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Q.CH3-CH2-Cl + NaI --(acetone, heat)--> CH3-CH2-I + NaCl. The reaction is

(a) Wurtz reaction
(b) Fittig reaction
(c) Finkelstein reaction
(d) none of these
Jharkhand JacJAC Intermediate Board 2018MCQ· 1mImportance★★★★★
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Heating an alkyl halide with NaI in dry acetone replaces the halogen with iodine, precipitating NaCl (or NaBr) out of the acetone solution - this halide-exchange reaction is called the Finkelstein reaction.

CH3-CH2-Cl + NaI --(dry acetone, heat)--> CH3-CH2-I + NaCl.

This works because NaI is soluble in acetone while NaCl (and NaBr) are not, so the precipitation of NaCl continuously drives the equilibrium (Le Chatelier's principle) towards the iodide product. This general method - converting an alkyl chloride or bromide into the corresponding iodide using NaI/dry acetone - is known as the Finkelstein reaction, and is a standard laborat …

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