Chemistry · Ch 6 — States of Matter
Viscosity
Viscosity
Resistance to flow
Viscosity measures a liquid's resistance to flow, arising from internal friction between layers of the fluid as they slide past one another. Strong intermolecular forces hold neighbouring layers together and resist this relative motion.
Laminar flow and the velocity gradient
When a liquid flows over a fixed surface, the very bottom layer — in direct contact with the surface — stays stationary, while each successive layer above it moves a little faster than the one below. This orderly build-up of speed from one layer to the next is called laminar flow (Fig. 5.16): any chosen layer is accelerated by the faster layer above it and retarded by the slower layer below it.
If the velocity changes by over a perpendicular distance , the velocity gradient is . Sustaining this layered flow requires a force that is proportional to both the area of contact between the layers and the velocity gradient:
Here (eta) is the proportionality constant, the coefficient of viscosity — numerically, the force needed when the velocity gradient and the contact area are both unity. So is the direct measure of a liquid's viscosity.
Units
- SI unit:
- CGS unit: the poise, named after Jean Louis Poiseuille:
What controls viscosity …
What this figure shows. A 3-D perspective diagram of three thin stacked parallelogram sheets (representing liquid layers), drawn in green, sitting one above another with a small vertical gap, viewed at an angle. The bottom-left corner of the stack is labelled 'Area of the plate A' with an arrow. Each of the three layers has a horizontal arrow projecting from its right edge showing its flow velocity: the topmost layer's arrow is labelled 'u + du', the middle layer's arrow is labelled 'u', and the bottom layer's arrow is labelled 'u - du' (arrows get progressively shorter/slower going down, illustrating the velocity gradient). Small vertical double-headed marks between the layers on the left side are labelled …