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NCERT Exemplar · Q1

Q.Which of the following is not an example of redox reaction?

(i) CuO + H2 → Cu + H2O
(ii) Fe2O3 + 3CO → 2Fe + 3CO2
(iii) 2K + F2 → 2KF
(iv) BaCl2 + H2SO4 → BaSO4 + 2HCl
Jharkhand JacMCQ· 1mImportance★★★★★est
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✓ Free question

A redox reaction involves simultaneous oxidation (loss of electrons/increase in oxidation number) and reduction (gain of electrons/decrease in oxidation number). The reaction that shows no change in oxidation numbers for any element is not a redox reaction. Here, that is option (iv).

  1. The core idea — Every redox reaction has two halves: one species gets oxidised (its oxidation number increases) and another gets reduced (its oxidation number decreases). If no oxidation number changes, the reaction is not redox; it is a simple double displacement or precipitation.

  2. Check each option by assigning oxidation numbers — We go element by element, using standard rules (O is usually -2, H is +1, alkali metals are +1, halogens are -1 in compounds, and free elements have oxidation number 0).

    Option (i): CuO + H₂ → Cu + H₂O

    • In CuO: Cu is +2, O is -2.
    • In H₂: H is 0 (free element).
    • In Cu: Cu is 0 (free element).
    • In H₂O: H is +1, O is -2. Change: Cu goes from +2 to 0 (reduction), H goes from 0 to +1 (oxidation). → Redox reaction.

    Option (ii): Fe₂O₃ + 3CO → 2Fe + 3CO₂

    • In Fe₂O₃: Fe is +3, O is -2.
    • In CO: C is +2, O is -2.
    • In Fe: Fe is 0.
    • In CO₂: C is +4, O is -2. Change: Fe goes from +3 to 0 (reduction), C goes from +2 to +4 (oxidation). → Redox reaction.

    Option (iii): 2K + F₂ → 2KF

    • K: 0 (free element) → in KF: K is +1.
    • F₂: 0 (free element) → in KF: F is -1. Change: K goes from 0 to +1 (oxidation), F goes from 0 to -1 (reduction). → Redox reaction.

    Option (iv): BaCl₂ + H₂SO₄ → BaSO₄ + 2HCl

    • BaCl₂: Ba is +2, Cl is -1.
    • H₂SO₄: H is +1, S is +6, O is -2.
    • BaSO₄: Ba is +2, S is +6, O is -2.
    • HCl: H is +1, Cl is -1. Every element keeps the same oxidation number throughout. No electron transfer occurs — it is simply a double displacement (precipitation) reaction. → Not a redox reaction.
Watch out

A common mistake is to think that because a precipitate forms (BaSO₄), the reaction must involve electron transfer. Precipitation is a physical rearrangement of ions, not a redox process. Always check oxidation numbers — if they don’t change, it’s not redox.

Tip

For quick screening: if the reaction involves a free element on one side (like H₂, O₂, K, F₂, Fe, Cu) and that element appears in a compound on the other side, it is almost certainly redox. Option (iv) has no free elements at all — a strong hint it is not redox.

✓Final answer

The reaction that is not an example of a redox reaction is option (iv).

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