Q.Monochromatic light of frequency 6.0×1014 Hz is produced by a laser. The power emitted is 2.0×10−3 W.
Concept understanding — Photon Energy
Photon Energy: The Energy Carried by Light
Light does not carry its energy in a continuous stream. It comes in discrete packets — like individual drops instead of a steady hose. Each packet is called a photon: the smallest possible unit of light of a given frequency. You cannot have half a photon; it is all or nothing.
The Intuition: Colour Determines Energy
Red light and blue light are both light, but they behave differently — blue light causes sunburn and drives chemical reactions more readily than red. The reason is that the colour (frequency) of light directly fixes how much energy each photon carries, and blue photons carry more energy than red photons.
The Planck–Einstein Relation
The energy E of a single photon is directly proportional to its frequency f, and inversely proportional to its wavelength λ:
E=hf=λhc
Where:
- E = energy of one photon (joules, J)
- f = frequency (hertz, Hz)
- λ = wavelength (metres, m)
- c = speed of light in vacuum (3.00×108 m/s)
- h = Planck's constant (6.626×10−34 J·s)
Planck's constant h is extremely tiny, so an individual photon carries a very small amount of energy — which is why we never feel single photons striking our skin.
What This Tells You
- Higher frequency = higher energy. Gamma rays have extremely energetic photons; radio waves have very low-energy photons.
- Shorter wavelength = higher energy. Ultraviolet photons are more energetic than visible-light photons; infrared photons are less.
- Energy is quantised. Light energy comes in fixed packets — you can have 1, 2, or 1000 photons, but never 0.5. This was Max Planck's revolutionary idea of 1900.
This is why UV light causes sunburn (UV photons carry enough energy to damage DNA, while visible photons do not), why X-ray photons are energetic enough to pass through soft tissue but get absorbed by bone, and why a photon needs enough energy to actually break a bond or drive a photochemical/biological reaction, rather than merely wavelength-dependent intensity.
A Concrete Example
Question: Which has more energy — a photon of red light (λ=700 nm) or a photon of blue light (λ=450 nm)?
Since E=λhc, energy is inversely proportional to wavelength, so the shorter-wavelength blue photon carries more energy:
- Red: Ered=700×10−9(6.626×10−34)(3.00×108)≈2.84×10−19 J
- Blue: Eblue=450×10−9(6.626×10−34)(3.00×108)≈4.42×10−19 J
The blue photon carries about 1.5 times the energy of the red photon.
A common mistake is to think brighter light means more energetic photons. Brightness is the number of photons per second, not the energy per photon. A bright red light has many low-energy photons; a dim blue light has fewer but higher-energy ones.
The Big Picture
Photon energy is the bridge between the wave nature of light (frequency, wavelength) and its particle nature (energy packets) — one of the foundational ideas of quantum mechanics: at the smallest scales, energy is not continuous but comes in discrete, indivisible units.
Photon energy, given by the Planck-Einstein relation E = hf, is one of the most fundamental formulas in the NCERT Class 12 Physics Dual Nature of Radiation and Matter chapter, and "photon energy formula and calculation" is a heavily searched query among students preparing for CBSE boards, JEE Main, and NEET. Because this idea links directly to the photoelectric effect and atomic spectra, it also anchors several "modern physics important questions" compiled for competitive-exam revision.
Why this formula?
Why Photon Energy is E=hf — The Reasoning Behind the Formula
The formula E=hf is not something you memorise and plug numbers into. It comes from a deep shift in how physicists understood light.
The problem that forced the formula
By the late 1800s, classical physics said light was a wave — continuous, carrying energy in proportion to its intensity (brightness). But blackbody radiation and the photoelectric effect showed something bizarre: when you shine light on a metal, electrons are ejected only if the light's frequency is above a certain threshold, no matter how bright the light is. Below that frequency, even the brightest lamp won't kick out a single electron. Classically this made no sense — a wave's energy depends on amplitude, not frequency.
Einstein's radical idea (1905)
Einstein proposed that light comes in discrete packets — photons — each carrying a fixed energy that depends only on its frequency, with Planck's constant h as the proportionality:
A single photon's energy is E=hf, where f is the frequency of the light.
This directly explains the photoelectric effect: an electron needs a minimum energy (the work function ϕ) to escape. If a photon's energy hf<ϕ, no electron is ejected — regardless of how many photons you send, because each photon interacts with one electron individually.
E=hf is not derived from deeper principles — it is a postulate justified by the experiments it explains, and it unified optics with quantum mechanics.
The equivalent forms
Since c=fλ for light in vacuum, the same idea in terms of wavelength is:
E=λhc
Use this when you're given λ instead of f. A photon also carries momentum (despite having no mass):
p=cE=λh
This follows from special relativity: E2=(pc)2+(mc2)2, and for a photon m=0, so E=pc, hence p=h/λ.
- h=6.626×10−34 J⋅s (Planck's constant)
- c=3.0×108 m/s (speed of light)
- For atomic-scale problems use electronvolts: 1 eV=1.602×10−19 J
A common exam trap
E=hf means higher frequency = more energy per photon — true. But a brighter light does not mean higher photon energy. Intensity is the number of photons per second per area; each photon still carries hf.
Do not confuse intensity (number of photons) with frequency (energy per photon). They are independent.
Final answer: E=hf
Concept: Photon Energy — each photon carries a discrete quantum of energy E=hν, where h is Planck’s constant and ν is the frequency.
(a) Energy of one photon:
E=hν=(6.63×10−34)(6.0×1014)=3.978×10−19 J
(b) Power P is energy per second. If n photons are emitted each second, total energy per second is nE=P. Hence:
n=EP=3.978×10−192.0×10−3≈5.03×1015
- The energy of a photon is 3.98×10−19 J;
- the number of photons emitted per second is 5.0×1015.
The energy of a single photon is found using E=hν, giving 3.98×10−19 J. The number of photons emitted per second is the total power divided by the photon energy, yielding 5.0×1015 photons/s.
Why Photon Energy Matters Here
Light is not a continuous stream of energy — it comes in discrete packets called photons. Each photon carries a specific energy that depends only on the frequency (or wavelength) of the light, not on the intensity. The laser's power tells us how much total energy is delivered per second. To find how many photons leave the laser each second, we simply divide the total energy per second (power) by the energy carried by one photon.
This is a clean, two-step problem: first find the energy of one photon, then count how many such photons make up the total power.
Step-by-Step Solution
1. Energy of a single photon
The energy E of one photon is given by the Planck-Einstein relation:
E=hν
where
h=6.626×10−34 J⋅s (Planck's constant)
ν=6.0×1014 Hz (frequency)
Substitute:
E=(6.626×10−34)×(6.0×1014)
E=3.9756×10−19 J
Rounding to two significant figures (matching the given data):
E≈3.98×10−19 J
Ephoton=hν
If you ever forget the value of h, remember it's roughly 6.63×10−34 J⋅s. For quick mental checks: light of frequency 5×1014 Hz (yellow-green) has photon energy about 3.3×10−19 J.
2. Number of photons emitted per second
Power P is energy per unit time. If each photon carries energy E, then the number of photons emitted per second n satisfies:
P=n×E
So:
n=EP
Given P=2.0×10−3 W (which is 2.0×10−3 J/s):
n=3.9756×10−192.0×10−3
n=5.03×1015 photons/s
Rounding to two significant figures:
n≈5.0×1015 photons/s
A common mistake is to forget that power is already in joules per second — no extra conversion is needed. Also, be careful with exponents: 10−3 divided by 10−19 gives 1016, not 10−22.
The energy of a photon is 3.98×10−19 J and the number of photons emitted per second is 5.0×1015 photons/s.
Method: Photon Energy Approach (using Planck's relation)
This problem uses the fundamental idea that light energy comes in discrete packets called photons. The energy of each photon depends only on the frequency of the light, not on the power. Power tells us how much total energy is delivered per second, so dividing that by the energy per photon gives the number of photons per second.
(a) Energy of a single photon
Step 1: Recall Planck's relation — the energy of one photon is directly proportional to its frequency:
E=hf
where h=6.63×10−34 J⋅s (Planck's constant) and f is the frequency in hertz.
Step 2: Substitute the given frequency:
E=(6.63×10−34)(6.0×1014)
Step 3: Multiply the numbers and the powers of ten separately:
6.63×6.0=39.78
10−34×1014=10−20
So E=39.78×10−20 J=3.978×10−19 J
Always check the exponent: 10−34×1014=10−20, not 10−48 — a common slip.
Step 4: Round to two significant figures (since the given frequency has two significant figures):
E=4.0×10−19 J
(b) Number of photons emitted per second
Step 1: Understand what power means. Power P=2.0×10−3 W means the source delivers 2.0×10−3 joules of energy each second.
Step 2: If each photon carries E joules, then the number of photons emitted per second, n, is:
n=energy per photontotal energy per second=EP
Step 3: Substitute the values:
n=4.0×10−192.0×10−3
Step 4: Divide the coefficients and subtract the exponents:
4.02.0=0.5
10−1910−3=1016
So n=0.5×1016=5.0×1015
Dividing powers of ten: 10−3÷10−19=10−3−(−19)=1016. The minus of a minus becomes plus.
n=5.0×1015 photons per second
Final answers:
- Energy of one photon = 4.0×10−19 J
- Number of photons emitted per second = 5.0×1015
Common Mistakes & How to Avoid Them
Mistake 1: Using the wrong formula for photon energy
Students often confuse E=hf with E=λhc. Both are correct, but the first is direct when frequency is given. The second requires an extra step (converting frequency to wavelength) and introduces more places for error — like using the wrong value for c or forgetting to convert units.
How to avoid: When frequency is given, use E=hf directly. Only switch to E=hc/λ when wavelength is provided. Memorise both forms but pick the one that matches the data.
If the problem gives frequency, your first instinct should be E=hf. No conversions needed.
Mistake 2: Forgetting the value of Planck's constant or using the wrong one
Planck's constant h is 6.63×10−34 J⋅s. Some students use 6.6×10−34 (acceptable in some boards, but risky) or accidentally use h=4.14×10−15 eV⋅s when the answer is expected in joules.
How to avoid: Write down h=6.63×10−34 J⋅s at the top of your working. If the question asks for energy in joules (which it usually does unless specified), stick to this value. If you must use the eV version, convert at the end — don't mix units mid-calculation.
Mistake 3: Incorrect exponent handling in part (a)
The calculation is:
E=(6.63×10−34)(6.0×1014)
Students often add exponents incorrectly: 10−34×1014=10−20, not 10−48 or 10−20 with a sign error. Also, they sometimes forget to multiply the coefficients: 6.63×6.0≈39.78, not 3.978.
How to avoid: Separate the calculation into two parts:
- Multiply the coefficients: 6.63×6.0=39.78
- Add the exponents: −34+14=−20
- Combine: 39.78×10−20=3.978×10−19
Then round to appropriate significant figures (here, two significant figures from the given data gives 4.0×10−19 J).
10−34×1014=10−20, not 10−48 (that's multiplying exponents instead of adding them). This is the single most common exponent error.
Mistake 4: Confusing power with energy in part (b)
Power P=2.0×10−3 W means 2.0×10−3 J of energy is emitted per second. Some students treat power as the total energy or forget that it's already a rate.
How to avoid: Write down what power means: P=tEtotal. For t=1 s, Etotal=P×1=P. So the number of photons per second is:
n=energy per photontotal energy per second=EP
Mistake 5: Dividing in the wrong order
Students sometimes compute E/P instead of P/E, getting a tiny fraction instead of a large number.
How to avoid: Check the units. You want photons per second, which has units of s−1. P has units J/s, E has units J. So P/E gives JJ/s=s−1, which is correct. E/P gives seconds — a time, not a rate.
Unit check: JW=JJ/s=s−1. Always verify your formula by checking what units it produces.
Mistake 6: Arithmetic errors in part (b)
n=4.0×10−192.0×10−3=0.5×1016=5.0×1015
Common errors: dividing coefficients as 2.0/4.0=0.5 but then writing 0.5×10−16 (sign error on exponent), or forgetting that 10−3/10−19=1016.
How to avoid: Again, separate coefficient and exponent:
- Coefficients: 2.0/4.0=0.5
- Exponents: −3−(−19)=−3+19=16
- Combine: 0.5×1016=5.0×1015
Final Answers
(a) E=hf=4.0×10−19 J
(b) n=EP=5.0×1015 photons per second
- KCET 2024Set D-21 markMCQQ.The ratio of area of first excited state to ground state of orbit of hydrogen atom is (A) 1:16 (B) 1:4 (C) 4:1 (D) 16:1
›Reveal solutionSolution
r∝n2⇒ area ∝n4; for n=2 vs n=1 that is 24:14=16:1.
Step 1 — Bohr's radius formula
For a hydrogen-like atom, Bohr's quantisation of angular momentum (mvr=nℏ) combined with the Coulomb-force–centripetal-force balance gives
rn=πme2Zn2h2ε0⟹rn∝n2 (for fixed Z)
For hydrogen (Z=1), rn=n2a0 with a0=0.529 A˚.
Step 2 — From radius to area
The orbit is a circle, so the area enclosed is
An=πrn2
Since rn∝n2,
An∝(n2)2=n4
This n4 (not n2) is the crux of the question — the squaring of an already-squared quantity.
Step 3 — Identify the two states
- Ground state: n=1.
- First excited state: the next level up, n=2. (Not n=3 — the "first excited" state is the first level above the ground state.)
Step 4 — Take the ratio
A1A2=πr12πr22=(12a0)2(22a0)2=(a0)2(4a0)2=a0216a02=16
The question asks for first excited : ground, i.e.
A2:A1=16:1
Step 5 — Guard against the traps
- 4:1 (option C) is the ratio of the radii, not the areas.
- 1:4 and 1:16 have the ratio inverted — the excited orbit is bigger, so the ratio must be greater than 1.
✓Final answerThe correct option is (D) — 16:1.
ANSWER: D
- COMEDK 2024Set 2024-M1 markMCQQ.The difference in energy levels of an electron at two excited levels is 13.75 eV. If it makes a transition from the higher energy level to the lower energy level then what will be the wave length of the emitted radiation? [given h=6.6×10−34 m2 kg s−1;c=3×108 ms−1;1 eV=1.6×10−19 J] (A) 900 nm (B) 90 A (C) 9000 nm (D) 900∘A
›Reveal solutionSolution
Using E=hc/λ, the 13.75 eV energy difference corresponds to a wavelength of 90 nm, i.e. 900 Å — matching option (D).
Step-by-step reasoning
- Convert the energy to joules.
E=13.75 eV×1.6×10−19 J/eV=2.2×10−18 J
- Solve for wavelength.
λ=Ehc=2.2×10−18(6.6×10−34)(3×108)=2.2×10−1819.8×10−26=9.0×10−8 m
- Convert to convenient units.
9.0×10−8 m=90 nm=900 A˚(since 1 nm=10 A˚)
This matches the option listing 900 Å.
Watch outDon't confuse nm and Å — 1 nm equals 10 Å, not 100 Å. Here 90 nm equals 900 Å.
TipQuick shortcut: E(eV)≈λ(nm)1240, so λ≈1240/13.75≈90.2 nm — confirming the result fast.
✓Final answerThe correct option is (D): 900 Å.
- KCET 2022Set B-31 markMCQQ.The radius of hydrogen atom in the ground state is 0.53 A∘. After collision with an electron, it is found to have a radius of 2.12 A∘, the principle quantum number 'n' of the final state of the atom is (A) n = 3 (B) n = 4 (C) n = 1 (D) n = 2
›Reveal solutionSolution
Bohr radii go as n2; the radius has grown by a factor of 4, so n2=4 and the atom is excited to n=2.
1. The Bohr radius law
Quantising the angular momentum (mvr=nh/2π) and balancing the Coulomb force against the centripetal requirement gives, for a hydrogen-like atom,
rn=πme2Zn2h2ε0=Zn2a0
where a0=0.53 A˚ is the Bohr radius. For hydrogen Z=1, so simply
rn=n2a0
The radius grows as the square of the principal quantum number — that quadratic dependence is the whole content of the problem.
2. Set up the ratio
Ground state: r1=0.53 A˚ (with n=1, consistent with the formula).
Final state after the collision: rn=2.12 A˚.
Taking the ratio kills a0 entirely:
r1rn=12a0n2a0=n2
3. Solve
n2=0.532.12=4
n=4=2
4. Physical reading
The collision with the electron transferred just enough energy to lift the atom from the ground state to the first excited state. Check consistency with the energy ladder: En=−13.6/n2 eV, so E2−E1=−3.4−(−13.6)=10.2 eV — precisely the well-known first excitation energy of hydrogen. Everything is self-consistent.
(Trap: option (C) n=1 would mean nothing happened, and n=3 or 4 would require the radius to be 9a0=4.77 A˚ or 16a0=8.48 A˚, not 2.12 A˚.)
✓Final answerThe correct option is (D) — n = 2.
ANSWER: D
- KCET 2019Set A-11 markMCQQ.Frequency of revolution of an electron revolving in nth orbit of H-atom is proportional to (A) n21 (B) n (C) n independent of n (D) n31
›Reveal solutionSolution
The frequency of revolution of an electron in the nth orbit of a hydrogen atom is proportional to n31, making option (D) correct.
The key here is to connect the frequency of revolution — how many times per second the electron circles the nucleus — to the orbital radius and velocity. In Bohr's model, the electron moves in a circular orbit under electrostatic attraction, and its angular momentum is quantized. Frequency is simply v/(2πr), so if we find how v and r depend on n, we can combine them.
Let's work through it step by step.
- Write the force balance for a stable orbit. The centripetal force is provided by the Coulomb attraction between the electron and the proton:
rmv2=r2ke2
where m is the electron mass, v its speed, r the orbit radius, k=1/(4πϵ0), and e the elementary charge.
- Apply Bohr's quantization condition. Angular momentum is an integer multiple of ℏ=h/(2π):
mvr=nℏ
- Solve for r in terms of n. From the quantization condition, v=nℏ/(mr). Substitute into the force equation:
rm(mrnℏ)2=r2ke2
Simplify:
mr3n2ℏ2=r2ke2
Multiply both sides by r3:
mn2ℏ2=ke2r
So:
r=mke2n2ℏ2
This shows r∝n2.
- Find v in terms of n. From mvr=nℏ, we have v=nℏ/(mr). Substitute r∝n2:
v∝n2n=n1
So v∝1/n.
- Now compute the frequency of revolution. Frequency f is the number of orbits per second:
f=2πrv
Substitute the proportionalities v∝1/n and r∝n2:
f∝n21/n=n31
Watch outA common mistake is to think frequency is proportional to 1/n2 because energy is proportional to 1/n2. But frequency here is mechanical revolution frequency, not the frequency of emitted radiation (which relates to energy differences). They are different quantities.
TipYou can also derive this directly from the known expressions: rn=n2a0 and vn=αc/n, where a0 is the Bohr radius and α the fine-structure constant. Then f=vn/(2πrn)∝(1/n)/(n2)=1/n3.
✓Final answerThe frequency of revolution is proportional to n31, so the correct option is (D).
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