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NCERT Exemplar · Q9

Q.Mark the correct options: (Note: more than one of the given options may be correct.)

(a) A system XX is in thermal equilibrium with YY but not with ZZ. System YY and ZZ may be in thermal equilibrium with each other.
(b) A system XX is in thermal equilibrium with YY but not with ZZ. Systems YY and ZZ are not in thermal equilibrium with each other.
(c) A system XX is neither in thermal equilibrium with YY nor with ZZ. The systems YY and ZZ must be in thermal equilibrium with each other.
(d) A system XX is neither in thermal equilibrium with YY nor with ZZ. The system YY and ZZ may be in thermal equilibrium with each other.
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Thermal equilibrium means "same temperature," and the Zeroth Law makes this relation transitive - exactly like mathematical equality. If XX shares a temperature with YY but not with ZZ, then YY and ZZ must have different temperatures (not merely "may"). If XX differs from both YY and ZZ, nothing is forced between YY and ZZ. Correct options: (B) and (D).

The Zeroth Law of Thermodynamics says: if two systems are each in thermal equilibrium with a third system, they are in thermal equilibrium with each other. In plain terms, "in thermal equilibrium" simply means "has the same temperature." So the Zeroth Law is really a statement about the transitivity of equality: if TX=TYT_X = T_Y and TX=TZT_X = T_Z, then TY=TZT_Y = T_Z.

The question gives two different starting scenarios and asks what follows for YY and ZZ in each.

Scenario 1 - options (A) and (B): XX in equilibrium with YY, not with ZZ

Here TX=TYT_X = T_Y and TX≠TZT_X \neq T_Z. Since YY has exactly the same temperature as XX, and XX's temperature is different from ZZ's, YY's temperature must also differ from ZZ's - there is no way for YY and ZZ to coincide, because that would force TX=TZT_X = T_Z too. So YY and ZZ are not in equilibrium - this is forced, not merely possible.

  • (A) says YY and ZZ "may be" in equilibrium - false, because it never happens.
  • (B) says YY and ZZ are "not" in equilibrium - true, and it is forced every time.

Scenario 2 - options (C) and (D): XX in equilibrium with neither YY nor ZZ …

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