Q.The wavelength of a photon needed to remove a proton from a nucleus which is bound to the nucleus with 1 MeV energy is nearly
Concept understanding — Photon Energy
Photon Energy: The Energy Carried by Light
Light does not carry its energy in a continuous stream. It comes in discrete packets — like individual drops instead of a steady hose. Each packet is called a photon: the smallest possible unit of light of a given frequency. You cannot have half a photon; it is all or nothing.
The Intuition: Colour Determines Energy
Red light and blue light are both light, but they behave differently — blue light causes sunburn and drives chemical reactions more readily than red. The reason is that the colour (frequency) of light directly fixes how much energy each photon carries, and blue photons carry more energy than red photons.
The Planck–Einstein Relation
The energy E of a single photon is directly proportional to its frequency f, and inversely proportional to its wavelength λ:
E=hf=λhc
Where:
- E = energy of one photon (joules, J)
- f = frequency (hertz, Hz)
- λ = wavelength (metres, m)
- c = speed of light in vacuum (3.00×108 m/s)
- h = Planck's constant (6.626×10−34 J·s)
Planck's constant h is extremely tiny, so an individual photon carries a very small amount of energy — which is why we never feel single photons striking our skin.
What This Tells You
- Higher frequency = higher energy. Gamma rays have extremely energetic photons; radio waves have very low-energy photons.
- Shorter wavelength = higher energy. Ultraviolet photons are more energetic than visible-light photons; infrared photons are less.
- Energy is quantised. Light energy comes in fixed packets — you can have 1, 2, or 1000 photons, but never 0.5. This was Max Planck's revolutionary idea of 1900.
This is why UV light causes sunburn (UV photons carry enough energy to damage DNA, while visible photons do not), why X-ray photons are energetic enough to pass through soft tissue but get absorbed by bone, and why a photon needs enough energy to actually break a bond or drive a photochemical/biological reaction, rather than merely wavelength-dependent intensity.
A Concrete Example
Question: Which has more energy — a photon of red light (λ=700 nm) or a photon of blue light (λ=450 nm)?
Since E=λhc, energy is inversely proportional to wavelength, so the shorter-wavelength blue photon carries more energy:
- Red: Ered=700×10−9(6.626×10−34)(3.00×108)≈2.84×10−19 J
- Blue: Eblue=450×10−9(6.626×10−34)(3.00×108)≈4.42×10−19 J
The blue photon carries about 1.5 times the energy of the red photon.
A common mistake is to think brighter light means more energetic photons. Brightness is the number of photons per second, not the energy per photon. A bright red light has many low-energy photons; a dim blue light has fewer but higher-energy ones.
The Big Picture
Photon energy is the bridge between the wave nature of light (frequency, wavelength) and its particle nature (energy packets) — one of the foundational ideas of quantum mechanics: at the smallest scales, energy is not continuous but comes in discrete, indivisible units.
Photon energy, given by the Planck-Einstein relation E = hf, is one of the most fundamental formulas in the NCERT Class 12 Physics Dual Nature of Radiation and Matter chapter, and "photon energy formula and calculation" is a heavily searched query among students preparing for CBSE boards, JEE Main, and NEET. Because this idea links directly to the photoelectric effect and atomic spectra, it also anchors several "modern physics important questions" compiled for competitive-exam revision.
Why this formula?
Why Photon Energy is E=hf — The Reasoning Behind the Formula
The formula E=hf is not something you memorise and plug numbers into. It comes from a deep shift in how physicists understood light.
The problem that forced the formula
By the late 1800s, classical physics said light was a wave — continuous, carrying energy in proportion to its intensity (brightness). But blackbody radiation and the photoelectric effect showed something bizarre: when you shine light on a metal, electrons are ejected only if the light's frequency is above a certain threshold, no matter how bright the light is. Below that frequency, even the brightest lamp won't kick out a single electron. Classically this made no sense — a wave's energy depends on amplitude, not frequency.
Einstein's radical idea (1905)
Einstein proposed that light comes in discrete packets — photons — each carrying a fixed energy that depends only on its frequency, with Planck's constant h as the proportionality:
A single photon's energy is E=hf, where f is the frequency of the light.
This directly explains the photoelectric effect: an electron needs a minimum energy (the work function ϕ) to escape. If a photon's energy hf<ϕ, no electron is ejected — regardless of how many photons you send, because each photon interacts with one electron individually.
E=hf is not derived from deeper principles — it is a postulate justified by the experiments it explains, and it unified optics with quantum mechanics.
The equivalent forms
Since c=fλ for light in vacuum, the same idea in terms of wavelength is:
E=λhc
Use this when you're given λ instead of f. A photon also carries momentum (despite having no mass):
p=cE=λh
This follows from special relativity: E2=(pc)2+(mc2)2, and for a photon m=0, so E=pc, hence p=h/λ.
- h=6.626×10−34 J⋅s (Planck's constant)
- c=3.0×108 m/s (speed of light)
- For atomic-scale problems use electronvolts: 1 eV=1.602×10−19 J
A common exam trap
E=hf means higher frequency = more energy per photon — true. But a brighter light does not mean higher photon energy. Intensity is the number of photons per second per area; each photon still carries hf.
Do not confuse intensity (number of photons) with frequency (energy per photon). They are independent.
Final answer: E=hf
The key idea is that the photon must supply at least the binding energy of the proton — here 1 MeV.
Reasoning:
- The minimum photon energy required is E=1 MeV=106 eV.
- Use the photon energy-wavelength relation:
E=λhc⇒λ=Ehc.
- A useful shortcut: hc≈1240 eV⋅nm. So
λ=106 eV1240 eV⋅nm=1.24×10−3 nm.
This matches option (B).
The wavelength is nearly 1.2×10−3 nm, which corresponds to option (B).
The photon must supply exactly the binding energy of the proton (1 MeV). Using E=hc/λ, the wavelength comes out to about 1.24×10−3 nm, which matches option (B).
The core idea here is that removing a proton from a nucleus requires overcoming the nuclear binding force. That binding energy is given as 1 MeV — the minimum energy a photon must carry to eject the proton. Since a photon’s energy is inversely proportional to its wavelength, we can directly compute the wavelength.
A common pitfall is forgetting to convert units properly or mixing up the energy-wavelength relation for photons. Let’s walk through it cleanly.
- Recall the photon energy-wavelength relation For any photon, E=λhc, where h is Planck’s constant and c is the speed of light. The product hc is a very useful constant:
hc=1240 eV⋅nm
(This is exact enough for all exam purposes — it comes from h=4.135667×10−15 eV⋅s and c=2.998×108 m/s, giving hc≈1240 eV⋅nm.)
- Set the photon energy equal to the binding energy The photon must have E=1 MeV=106 eV. So:
λhc=106 eV
- Solve for λ
λ=106 eVhc=106 eV1240 eV⋅nm=1.24×10−3 nm
- Match with the options The value 1.24×10−3 nm is extremely close to 1.2×10−3 nm — the slight difference is due to rounding hc to 1240 instead of 1239.84. In multiple-choice exams, this is the intended match.
A very common mistake is to use E=hf and then forget that c=fλ, or to mix up units (e.g., using hc=1240 eV⋅nm but then treating the energy in MeV without converting to eV). Always convert MeV to eV first: 1 MeV=106 eV.
Memorising hc=1240 eV⋅nm saves enormous time. For any photon energy in eV, the wavelength in nm is simply 1240/E. For MeV energies, just shift the decimal: 1240/106=1.24×10−3.
The correct option is (B) 1.2×10−3 nm.
Method: Converting a Threshold/Binding Energy into a Photon Wavelength
Use this whenever a question gives you a minimum energy a photon must supply (a binding energy, an ionisation energy, a work function) and asks for the corresponding photon wavelength.
Steps
Step 1: Identify the minimum photon energy required
The photon must carry at least the stated binding/threshold energy — treat that value as E directly. Convert it to electron-volts if it isn't already (e.g. 1 MeV=106 eV); electron-volts pair naturally with the shortcut in Step 3.
Step 2: Start from the photon energy–wavelength relation
E=λhc⇒λ=Ehc
Step 3: Use the hc≈1240 eV⋅nm shortcut
For any photon energy expressed in eV, the wavelength in nanometres is simply
λ(nm)=E(eV)1240
This avoids carrying h and c separately through the algebra and is accurate enough for exam purposes.
Step 4: Apply to this problem and sanity-check the order of magnitude
Divide 1240 by the energy in eV, watching the powers of ten carefully — a binding energy in the MeV range (nuclear scale) should give a wavelength many orders of magnitude shorter than a typical atomic-scale binding energy (eV range, giving hundreds of nm). If your answer doesn't fall in the expected range for the physical scale of the problem, re-check the unit conversion in Step 1 rather than the formula.
- KCET 2024Set D-21 markMCQQ.The ratio of area of first excited state to ground state of orbit of hydrogen atom is (A) 1:16 (B) 1:4 (C) 4:1 (D) 16:1
›Reveal solutionSolution
r∝n2⇒ area ∝n4; for n=2 vs n=1 that is 24:14=16:1.
Step 1 — Bohr's radius formula
For a hydrogen-like atom, Bohr's quantisation of angular momentum (mvr=nℏ) combined with the Coulomb-force–centripetal-force balance gives
rn=πme2Zn2h2ε0⟹rn∝n2 (for fixed Z)
For hydrogen (Z=1), rn=n2a0 with a0=0.529 A˚.
Step 2 — From radius to area
The orbit is a circle, so the area enclosed is
An=πrn2
Since rn∝n2,
An∝(n2)2=n4
This n4 (not n2) is the crux of the question — the squaring of an already-squared quantity.
Step 3 — Identify the two states
- Ground state: n=1.
- First excited state: the next level up, n=2. (Not n=3 — the "first excited" state is the first level above the ground state.)
Step 4 — Take the ratio
A1A2=πr12πr22=(12a0)2(22a0)2=(a0)2(4a0)2=a0216a02=16
The question asks for first excited : ground, i.e.
A2:A1=16:1
Step 5 — Guard against the traps
- 4:1 (option C) is the ratio of the radii, not the areas.
- 1:4 and 1:16 have the ratio inverted — the excited orbit is bigger, so the ratio must be greater than 1.
✓Final answerThe correct option is (D) — 16:1.
ANSWER: D
- COMEDK 2024Set 2024-M1 markMCQQ.The difference in energy levels of an electron at two excited levels is 13.75 eV. If it makes a transition from the higher energy level to the lower energy level then what will be the wave length of the emitted radiation? [given h=6.6×10−34 m2 kg s−1;c=3×108 ms−1;1 eV=1.6×10−19 J] (A) 900 nm (B) 90 A (C) 9000 nm (D) 900∘A
›Reveal solutionSolution
Using E=hc/λ, the 13.75 eV energy difference corresponds to a wavelength of 90 nm, i.e. 900 Å — matching option (D).
Step-by-step reasoning
- Convert the energy to joules.
E=13.75 eV×1.6×10−19 J/eV=2.2×10−18 J
- Solve for wavelength.
λ=Ehc=2.2×10−18(6.6×10−34)(3×108)=2.2×10−1819.8×10−26=9.0×10−8 m
- Convert to convenient units.
9.0×10−8 m=90 nm=900 A˚(since 1 nm=10 A˚)
This matches the option listing 900 Å.
Watch outDon't confuse nm and Å — 1 nm equals 10 Å, not 100 Å. Here 90 nm equals 900 Å.
TipQuick shortcut: E(eV)≈λ(nm)1240, so λ≈1240/13.75≈90.2 nm — confirming the result fast.
✓Final answerThe correct option is (D): 900 Å.
- KCET 2022Set B-31 markMCQQ.The radius of hydrogen atom in the ground state is 0.53 A∘. After collision with an electron, it is found to have a radius of 2.12 A∘, the principle quantum number 'n' of the final state of the atom is (A) n = 3 (B) n = 4 (C) n = 1 (D) n = 2
›Reveal solutionSolution
Bohr radii go as n2; the radius has grown by a factor of 4, so n2=4 and the atom is excited to n=2.
1. The Bohr radius law
Quantising the angular momentum (mvr=nh/2π) and balancing the Coulomb force against the centripetal requirement gives, for a hydrogen-like atom,
rn=πme2Zn2h2ε0=Zn2a0
where a0=0.53 A˚ is the Bohr radius. For hydrogen Z=1, so simply
rn=n2a0
The radius grows as the square of the principal quantum number — that quadratic dependence is the whole content of the problem.
2. Set up the ratio
Ground state: r1=0.53 A˚ (with n=1, consistent with the formula).
Final state after the collision: rn=2.12 A˚.
Taking the ratio kills a0 entirely:
r1rn=12a0n2a0=n2
3. Solve
n2=0.532.12=4
n=4=2
4. Physical reading
The collision with the electron transferred just enough energy to lift the atom from the ground state to the first excited state. Check consistency with the energy ladder: En=−13.6/n2 eV, so E2−E1=−3.4−(−13.6)=10.2 eV — precisely the well-known first excitation energy of hydrogen. Everything is self-consistent.
(Trap: option (C) n=1 would mean nothing happened, and n=3 or 4 would require the radius to be 9a0=4.77 A˚ or 16a0=8.48 A˚, not 2.12 A˚.)
✓Final answerThe correct option is (D) — n = 2.
ANSWER: D
- KCET 2019Set A-11 markMCQQ.Frequency of revolution of an electron revolving in nth orbit of H-atom is proportional to (A) n21 (B) n (C) n independent of n (D) n31
›Reveal solutionSolution
The frequency of revolution of an electron in the nth orbit of a hydrogen atom is proportional to n31, making option (D) correct.
The key here is to connect the frequency of revolution — how many times per second the electron circles the nucleus — to the orbital radius and velocity. In Bohr's model, the electron moves in a circular orbit under electrostatic attraction, and its angular momentum is quantized. Frequency is simply v/(2πr), so if we find how v and r depend on n, we can combine them.
Let's work through it step by step.
- Write the force balance for a stable orbit. The centripetal force is provided by the Coulomb attraction between the electron and the proton:
rmv2=r2ke2
where m is the electron mass, v its speed, r the orbit radius, k=1/(4πϵ0), and e the elementary charge.
- Apply Bohr's quantization condition. Angular momentum is an integer multiple of ℏ=h/(2π):
mvr=nℏ
- Solve for r in terms of n. From the quantization condition, v=nℏ/(mr). Substitute into the force equation:
rm(mrnℏ)2=r2ke2
Simplify:
mr3n2ℏ2=r2ke2
Multiply both sides by r3:
mn2ℏ2=ke2r
So:
r=mke2n2ℏ2
This shows r∝n2.
- Find v in terms of n. From mvr=nℏ, we have v=nℏ/(mr). Substitute r∝n2:
v∝n2n=n1
So v∝1/n.
- Now compute the frequency of revolution. Frequency f is the number of orbits per second:
f=2πrv
Substitute the proportionalities v∝1/n and r∝n2:
f∝n21/n=n31
Watch outA common mistake is to think frequency is proportional to 1/n2 because energy is proportional to 1/n2. But frequency here is mechanical revolution frequency, not the frequency of emitted radiation (which relates to energy differences). They are different quantities.
TipYou can also derive this directly from the known expressions: rn=n2a0 and vn=αc/n, where a0 is the Bohr radius and α the fine-structure constant. Then f=vn/(2πrn)∝(1/n)/(n2)=1/n3.
✓Final answerThe frequency of revolution is proportional to n31, so the correct option is (D).
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