Q.Suppose, we think of fission of a 2656Fe nucleus into two equal fragments, 1328Al. Is the fission energetically possible? Argue by working out Q of the process. Given m(2656Fe)=55.93494 u and m(1328Al)=27.98191 u.
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🔒 Start your 14-day free trial to unlock the full solution →Concept understanding — Nuclear Reaction Balancing
Nuclear Reaction Balancing: The Intuition
Think of a nuclear reaction like a game of atomic Lego. You start with a certain set of blocks (the reactants), and after the reaction, you end up with a different set of blocks (the products). The fundamental rule is: you cannot lose or gain any Lego pieces. You can rearrange them, break some apart, or fuse them together, but the total number of each type of piece must stay the same.
In the atomic world, the "pieces" are:
- Protons (positive charge, found in the nucleus)
- Neutrons (neutral charge, also in the nucleus)
- Energy (which can appear or disappear, but that's a separate story)
The nucleus of an atom is made of protons and neutrons. When a nuclear reaction happens, the nuclei change. But the total number of protons and the total number of neutrons must be conserved — they cannot be created or destroyed.
This is different from chemical reactions, where atoms themselves are conserved. In nuclear reactions, atoms can change into different elements, but the nucleons (protons + neutrons) are conserved.
The Precise Statement
A nuclear reaction is balanced when two quantities are equal on both sides of the reaction arrow:
- Mass number (A) — the total number of nucleons (protons + neutrons). This is the superscript number.
- Atomic number (Z) — the total number of protons. This is the subscript number.
For any nuclear reaction:
Reactant1+Reactant2→Product1+Product2+…
The balancing conditions are:
∑Areactants=∑Aproducts
∑Zreactants=∑Zproducts
Nuclear Reaction Balancing Rules
Total mass number (A) on left=Total mass number (A) on right
Total atomic number (Z) on left=Total atomic number (Z) on right
How to Write a Nuclear Equation
Every nuclear particle is written as:
ZAX
Where:
- X = chemical symbol of the element
- A = mass number (top left)
- Z = atomic number (bottom left)
Common particles you'll encounter:
| Particle | Symbol | A | Z |
|---|---|---|---|
| Alpha particle | α or 24He | 4 | 2 |
| Beta particle | β− or −10e | 0 | -1 |
| Gamma ray | γ or 00γ | 0 | 0 |
| Neutron | n or 01n | 1 | 0 |
| Proton | p or 11p | 1 | 1 |
| Positron | β+ or +10e | 0 | +1 |
A common mistake: forgetting that beta particles have Z=−1 (for β−) or Z=+1 (for β+). This is because a neutron turns into a proton (or vice versa), and the beta particle carries away the "missing" charge.
Worked Example
Problem: Balance the following alpha decay reaction:
92238U→90234Th+?
Step 1: Identify what's missing. We have an unknown particle on the right.
Step 2: Balance mass numbers (A).
Left: A=238
Right: A=234+Aunknown
So 238=234+Aunknown⟹Aunknown=4
Step 3: Balance atomic numbers (Z).
Left: Z=92
Right: Z=90+Zunknown …
Why this formula?
Why Nuclear Reaction Balancing Works
Nuclear reaction balancing rests on a single, non-negotiable principle: conservation laws are absolute. In every nuclear reaction — whether natural decay, artificial transmutation, or fission/fusion — two quantities never change:
- Total mass number (A) — the sum of protons + neutrons
- Total atomic number (Z) — the sum of protons
These aren't arbitrary rules. They follow from deeper physics: baryon number conservation (protons and neutrons are baryons, and their total count is fixed) and charge conservation (electric charge cannot be created or destroyed). A nuclear reaction is just a rearrangement of nucleons; the number of nucleons stays constant, and the total charge stays constant.
For a reaction Z1A1X+Z2A2Y→Z3A3W+Z4A4Z:
A1+A2=A3+A4
Z1+Z2=Z3+Z4
The Reasoning Behind Each Conservation Law
Mass number conservation (A conserved):
A nucleon (proton or neutron) can change identity — a neutron can beta-decay into a proton, or a proton can capture an electron and become a neutron — but it cannot vanish or appear from nothing. The total count of nucleons before the reaction equals the total count after. This is why, for example, in alpha decay:
92238U→90234Th+24He
The left side has A=238; the right side has 234+4=238. The alpha particle carries away exactly 4 nucleons.
Atomic number conservation (Z conserved):
Charge is strictly conserved. The total positive charge (proton count) before equals the total after. In the same alpha decay, Z goes from 92 to 90+2=92. If charge weren't conserved, atoms would spontaneously change their chemical identity — which never happens in a closed system.
A common mistake is to think mass number conservation means mass is conserved. It does not. Mass-energy is conserved, but the rest mass can change (and usually does, releasing energy). The mass number A is a count of nucleons, not a measure of mass in kilograms.
How to Apply It: A Worked Example
Suppose you see: 92235U+01n→56141Ba+??Kr+301n
You know the total A on the left: 235+1=236.
On the right, you have 141+AKr+3(1)=144+AKr. …
Concept: Nuclear Reaction Balancing — The Q-value determines if a reaction is energetically possible: Q>0 means energy is released (possible), Q<0 means energy must be supplied (not possible).
Step 1: Write the reaction
2656Fe→21328Al
Step 2: Compute the mass defect
Total mass of products = 2×27.98191 u=55.96382 u
Mass of reactant = 55.93494 u
Mass defect Δm=55.93494−55.96382=−0.02888 u
Step 3: Convert to Q-value …
Fission of 2656Fe into two 1328Al nuclei is not energetically possible because the Q-value is negative (Q≈−0.02888 u≈−26.9 MeV), meaning energy must be supplied rather than released.
The Core Idea: Why Q Tells Us If a Reaction "Goes"
Nuclear reactions, like chemical reactions, obey energy conservation. But in nuclear physics, mass is a form of energy — Einstein's E=mc2. So when a nucleus splits (fission) or joins (fusion), we don't just track kinetic energy; we track the mass defect.
The Q-value of a nuclear reaction is the energy released (or absorbed) during the process. It's defined as:
Q=(total mass of reactants−total mass of products)×c2
If Q>0, the reaction is exothermic — mass is converted to energy, and the reaction can happen spontaneously. If Q<0, the reaction is endothermic — you'd need to pump energy in to make it happen. That's the whole game here.
A common mistake is to forget that the number of nucleons must balance on both sides. Here, 2656Fe has 56 nucleons; two 1328Al nuclei also have 2×28=56 nucleons. So the reaction is possible in terms of nucleon conservation — but energetics is another matter.
Step-by-Step Calculation
1. Write the reaction clearly
We're considering:
2656Fe→1328Al+1328Al
That's one iron nucleus splitting into two identical aluminum nuclei.
2. Recall the Q-value formula
For a reaction A→B+C:
Q=[m(A)−m(B)−m(C)]×c2
If Q comes out positive, mass has been lost and energy released. If negative, mass has been gained — meaning energy must be supplied.
3. Plug in the given masses
We have:
- m(2656Fe)=55.93494 u
- m(1328Al)=27.98191 u
So:
Q=[55.93494−(27.98191+27.98191)] u×c2
Q=[55.93494−55.96382] u×c2
Q=(−0.02888 u)×c2
4. Convert to energy units
We know 1 u=931.5 MeV/c2. So:
Q=−0.02888×931.5 MeV
Q≈−26.9 MeV …
Method: Q-value calculation for nuclear reactions
The Q-value tells us whether a nuclear reaction is energetically possible. If Q>0, the reaction is exothermic and can occur spontaneously. If Q<0, energy must be supplied from outside.
Step 1: Write the reaction clearly
The proposed fission is:
2656Fe→1328Al+1328Al
Step 2: Write the Q-value formula
For a reaction Parent→Daughter1+Daughter2, the Q-value is:
Q=[m(parent)−m(daughter1)−m(daughter2)]c2
In atomic mass units, we can work directly in u, since 1 u⋅c2≈931.5 MeV.
Step 3: Plug in the given masses
m(2656Fe)=55.93494 u
m(1328Al)=27.98191 u
So:
Q=[55.93494−27.98191−27.98191]×931.5 MeV
Step 4: Compute the mass difference
55.93494−2×27.98191=55.93494−55.96382=−0.02888 u
Step 5: Convert to energy
Q=(−0.02888)×931.5 MeV≈−26.9 MeV …
Common Mistakes in Nuclear Reaction Balancing (Fe Fission Problem)
Mistake 1: Forgetting to check charge conservation
Students often jump straight to the mass defect calculation without verifying that the reaction is even balanced. Here, the parent nucleus is 2656Fe with atomic number 26. Two 1328Al fragments give a total atomic number of 13+13=26 — that checks out. But the mass numbers: 56 vs 28+28=56 — also fine. So the reaction is balanced.
How to avoid: Always write the full nuclear equation first, with both mass numbers and atomic numbers on each side. Tick them off one by one before doing any energy calculation.
Mistake 2: Using the wrong Q-value formula
The Q-value for fission is:
Q=[mparent−∑mfragments]c2
Some students write it as Q=∑mproducts−mreactant, which flips the sign. If you do that, you'll get a negative Q and wrongly conclude the reaction is impossible — or vice versa.
How to avoid: Remember: Q=(initial mass−final mass)×c2. A positive Q means energy is released (exothermic/energetically possible). A negative Q means energy must be supplied.
Mistake 3: Forgetting to multiply fragment masses by the number of fragments
The problem says "two equal fragments." Each fragment is 1328Al with mass 27.98191 u. The total final mass is 2×27.98191 u, not 27.98191 u.
How to avoid: Circle the stoichiometric coefficients in your nuclear equation. If the equation says 2 Al, then the mass contribution is 2×m(Al).
Mistake 4: Not converting atomic mass units to energy correctly
Even if you get the mass defect right, you need 1 u=931.5 MeV/c2. Some students use 931 or forget the c2 entirely.
How to avoid: Write the conversion factor explicitly: Q(MeV)=Δm(u)×931.5 MeV/u.
Mistake 5: Misinterpreting the sign of Q
Let's do the actual calculation:
Δm=55.93494−2(27.98191)=55.93494−55.96382=−0.02888 u
Q=(−0.02888)×931.5=−26.9 MeV …
- COMEDK 2026Set 2026-M1 markMCQQ.A mercury-198 nucleus is bombarded by a neutron, which causes a nuclear reaction n01+Hg80198⟶Au79197+X What is the unknown product particle X ? (A) Alpha particle (B) Beta particle (C) Deuteron (D) Proton
›Reveal solutionSolution
Balancing mass and charge numbers in n01+Hg80198→Au79197+X gives X with A=2, Z=1: a deuteron — option (C).
Concept and Intuition
In any nuclear reaction the total mass number A (superscript) and the total atomic number Z (subscript) are each conserved. Balance them on both sides to identify the unknown particle.
Step-by-step solution
- Conserve mass number A:
1+198=197+AX ⇒ AX=2
- Conserve atomic number Z: 0+80=79+ZX ⇒ ZX=1 …
- COMEDK 2025Set 2025-E1 markMCQQ.When 10 B5 nuclei are bombarded by neutrons, one of the resultant nuclei is 7Li3. Then the emitted particle will be: (A) Alpha particle (B) Neutrons (C) Gamma particle (D) Beta particle
›Reveal solutionSolution
In a nuclear reaction, both mass number and atomic number must be conserved. Bombarding boron-10 with a neutron yields lithium-7 and an alpha particle, so the emitted particle is an alpha particle.
Concept & Intuition
Nuclear reactions obey two fundamental conservation laws:
- Conservation of mass number (total number of protons + neutrons)
- Conservation of atomic number (total number of protons)
When a neutron strikes a boron-10 nucleus, the compound nucleus rearranges and breaks apart. The unknown emitted particle must balance the equation so that the sums on both sides match. By writing the reaction with symbols and solving for the missing particle’s mass and atomic numbers, we can identify it.
Step-by-step reasoning
- Write the reaction in standard nuclear notation The target is boron-10: 510B. The projectile is a neutron: 01n. One product is lithium-7: 37Li. Let the unknown emitted particle be ZAX. The reaction is:
510B+01n⟶37Li+ZAX
-
Apply conservation of mass number
Left side: 10+1=11.
Right side: 7+A.
So 7+A=11 → A=4.
-
Apply conservation of atomic number
Left side: 5+0=5.
Right side: 3+Z. …
- COMEDK 2023Set 2023-E1 markMCQQ.Which of the following statement is true when a gamma decay occurs from the nucleus of an atom? (A) Mass number is reduced by 4 and atomic number remains the same (B) Mass number remains the same and atomic number increases by 1 (C) Mass number and atomic number are not changed (D) Mass number is reduced by 4 and atomic number is reduced by 2
›Reveal solutionSolution
Gamma emission is a de-excitation of the nucleus; it emits only a photon, so neither A nor Z changes.
Gamma decay occurs when a nucleus in an excited state releases its excess energy as a high-energy photon (γ-ray) and settles to a lower energy state. A photon has no charge and no rest mass, and no protons or neutrons leave the nucleus. Therefore:
- Mass number A — unchanged
- Atomic number Z — unchanged …
- KCET 2022Set B-31 markMCQQ.Binding energy of a Nitrogen nucleus [714N], given m[714N]=14.00307u (A) 206.5 MeV (B) 78 MeV (C) 104.7 MeV (D) 85 MeV
›Reveal solutionSolution
Find the mass defect between the 7 free protons + 7 free neutrons and the actual nucleus, then convert with 1 u=931.5 MeV.
1. The concept — mass defect
A bound nucleus is lighter than the sum of its free constituents. The missing mass, the mass defect Δm, has been released as the binding energy that holds the nucleons together (Einstein: E=Δmc2). Equivalently, Eb is the energy you must supply to pull the nucleus apart into free nucleons.
Δm=[ZmH+(A−Z)mn]−M(atom)
Eb=Δm×931.5 MeV/u
Why mH and not mp: the quoted mass 14.00307 u is the atomic mass of 14N, which includes its 7 electrons. Using the hydrogen atom mass (1.00783 u = proton + 1 electron) on the other side means the 7 electron masses cancel automatically — the standard bookkeeping trick.
2. Identify the nucleons
For 714N: Z=7 protons, A−Z=14−7=7 neutrons.
Standard masses:
mH=1.00783 u,mn=1.00867 u
3. Compute the mass defect
7×1.00783=7.05481 u
7×1.00867=7.06069 u
Sum=7.05481+7.06069=14.11550 u
Δm=14.11550−14.00307=0.11243 u
4. Convert to energy …
- COMEDK 2022Set 20221 markMCQQ.During α-decay, atomic mass of parent nuclei is (A) decreased by 2 units (B) increased by 2 units (C) decreased by 4 units (D) increased by 4 units
›Reveal solutionSolution
So the mass number A decreases by 4 (and the atomic number Z decreases by 2). The question asks about the atomic mass → decreased by 4 units.
Concept: α-decay emits a helium nucleus ⁴₂He.
ᴬ_Z X → ᴬ⁻⁴_(Z−2) Y + ⁴₂He …
- COMEDK 2021Set 2021-B1 markMCQQ.When 5B10 bombarded by a certain particles, α particles are emitted with the resulting nucleus having a mass number 7 and atomic number 3. The particle used for bombarded is (A) Positron (B) Neutron (C) Proton (D) Electron
›Reveal solutionSolution
Conserving mass number and charge in 510B+x→37Li+24He gives the bombarding particle mass number 1 and charge 0 — a neutron.
The reaction is
510B+ZAx→37Li+24He.
Mass number: 10+A=7+4=11⇒A=1. …
- KCET 2020Set A-11 markMCQQ.During a β− decay (A) an atomic electron is ejected. (B) an electron which is already present within the nucleus is ejected. (C) A neutron in the nucleus decays emitting an electron. (D) A proton in the nucleus decays emitting an electron.
›Reveal solutionSolution
β− decay is the conversion of a nuclear neutron into a proton with the creation of an electron and an antineutrino.
Step 1 — The fundamental process.
01n⟶11p+−10e+νˉ
and at the level of the whole nucleus,
ZAX⟶Z+1AY+−10e+νˉ.
The mass number A is unchanged (a nucleon is merely converted), while the atomic number increases by 1 — the fingerprint of β− decay. It occurs in neutron-rich nuclei, because converting a neutron to a proton moves them towards the stability line.
Step 2 — Why (B) is wrong (the key conceptual point).
Electrons do not exist inside the nucleus. Two arguments: (i) confining an electron to a nuclear radius (∼10−15 m) would, by the uncertainty principle, give it an energy of tens of MeV — far above the few-MeV energies actually observed;
(ii) nuclear spin statistics forbid it. The β particle is created at the instant of decay, exactly as a photon is created when an atom de-excites.
Step 3 — Why (A) and (D) are wrong.
- (A) An atomic (orbital) electron is not involved: ejecting one would ionise the atom, not change Z. (The related process where a nucleus captures an orbital electron is electron capture, and it lowers Z.) …
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