Q.Savita was surprised to see oil spreading on the surface of water and asked her mother to explain why oil spreads on the surface of water. Her mother explained the reason behind it. By going through the explanation, she thought of learning more about other scientific phenomenon also.
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Start your 14-day free trial to unlock the full solution →A liquid spreads over another only if doing so lowers the total surface energy of the system; oil's low surface tension lets it spread on water, while water's high surface tension makes it bead up rather than spread on oil.
Whether one liquid spreads to form a thin film over another is governed by the spreading coefficient, S, which compares the surface energies (tensions) involved:
S = gamma(A-air) - gamma(B-air) - gamma(A-B)
where gamma(A-air) is the surface tension of the underlying liquid (water) against air, gamma(B-air) is the surface tension of the liquid being placed on top (oil) against air, and gamma(A-B) is the interfacial tension between the two liquids. A liquid spreads spontaneously over another only if this makes S positive, i.e. if doing so lowers the total surface energy of the exposed surfaces.
Water has a much higher surface tension (about 72 mN/m) than oils (typically around 30 mN/m or less). When a drop of oil is placed on water, replacing the high-energy water-air surface with a lower-energy oil-air surface (plus the oil-water interface) lowers the overall surface energy of the system — so the oil spreads out into a thin film to reduce that energy.
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