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Exercises · 2.26

Q.An atom of an element contains 29 electrons and 35 neutrons. Deduce

(i) the number of protons and
(ii) the electronic configuration of the element.
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In a neutral atom, the number of protons equals the number of electrons. With 29 electrons, the element has 29 protons, which identifies it as copper (Cu). Its electronic configuration is 1s22s22p63s23p63d104s11s^2 2s^2 2p^6 3s^2 3p^6 3d^{10} 4s^1.


The key to this problem lies in understanding the relationship between the three fundamental particles in an atom: protons, electrons, and neutrons. For a neutral atom — which is what we always assume unless told otherwise — the number of protons and electrons must be equal. This is because the positive charge of each proton balances the negative charge of each electron, making the atom electrically neutral.

The number of neutrons, on the other hand, is independent of the charge. It only affects the mass of the atom (the isotope), not its identity. So the first step is always: protons = electrons in a neutral atom.

  1. Finding the number of protons

    The atom has 29 electrons. Since it is neutral, the number of protons must also be 29.

    This number is the atomic number (Z) of the element.

    So Z=29Z = 29.

  2. Identifying the element

    The atomic number 29 corresponds to copper (Cu) on the periodic table.

    The mass number (protons + neutrons) would be 29+35=6429 + 35 = 64, so this is the isotope 64Cu^{64}\text{Cu}, but the question only asks for the electronic configuration, not the isotope.

  3. Writing the electronic configuration

    For an atom with 29 electrons, we fill orbitals in order of increasing energy (the Aufbau principle). The order is:

    1s<2s<2p<3s<3p<4s<3d<4p1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p, etc.

    Let’s fill step by step:

    • 1s21s^2 → 2 electrons
    • 2s22s^2 → 2 more (total 4)
    • 2p62p^6 → 6 more (total 10)
    • 3s23s^2 → 2 more (total 12)
    • 3p63p^6 → 6 more (total 18)
    • 4s24s^2 → 2 more (total 20)
    • Now we have 9 electrons left to place. The next orbital is 3d3d, which can hold up to 10 electrons. …

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