Q.Which of the following is not an example of redox reaction?
A redox reaction involves simultaneous oxidation (loss of electrons/increase in oxidation number) and reduction (gain of electrons/decrease in oxidation number). The reaction that shows no change in oxidation numbers for any element is not a redox reaction. Here, that is option (iv).
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The core idea — Every redox reaction has two halves: one species gets oxidised (its oxidation number increases) and another gets reduced (its oxidation number decreases). If no oxidation number changes, the reaction is not redox; it is a simple double displacement or precipitation.
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Check each option by assigning oxidation numbers — We go element by element, using standard rules (O is usually -2, H is +1, alkali metals are +1, halogens are -1 in compounds, and free elements have oxidation number 0).
Option (i): CuO + H₂ → Cu + H₂O
- In CuO: Cu is +2, O is -2.
- In H₂: H is 0 (free element).
- In Cu: Cu is 0 (free element).
- In H₂O: H is +1, O is -2. Change: Cu goes from +2 to 0 (reduction), H goes from 0 to +1 (oxidation). → Redox reaction.
Option (ii): Fe₂O₃ + 3CO → 2Fe + 3CO₂
- In Fe₂O₃: Fe is +3, O is -2.
- In CO: C is +2, O is -2.
- In Fe: Fe is 0.
- In CO₂: C is +4, O is -2. Change: Fe goes from +3 to 0 (reduction), C goes from +2 to +4 (oxidation). → Redox reaction.
Option (iii): 2K + F₂ → 2KF
- K: 0 (free element) → in KF: K is +1.
- F₂: 0 (free element) → in KF: F is -1. Change: K goes from 0 to +1 (oxidation), F goes from 0 to -1 (reduction). → Redox reaction.
Option (iv): BaCl₂ + H₂SO₄ → BaSO₄ + 2HCl
- BaCl₂: Ba is +2, Cl is -1.
- H₂SO₄: H is +1, S is +6, O is -2.
- BaSO₄: Ba is +2, S is +6, O is -2.
- HCl: H is +1, Cl is -1. Every element keeps the same oxidation number throughout. No electron transfer occurs — it is simply a double displacement (precipitation) reaction. → Not a redox reaction.
A common mistake is to think that because a precipitate forms (BaSO₄), the reaction must involve electron transfer. Precipitation is a physical rearrangement of ions, not a redox process. Always check oxidation numbers — if they don’t change, it’s not redox.
For quick screening: if the reaction involves a free element on one side (like H₂, O₂, K, F₂, Fe, Cu) and that element appears in a compound on the other side, it is almost certainly redox. Option (iv) has no free elements at all — a strong hint it is not redox.
The reaction that is not an example of a redox reaction is option (iv).
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