Q.Suppose you are given a chance to repeat the alpha-particle scattering experiment using a thin sheet of solid hydrogen in place of the gold foil. (Hydrogen is a solid at temperatures below 14 K.) What results do you expect?
Concept understanding — Rutherford Scattering Distance
Rutherford Scattering Distance – From Intuition to Precision
Imagine you are firing a tiny, fast bullet at a large, heavy cannonball hidden inside a big cloud of cotton. Most bullets zip right through the cotton, barely slowing down. But a few bullets come very close to the cannonball itself. Those bullets get deflected sharply, sometimes even bouncing back.
The Rutherford scattering distance is the answer to this question: How close did that bullet get to the cannonball before it turned around?
In the real experiment, the "bullet" is an alpha particle (a helium nucleus, positively charged), the "cannonball" is the gold nucleus (also positively charged, and very heavy), and the "cotton" is the mostly empty space inside the gold atom. The alpha particle and the gold nucleus repel each other because both are positive. The closer the alpha particle gets, the stronger the repulsion.
The Intuitive Picture
Think of a ball rolling up a steep hill. The ball starts with some speed (kinetic energy). As it climbs, it slows down because gravity is pulling it back. At the very top of its climb, it stops for an instant — all its kinetic energy has been converted into gravitational potential energy. Then it rolls back down.
The alpha particle does the same thing, but with electric repulsion instead of gravity. It approaches the nucleus, slows down, stops at the closest possible point, and then flies back the way it came.
That closest point — the distance of closest approach — is the Rutherford scattering distance. It is the distance at which the alpha particle's initial kinetic energy is completely converted into electrostatic potential energy.
This distance is not the radius of the nucleus. It is the distance at which the alpha particle would just touch the nucleus if the nucleus were a point charge. In reality, the alpha particle never actually reaches the nucleus — it turns around before that.
The Precise Statement
Let an alpha particle with charge +2e and mass m approach a gold nucleus with charge +Ze (where Z=79 for gold). The alpha particle starts from very far away with initial kinetic energy K=21mv2.
At the distance of closest approach, call it r0, the alpha particle's speed becomes zero. All its kinetic energy has become electrostatic potential energy:
K=4πε01⋅r0(2e)(Ze)
Solving for r0:
r0=4πε01⋅K2Ze2
This is the Rutherford scattering distance (also called the distance of closest approach in a head-on collision).
What It Tells Us
- If the alpha particle hits the nucleus head-on, it comes exactly this close before reversing direction.
- If it misses slightly, it comes closer than r0? No — it comes less close. The head-on collision gives the minimum possible distance of closest approach for a given initial energy. Any sideways motion means the particle never gets as close.
- If the initial kinetic energy is larger, r0 becomes smaller — the alpha particle can punch closer to the nucleus before being stopped.
Do not confuse this with the impact parameter (the perpendicular distance from the nucleus to the initial line of motion). The impact parameter is a different quantity — it tells you how "off-center" the collision is. The Rutherford scattering distance r0 is the actual closest distance achieved during the collision, which depends on both the impact parameter and the initial energy.
A Quick Numerical Feel
For a typical alpha particle from radioactive decay (kinetic energy about 5 MeV) and a gold nucleus (Z=79):
r0≈5×106⋅1.6×10−199×109⋅2⋅79⋅(1.6×10−19)2≈4.5×10−14 m
That's about 45 femtometers — roughly 10,000 times smaller than the atom itself. This tiny number was the first direct evidence that the positive charge in an atom is concentrated in an incredibly small nucleus.
The Key Takeaway
Rutherford scattering distance is the distance at which an alpha particle, approaching a nucleus head-on, comes to a complete stop and reverses direction. It is given by:
r0=4πε01⋅K2Ze2
It is the minimum possible distance of closest approach for a given initial kinetic energy, and it revealed that the atom's positive charge is packed into a volume far smaller than the atom itself.
The distance of closest approach in Rutherford scattering is a classic numerical from the NCERT Class 12 Physics chapter on Atoms, regularly appearing in "Rutherford scattering distance of closest approach formula" searches and in JEE Main/NEET important-questions compilations on atomic structure. Mastering this derivation also builds the groundwork for later problems on nuclear size and the scale of the atom covered in the same chapter.
Why this formula?
Rutherford Scattering: Why the Distance of Closest Approach Formula Works
The distance of closest approach — often denoted d0 or r0 — is the minimum separation between an alpha particle and the nucleus in a head-on collision. It's a beautiful example of energy conservation doing all the heavy lifting.
The Physical Picture
Imagine an alpha particle (charge +2e) fired straight at a gold nucleus (charge +Ze). As it approaches, the Coulomb repulsion slows it down. At the point of closest approach, the alpha particle's radial velocity becomes zero — it stops moving toward the nucleus, and is about to turn around and fly back.
At that instant, all the kinetic energy it had at infinity has been converted into electrostatic potential energy. No other forces are at play (gravity is negligible, and we're far from the nuclear force range).
The Derivation in One Step
Let the alpha particle have initial kinetic energy K=21mv2 at a large distance (where potential energy is zero). At the distance of closest approach r0, its speed is zero, so kinetic energy is zero. Energy conservation gives:
21mv2=4πϵ01⋅r0(2e)(Ze)
r0=4πϵ01⋅K2Ze2
That's it. The formula is a direct consequence of energy conservation in a pure Coulomb field.
Why This Makes Physical Sense
- Higher kinetic energy → the alpha particle can push closer before being stopped → r0 is smaller.
- Higher nuclear charge Z → stronger repulsion → the alpha stops farther away → r0 is larger.
- The factor 2Ze2 comes from the product of charges: (2e)(Ze)=2Ze2.
This is the head-on distance. For non-head-on collisions (nonzero impact parameter), the distance of closest approach is larger because some energy remains in the perpendicular component of motion. The general formula involves the impact parameter b and scattering angle θ, but the head-on case gives the absolute minimum possible approach.
A Common Misconception
Students sometimes think the alpha particle "hits" the nucleus at r0. It doesn't — it's turned around purely by the electric field. The fact that Rutherford's experiment did see some alpha particles bounce back at large angles (implying they got very close) is what told him the nucleus must be extremely small — smaller than r0 for those particles. If the nucleus were larger, the alpha would have hit it and the scattering pattern would have been different.
The formula r0=4πϵ0K2Ze2 assumes the nucleus is point-like and stationary. In reality, the nucleus recoils slightly, so the reduced mass should technically be used. But for gold (A≈197) vs alpha (A=4), the correction is tiny — less than 2%.
The Deeper Insight
Rutherford didn't just measure r0 — he used it to set an upper limit on nuclear size. By observing that alpha particles with kinetic energy K were still being scattered (not absorbed), he knew the nucleus must be smaller than the corresponding r0. This gave the first experimental evidence that the atom's positive charge is concentrated in a region less than 10−14 m across — a thousand times smaller than the atom itself.
That's why this simple energy-conservation formula is historically monumental: it opened the door to the nuclear age.
The outcome is decided by the mass of the target nucleus, not by its charge alone. A solid-hydrogen sheet presents single protons (≈1 u), which are lighter than the incoming α-particle (4 u).
- Large-angle and back-scattering in the gold-foil experiment occurred because the gold nucleus (A≈197) is far heavier than the α and acts like a fixed wall.
- A proton is 4 times lighter than the α, so it recoils and carries off energy instead of turning the α around. A light target can never scatter a heavier projectile through a large angle.
- For an elastic collision of a heavier projectile (m=4 u) with a lighter stationary target (M=1 u), the projectile's deflection is bounded by
θmax=sin−1(mM)=sin−1(41)≈14.5∘.
So the α-particles emerge within about 14∘ of their original direction, with no back-scattering — the experiment would not reveal a tiny massive nucleus.
Only small-angle deflections (θ≤θmax≈14.5∘) and no back-scattering, because the proton target is lighter than the α-particle. The experiment would fail to show the large-angle scattering seen with gold.
A solid-hydrogen target is a single proton (≈1 u), lighter than the α-particle (4 u). A light target cannot throw a heavier projectile through a large angle, so there is no back-scattering — the α-particles pass through with only small deflections (at most ≈14.5∘).
1. Why the target mass is decisive. In the gold-foil experiment the large-angle (and back-) scattering arose because the gold nucleus (A≈197) is roughly 50 times heavier than the α-particle and behaves essentially like a fixed scattering centre. A proton, by contrast, is 4 times lighter than the α: instead of turning the α around, it recoils and is knocked forward.
2. Kinematic limit for a heavy projectile on a light target. For an elastic collision of a projectile of mass m=4 u with a stationary target of mass M=1 u (with m>M), the projectile's scattering angle in the lab frame can never exceed
θmax=sin−1(mM)=sin−1(41)≈14.5∘.
Hence every α-particle emerges within about 14∘ of its incident direction; none is deflected backwards.
3. Where the energy goes. Being light, the struck proton recoils and carries off a substantial share of the kinetic energy, while the α-particle continues almost straight ahead, only slightly slowed and slightly deflected.
4. Consequence for the experiment. The dramatic large-angle scattering that led Rutherford to infer a tiny, massive, positively charged nucleus would be absent. Repeating the experiment with solid hydrogen would therefore fail to reveal the nuclear structure of the atom.
The α-particles would suffer only small-angle deflections (at most θmax≈14.5∘) with no back-scattering, because the proton target is lighter than the α-particle. The experiment would not show the large-angle scattering — and hence the nucleus — seen with gold.
Method: Impact Parameter Analysis in Rutherford Scattering
This problem tests your understanding of how the impact parameter (the perpendicular distance between the alpha particle's initial path and the nucleus) determines the scattering angle — and how that depends on the nuclear charge of the target.
Step 1 — Recall the key relationship
For Rutherford scattering, the distance of closest approach r0 (for a head-on collision) is given by:
r0=4πε01⋅E2Ze2
where Z is the atomic number of the target nucleus, e is the electronic charge, and E is the kinetic energy of the alpha particle.
The scattering angle θ is related to the impact parameter b by:
b=4πε01⋅EZe2cot2θ
The scattering angle depends directly on Z — larger Z means stronger Coulomb repulsion, so larger scattering angles for the same impact parameter.
Step 2 — Compare the target nuclei
| Property | Gold (Au) | Hydrogen (H) |
|---|---|---|
| Atomic number Z | 79 | 1 |
| Nuclear charge | 79e | 1e |
| Nuclear mass | ~197 u | ~1 u |
The alpha particle itself has Z=2 and mass ~4 u.
Step 3 — Analyse the two key effects
Effect 1: Much weaker Coulomb repulsion
Since Z for hydrogen is 79 times smaller than for gold, the Coulomb force at the same distance is 79 times weaker. For the same impact parameter, the scattering angle will be drastically smaller. Most alpha particles will pass through with very little deflection — the scattering pattern will be much more concentrated near 0∘.
Effect 2: Recoil of the target nucleus
This is the critical difference. In gold, the nucleus is massive (~197 u) compared to the alpha particle (~4 u), so it barely moves — the scattering is essentially elastic with a fixed centre. But hydrogen has a nucleus of mass ~1 u, which is lighter than the alpha particle.
When a moving alpha particle collides with a stationary hydrogen nucleus, the hydrogen nucleus can recoil significantly. In fact, in a head-on collision, the alpha particle can transfer a large fraction of its energy to the proton.
The Rutherford scattering formula assumes a fixed, infinitely massive target nucleus. This assumption breaks down for hydrogen because the target is lighter than the projectile.
Step 4 — Predict the expected results
-
Most alpha particles will pass through with very small deflection angles (much smaller than with gold), because the nuclear charge is tiny.
-
A small fraction of alpha particles that come very close to a hydrogen nucleus will experience a large-angle scattering, but the kinematics will be different — the hydrogen nucleus will recoil, and the alpha particle will lose significant energy.
-
Head-on collisions will result in the alpha particle transferring most of its kinetic energy to the proton, and the alpha particle may even be scattered backwards in the centre-of-mass frame, but with much lower energy than in the gold case.
-
The scattering pattern will not follow the simple Rutherford 1/sin4(θ/2) law because the target recoil cannot be ignored.
In the actual experiment with gold foil, Rutherford observed a few alpha particles scattered through angles > 90∘. With hydrogen, such large-angle scattering would be even rarer due to the weak Coulomb force, and when it does occur, the alpha particle emerges with much less energy.
Final answer: With a solid hydrogen target, most alpha particles pass through undeflected or with tiny angles. Very few are scattered through large angles, and those that are lose significant energy to the recoiling proton. The classical Rutherford scattering formula does not apply because the target nucleus is lighter than the projectile.
Common Mistakes in the Rutherford Scattering Distance Problem (Hydrogen vs Gold Foil)
This question from the NCERT/CBSE syllabus tests your understanding of how the scattering formula depends on the nuclear charge Z and the target thickness. Students typically make four distinct errors here.
Mistake 1: Forgetting that hydrogen has Z=1
The most common error is to treat hydrogen as having the same nuclear charge as gold (Z=79). The distance of closest approach in Rutherford scattering is given by:
r0=4πε01⋅mv22Ze2
Since r0∝Z, using hydrogen (Z=1) instead of gold (Z=79) means the distance of closest approach becomes 79 times smaller. Students often miss this factor entirely.
Do not assume "solid" means "dense like a metal" — hydrogen is a monovalent element with a single proton in its nucleus. Its nuclear charge is the smallest possible.
How to avoid: Always write down the proportionality r0∝Z before plugging numbers. Compare the Z values explicitly: ZAu=79, ZH=1.
Mistake 2: Ignoring the target thickness effect
Students often compare only the nuclear charge and forget that the foil is a thin sheet of solid hydrogen. The number of target nuclei per unit area (Nt) matters because the scattering probability depends on it.
For a given foil thickness t and number density n:
Nt=n⋅t
Solid hydrogen has a much lower density than gold. At 14 K, solid hydrogen has a density of about 0.086 g/cm3, compared to gold's 19.3 g/cm3. The number density of hydrogen nuclei is:
nH=MHρHNA≈1.0080.086×6.02×1023≈5.1×1022 atoms/cm3
For gold:
nAu=19719.3×6.02×1023≈5.9×1022 atoms/cm3
Surprisingly, the number densities are comparable! But the scattering cross-section per nucleus is proportional to Z2, so the overall scattering rate drops by a factor of 792≈6240 for the same thickness.
The number of scattered alpha particles N(θ)∝NtZ2. Even with similar Nt, the Z2 factor dominates.
How to avoid: Always check both factors: nuclear charge Z and target thickness Nt. Write the full proportionality:
N(θ)∝sin4(θ/2)NtZ2
Mistake 3: Claiming "no scattering" or "all alpha particles pass through"
Some students conclude that because hydrogen has a tiny nucleus, alpha particles will never be scattered. This is incorrect — scattering still occurs, but the angles are much smaller and the probability of large-angle scattering is drastically reduced.
The impact parameter b for a given scattering angle θ is:
b=4πε01⋅mv2Ze2⋅cot(2θ)
Since b∝Z, for the same scattering angle, the impact parameter with hydrogen is 79 times smaller than with gold. This means only alpha particles that come extremely close to the hydrogen nucleus (within about 10−15 m) will scatter at large angles.
| Property | Gold (Z=79) | Hydrogen (Z=1) |
|----------|---------------|-------------------|
| Distance of closest approach (for head-on collision) | ≈3×10−14 m | ≈4×10−16 m |
| Impact parameter for 90∘ scattering | ≈3×10−14 m | ≈4×10−16 m |
| Relative scattering probability (same θ) | 1 | ≈1/6240 |
How to avoid: State clearly: "Scattering still occurs, but the cross-section is smaller by a factor of Z2=6241, so large-angle scattering events become extremely rare."
Mistake 4: Confusing the target with the projectile
A subtle error: some students think that because hydrogen is light, the alpha particle might knock the hydrogen nucleus out of the foil (like in a collision between billiard balls). While this is true for close collisions (the hydrogen nucleus can recoil), the question specifically asks about Rutherford scattering of the alpha particle itself.
The Rutherford formula assumes the target nucleus is stationary and heavy. For hydrogen, this assumption breaks down for very close collisions — the hydrogen nucleus recoils significantly. However, for the typical scattering experiment, the alpha particle is much heavier than the proton (mα≈4mp), so the correction is not drastic.
The Rutherford scattering formula is derived assuming the target nucleus is infinitely heavy. For hydrogen, a reduced mass correction is needed for precise work, but at the NCERT level, the Z2 factor is the key point.
How to avoid: Mention that the hydrogen nucleus can recoil, but the dominant effect is still the Z2 reduction in scattering cross-section.
Final Expected Answer
N(θ)∝sin4(θ/2)NtZ2
With a solid hydrogen foil:
- The distance of closest approach decreases by a factor of 79.
- The scattering probability at any given angle decreases by a factor of 792≈6240.
- Large-angle scattering becomes extremely improbable — most alpha particles pass through undeflected or with very small deflections.
- The foil must be kept at cryogenic temperatures (below 14 K) to remain solid.
- COMEDK 2024Set 2024-E1 markMCQQ.The distance of closest approach when an alpha particle of kinetic energy 6.5 MeV strikes a nucleus of atomic number 50 is (A) 0.221 fm (B) 1.101 fm (C) 0.0221 fm (D) 4.42 fm
›Reveal solutionSolution
The distance of closest approach is found by equating the initial kinetic energy to the electrostatic potential energy at the turning point. For a 6.5 MeV alpha particle and a nucleus with Z=50, the result is about 22 fm, which corresponds to option (C) 0.0221 pm (since 1 pm = 1000 fm, 22 fm = 0.022 pm).
Concept & Intuition
When an alpha particle (charge 2e) is fired head-on toward a heavy nucleus (charge Ze), it slows down as it climbs the Coulomb potential hill. At the point of closest approach, its kinetic energy has been completely converted into electrostatic potential energy — it momentarily stops before being repelled back. This is a pure energy conservation problem:
Kinitial=4πε01rmin(2e)(Ze)
Solving for rmin gives the distance of closest approach. The trick is to use consistent units — nuclear physicists often work in MeV and femtometers, using the handy constant e2/(4πε0)≈1.44 MeV⋅fm.
Step-by-step solution
- Write the energy conservation equation At the turning point, all kinetic energy K becomes Coulomb potential energy:
K=4πε01rmin(2e)(Ze)
Here Z=50 (atomic number of the target nucleus), and the alpha particle has charge 2e.
- Solve for rmin
rmin=4πε01K2Ze2
- Use the convenient constant The product 4πε0e2≈1.44 MeV⋅fm. So:
rmin=K2Z×1.44 MeV⋅fm
- Plug in numbers Z=50, K=6.5 MeV:
rmin=6.52×50×1.44 fm
rmin=6.5144 fm≈22.15 fm
-
Convert to the units used in the options
The options are given in fm (femtometers) but note that (C) is 0.0221 fm — that’s suspiciously small. Actually, check: 22.15 fm = 22.15×10−15 m. But 1 picometer (pm) = 10−12 m = 1000 fm. So 22.15 fm = 0.02215 pm. The options list (C) as 0.0221 fm — but that would be 0.0221 fm, which is 1000 times smaller. Wait — let’s re-read the options carefully:
(A) 0.221 fm
(B) 1.101 fm
(C) 0.0221 fm
(D) 4.42 fm
Our computed value is ~22 fm, which is not among these. This suggests the options might actually be in picometers (pm) but mislabeled? Let’s check: 22 fm = 0.022 pm. That matches 0.0221 — so option (C) is almost certainly meant to be 0.0221 pm (or equivalently 22.1 fm). In many textbooks, the distance of closest approach for such parameters is indeed about 22 fm.
Watch outA common mistake is to forget that 1 fm = 10−15 m, while 1 pm = 10−12 m. The number 0.0221 looks tiny in fm but is actually ~22 fm when expressed properly. Always check the unit context — here the intended unit is likely picometers, making (C) correct.
- Final check Using exact values:
rmin=6.52×50×1.44=6.5144=22.1538 fm
Rounded to three significant figures: 22.2 fm = 0.0222 pm. Option (C) says 0.0221 fm — but that’s a factor of 1000 off unless the unit is pm. Given typical exam conventions, (C) is the intended answer.
✓Final answerThe correct option is (C).
ANSWER: C
- COMEDK 2024Set 2024-M1 markMCQQ.The closest approach of an alpha particle when it make a head on collision with a gold nucleus is 10×10−14 m, then the kinetic energy of the alpha particle is : (A) 3640 J (B) 3.64 J (C) 3.64×10−16 J (D) 3.64×10−13 J
›Reveal solutionSolution
The kinetic energy of the alpha particle equals the electrostatic potential energy at the distance of closest approach. Using Coulomb’s law, the energy is found to be about 3.64×10−13J, which corresponds to option (D).
Concept and intuition:
When an alpha particle (charge +2e) is fired head-on at a gold nucleus (charge +79e), it slows down as it approaches because of the repulsive electrostatic force. At the point of closest approach, its speed becomes zero — all its initial kinetic energy has been converted into electrostatic potential energy. So we can equate the kinetic energy K to the potential energy U at that distance r:
K=4πε01r(2e)(79e)
This is a direct application of energy conservation in a purely electrostatic field.
Step-by-step solution:
-
Identify the charges and constants
Alpha particle charge: q1=2e=2×1.6×10−19C
Gold nucleus charge: q2=79e=79×1.6×10−19C
Distance of closest approach: r=10×10−14m=10−13m
Coulomb constant: k=4πε01=9×109N⋅m2/C2
-
Write the potential energy formula
U=krq1q2
- Substitute the values
U=(9×109)⋅10−13(2×1.6×10−19)⋅(79×1.6×10−19)
- Simplify step by step First, compute the product of charges:
(2×1.6×10−19)×(79×1.6×10−19)=2×79×(1.6)2×10−38
2×79=158 and (1.6)2=2.56, so:
158×2.56=404.48
Thus numerator = 404.48×10−38C2
Now divide by r=10−13m:
10−13404.48×10−38=404.48×10−25
Multiply by k=9×109:
U=9×109×404.48×10−25=3640.32×10−16
Which is 3.64032×10−13J.
- Round to match the options This is 3.64×10−13J.
Watch outA common mistake is forgetting that the distance is given as 10×10−14m, which is 10−13m, not 10−14m. Also, be careful with the exponent when multiplying powers of ten.
TipYou can avoid large exponents by working in electronvolts: K=rk⋅2e⋅79e. Plugging numbers gives about 2.27MeV, which converts to 3.64×10−13J (since 1eV=1.6×10−19J).
✓Final answerThe correct option is (D).
ANSWER: D
-
- COMEDK 2023Set 2023-E1 markMCQQ.In the head-on collision of two alpha particles α1 and α2 with the gold nucleus, the closest approaches are 31.4 fermi and 94.2 fermi respectively. Then the ratio of the energy possessed by the alpha particles α2/α1 is: (A) 1:3 (B) 9:1 (C) 3:1 (D) 1:9
›Reveal solutionSolution
At closest approach kinetic energy converts fully to Coulomb potential, so r∝1/E; the larger closest approach means smaller energy, giving Eα2:Eα1=1:3.
At the distance of closest approach r, all kinetic energy E becomes electrostatic potential energy:
E=4πε01rqαqAu⟹r∝E1.
Same charges for both alphas and the same gold nucleus, so
E1E2=r2r1=94.231.4=31.
Hence α2:α1=1:3.
✓Final answerThe correct option is (A) — 1:3
- KCET 2022Set B-31 markMCQQ.In accordance with the Bohr’s model, the quantum number that characterizes the Earth’s revolution around the sun in an orbit of radius 1.5×1011m with orbital speed 3×104 ms−1 is [given mass of Earth=6×1024kg] (A) 8.57×1064 (B) 2.57×1074 (C) 5.98×1066 (D) 2.57×1038
›Reveal solutionSolution
Bohr’s quantization of angular momentum applies to any orbital motion — treat Earth’s revolution as a giant quantum orbit. The quantum number is n≈2.57×1074, matching option (B).
The key idea is that Bohr’s model isn’t limited to electrons. It says angular momentum in any bound orbital motion comes in integer multiples of 2πh (i.e., ℏ). For Earth going around the Sun, we can compute its classical angular momentum and then see which integer n it corresponds to.
- Write Bohr’s quantization condition Bohr’s postulate:
mvr=n2πh=nℏ
Here m is Earth’s mass, v its orbital speed, r the orbit radius, h Planck’s constant, and n the quantum number we want.
-
Plug in the given numbers
- m=6×1024 kg
- v=3×104 m/s
- r=1.5×1011 m
- h=6.63×10−34 J⋅s (standard value)
First compute the classical angular momentum:
L=mvr=(6×1024)×(3×104)×(1.5×1011)
Multiply stepwise:
6×3×1.5=27
Powers of ten: 1024×104×1011=1039
So L=27×1039=2.7×1040 kg⋅m2/s
- Find n From L=nℏ, we have
n=ℏL=2π6.63×10−342.7×1040
Compute ℏ:
ℏ=2×3.14166.63×10−34≈1.055×10−34 J⋅s
Then
n=1.055×10−342.7×1040≈2.56×1074
Rounding gives 2.57×1074.
Watch outA common mistake is to forget the 2π in ℏ=h/2π and use h directly — that would give an answer off by a factor of about 6, leading to a wrong option.
TipNotice how enormous n is — this tells you that Earth’s orbit is a very high quantum state, so classical physics is an excellent approximation. The correspondence principle at work.
✓Final answerThe quantum number is 2.57×1074, which corresponds to option (B).
- KCET 2022Set B-31 markMCQQ.If an electron is revolving in its Bohr orbit having Bohr radius of 0.529 A∘, then the radius of third orbit is (A) 4.761 A∘ (B) 5125 nm (C) 4234 nm (D) 4.496 A∘
›Reveal solutionSolution
The Bohr orbit radius scales as rn=n2a0; multiply the given first-orbit (Bohr) radius by n2=9 to get the third orbit's radius.
Step 1 — The Bohr radius formula
In Bohr's model of the hydrogen-like atom, the radius of the n-th permitted orbit is
rn=n2a0
where a0 is the radius of the first orbit (n=1), called the Bohr radius. Here a0=0.529 A∘ is given directly (its theoretical value a0=mee24πε0ℏ2≈0.529 A∘ is exactly this number, so no separate derivation of a0 is needed).
Step 2 — Apply for the third orbit
For the third orbit, n=3, so n2=9:
r3=9×a0=9×0.529 A∘=4.761 A∘
Step 3 — Check the other options
- (B) 5125 nm and (C) 4234 nm are both off by orders of magnitude (1 A∘=0.1 nm, so a Bohr-orbit radius here should be a few A∘ — a few tenths of a nanometre — not thousands of nanometres); these are unit-scale distractors.
- (D) 4.496 A∘ does not equal 9×0.529 and does not follow from the n2 scaling law.
✓Final answerThe correct option is (A) — 4.761 A∘.
- KCET 2020Set A-11 markMCQQ.Angular momentum of an electron in hydrogen atom is 2π3h (h is the Planck's constant). The K.E. of the electron is (A) 4.35 eV (B) 1.51 eV (C) 3.4 eV (D) 6.8 eV
›Reveal solutionSolution
Read off n from Bohr's angular-momentum quantisation, then use K.E.=+n213.6 eV (kinetic energy is the negative of the total energy in a Coulomb orbit).
Step 1 — Find the orbit number n.
Bohr's second postulate quantises angular momentum in units of h/2π:
L=2πnh.
Given L=2π3h, comparing gives
n=3.
Step 2 — Relate kinetic energy to total energy.
For an electron bound by the Coulomb force, the electrostatic attraction supplies the centripetal force:
r2ke2=rmv2⟹K21mv2=2rke2,U=−rke2=−2K.
Hence the total energy E=K+U=−K, i.e. K=−E (the virial theorem for an inverse-square field).
Step 3 — Put in the hydrogen energy level.
En=−n213.6 eV=−3213.6=−913.6=−1.51 eV.
Step 4 — Kinetic energy.
K=−E3=+1.51 eV.
Note the traps: 3.4eV and 6.8eV correspond to n=2 (they are ∣E2∣ and 2∣E2∣), and would be picked by anyone who mis-reads n or confuses K with ∣U∣.
✓Final answerThe correct option is (B) — 1.51 eV.
ANSWER: B
- KCET 2018Set A-11 markMCQQ.The total energy of an electron revolving in the second orbit of hydrogen atom is (A) −13.6 eV (B) −1.51 eV (C) −3.4 eV (D) Zero
›Reveal solutionSolution
Bohr's energy formula En=−13.6/n2 eV, evaluated at n=2.
Step 1 — The Bohr energy levels of hydrogen.
Bohr's model gives the total energy (kinetic + electrostatic potential) of the electron in the n-th orbit as
En=−8ε02h2n2me4=−n213.6 eV
The energy is negative because the electron is bound: work must be done to pull it to infinity, where E=0.
Step 2 — Substitute n=2 (the second orbit).
E2=−2213.6=−413.6=−3.4 eV
Step 3 — Check the distractors.
- −13.6 eV is E1 — the ground state (n=1), not the second orbit.
- −1.51 eV is E3=−13.6/9 — the third orbit.
- Zero is the energy of a free electron at n→∞ (the ionised atom). Only −3.4 eV corresponds to n=2.
✓Final answerThe correct option is (C) — −3.4 eV.
ANSWER: C
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