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Q.CH3CH2Cl + NaI --(Acetone)--> CH3CH2I + NaCl. The reaction is

(a) Wurtz reaction
(b) Finkelstein reaction
(c) Sandmeyer reaction
(d) Swarts reaction
Jharkhand JacJAC Intermediate Board 2023MCQ· 1mImportance★★★★★
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The Finkelstein reaction is the specific name for halide exchange using NaI in acetone, driven by NaCl's insolubility in acetone.

CH3CH2Cl + NaI --(acetone)--> CH3CH2I + NaCl

This is the Finkelstein reaction: NaI is soluble in dry acetone while the NaCl (or NaBr) byproduct is not, so it precipitates out, driving the equilibrium (Le Chatelier) towards the iodide product. (Wurtz reaction couples two alkyl halides with Na metal to form a larger alkane; Sandmeyer reaction …

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