different atomic numbers (66 and 77). Therefore, they are isobars.
  2. Analyze the given options.

    • (A) they have same atomic number but different mass number.

      This describes isotopes. Isotopes are atoms of the same element (same ZZ) but with different numbers of neutrons, leading to different mass numbers (AA). For example, Carbon-12 (612C_{6}^{12}\text{C}) and Carbon-14 (614C_{6}^{14}\text{C}) are isotopes. This option is incorrect for isobars.

    • (B) they have same number of electrons but different number of neutrons. …

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