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Chemistry · Ch 6 — States of Matter

Viscosity

6.11.3

Viscosity

Resistance to flow

Viscosity measures a liquid's resistance to flow, arising from internal friction between layers of the fluid as they slide past one another. Strong intermolecular forces hold neighbouring layers together and resist this relative motion.

Laminar flow and the velocity gradient

When a liquid flows over a fixed surface, the very bottom layer — in direct contact with the surface — stays stationary, while each successive layer above it moves a little faster than the one below. This orderly build-up of speed from one layer to the next is called laminar flow (Fig. 5.16): any chosen layer is accelerated by the faster layer above it and retarded by the slower layer below it.

If the velocity changes by dudu over a perpendicular distance dzdz, the velocity gradient is dudz\dfrac{du}{dz}. Sustaining this layered flow requires a force FF that is proportional to both the area of contact AA between the layers and the velocity gradient:

F∝A(dudz)⟹F=ηA(dudz)F \propto A\left(\frac{du}{dz}\right)\qquad\Longrightarrow\qquad F = \eta A\left(\frac{du}{dz}\right)

Here η\eta (eta) is the proportionality constant, the coefficient of viscosity — numerically, the force needed when the velocity gradient and the contact area are both unity. So η\eta is the direct measure of a liquid's viscosity.

Units

  • SI unit: 1 N s m−2=1 pascal second (Pa s)=1 kg m−1s−11\ \text{N s m}^{-2} = 1\ \text{pascal second (Pa s)} = 1\ \text{kg m}^{-1}\text{s}^{-1}
  • CGS unit: the poise, named after Jean Louis Poiseuille:

1 poise=1 g cm−1s−1=10−1 kg m−1s−11\ \text{poise} = 1\ \text{g cm}^{-1}\text{s}^{-1} = 10^{-1}\ \text{kg m}^{-1}\text{s}^{-1}

What controls viscosity …

Figure 5.16Gradation of velocity in the laminar flow

What this figure shows. A 3-D perspective diagram of three thin stacked parallelogram sheets (representing liquid layers), drawn in green, sitting one above another with a small vertical gap, viewed at an angle. The bottom-left corner of the stack is labelled 'Area of the plate A' with an arrow. Each of the three layers has a horizontal arrow projecting from its right edge showing its flow velocity: the topmost layer's arrow is labelled 'u + du', the middle layer's arrow is labelled 'u', and the bottom layer's arrow is labelled 'u - du' (arrows get progressively shorter/slower going down, illustrating the velocity gradient). Small vertical double-headed marks between the layers on the left side are labelled …